Caution Against the Inappropriate Use of Analytical Fate and Transport Models to Estimate the Age and Risk of Petroleum Product Releases     

Pedro J. J. Alvarez 《Ground Water Monitoring & Remediation》1996,16(2):72-76

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The chemical durability of tektites—A laboratory study and correlation with long-term corrosion behavior     

Aaron Barkatt  Mervet S Boulos  Alisa Barkatt  William Sousanpour  Morad A Boroomand  Pedro B Macedo  John A O&#x;Keefe 《Geochimica et cosmochimica acta》1984,48(2):361-371

Leach tests carried out on tektite specimens (indochinites and australites) under high-dilution conditions show a common behavior characterized by low leach rates (1.8 × 10^?5g · m^?2 · d^?1or 7.2 × 10^?12m · d^?1 at 23°C) and an activation energy of (79.6 ± 0.7) × 10³J · mol^?1. The extent of selective leaching is very small, of the order of 10^?8 m. Extrapolation of test results over the lifetime of the tektites gives an excellent agreement with field observations on the extent of corrosion, and this is an important step in establishing the validity of laboratory tests as a basis for the development of models and predictions concerning long-term durabilities at least in the limiting case of high dilution or rapid flow. The results are also shown to be in agreement with various previous observations on the corrosion resistance of tektites. The chemical durability of tektites is observed to be consistent with their composition, highlighting requirements for high corrosion resistance in glasses; these requirements include a silica content in excess of 67 mol%, an extremely low water content and an alkali content which is low both absolutely and relative to the di- and poly-valent metal oxide levels. It is shown that artificial glasses which fulfil these criteria are no less corrosion-resistant than the corresponding natural glasses. These conclusions have bearing on the development as well as on the evaluation of glasses intended for very long service, such as radioactive waste vitrification media.  相似文献   

A conceptual framework and its application for addressing leakage: the case of avoided deforestation     

Louise Aukland  Pedro Moura CostaSandra Brown 《Climate Policy》2003,3(2):123-136

One of the most challenging technical issues associated with project-based mechanisms is that of leakage. A conceptual framework is proposed for the identification and analysis of leakage potentially generated by a project. The categorization of leakage based on the actors responsible for their manifestation is proposed, which divides sources of leakage into primary and secondary types. It is the actors or agents responsible for the baseline activities that cause primary leakage. Secondary leakage occurs when the project’s outputs create incentives for third parties to increase emissions elsewhere. This distinction, based on the source of leakage, provides a basis for the analysis outlined in the paper. The extent and type of leakage will vary depending on the project typology and design. Using a decision tree approach, the process of identifying potential sources of leakage is demonstrated for the case study of avoided deforestation projects. If the main elements determining a baseline are properly identified and understood, in particular the ‘baseline agents’, a combination of the decision tree approach and apportioning responsibility, can assist in the quantification and monitoring of primary leakage. An analysis at the project design stage can also assist in minimizing the risk of future leakage. Econometric methods may prove more useful in analyzing secondary leakage.  相似文献   

APPLICATION OF A QUASI-2D HYDRO-MORPHOLOGICAL MODEL TO THE ARGENTINEAN PARAN RIVER     

Pedro A. BASILE  Gerardo A. RICCARDI  Center for Hydroenvironmental Research  National University of Rosario  Riobamba bis   《国际泥沙研究》2002,(1)

1 INTRODUCTION Mathematical models to analyze the one-dimensional morphological evolution of alluvial rivers, induced either by natural events or anthropic actions, have been commonly applied since the original work of de Vries (1957, 1965, 1969). In the last decades much effort was made in developing suitable 2D horizontal and 3D time-depending mathematical models to study riverbed changes. In fact, full 2D-H hydro-morphological models (Olesen, 1987; Spasojevic and Holly, 1988) as w…  相似文献   

Dynamics of perfect fluid unified dark energy models     

Luís M. G. Beça  Pedro P. Avelino 《Monthly notices of the Royal Astronomical Society》2007,376(3):1169-1172

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Tectonic shortening and gravitational spreading in the Gulf of Cadiz accretionary wedge: Observations from multi-beam bathymetry and seismic profiling     

Marc-André Gutscher  Stephane Dominguez  Graham K. Westbrook  Pascal Gente  Nathalie Babonneau  Thierry Mulder  Eliane Gonthier  Rafael Bartolome  Joaquim Luis  Filipe Rosas  Pedro Terrinha 《Marine and Petroleum Geology》2009,26(5):647-659

The Gulf of Cadiz lies astride the complex plate boundary between Africa and Eurasia west of the Betic-Rif mountain belt. We report on the results of recent bathymetric swathmapping and multi-channel seismic surveys carried out here. The seafloor is marked by contrasting morphological provinces, spanning the SW Iberian and NW Moroccan continental margins, abyssal plains and an elongate, arcuate, accretionary wedge. A wide variety of tectonic and gravitational processes appear to have shaped these structures. Active compressional deformation of the wedge is suggested by folding and thrusting of the frontal sedimentary layers as well as basal duplexing in deeper internal units. There is evidence for simultaneous gravitational spreading occurring upslope. The very shallow mean surface and basal slopes of the accretionary wedge (1° each) indicate a very weak decollement layer, geometrically similar to the Mediterranean Ridge accretionary complex. Locally steep slopes (up to 10°) indicate strongly focused, active deformation and potential gravitational instabilities. The unusual surface morphology of the upper accretionary wedge includes “raft-tectonics” type fissures and abundant sub-circular depressions. Dissolution and/or diapiric processes are proposed to be involved in the formation of these depressions.  相似文献   

Vulnerability of water resources,vegetation productivity and soil erosion to climate change in Mediterranean watersheds     

João Pedro Nunes  Júlia Seixas  Nuno Ricardo Pacheco 《水文研究》2008,22(16):3115-3134

Climate change is expected to increase temperatures and lower rainfall in Mediterranean regions; however, there is a great degree of uncertainty as to the amount of change. This limits the prediction capacity of models to quantify impacts on water resources, vegetation productivity and erosion. This work circumvents this problem by analysing the sensitivity of these variables to varying degrees of temperature change (increased by up to 6·4 °C), rainfall (reduced by up to 40%) and atmospheric CO₂ concentrations (increased by up to 100%). The SWAT watershed model was applied to 18 large watersheds in two contrasting regions of Portugal, one humid and one semi‐arid; incremental changes to climate variables were simulated using a stochastic weather generator. The main results indicate that water runoff, particularly subsurface runoff, is highly sensitive to these climate change trends (down by 80%). The biomass growth of most species showed a declining trend (wheat down by 40%), due to the negative impacts of increasing temperatures, dampened by higher CO₂ concentrations. Mediterranean species, however, showed a positive response to milder degrees of climate change. Changes to erosion depended on the interactions between the decline in surface runoff (driving erosion rates downward) and biomass growth (driving erosion rates upward). For the milder rainfall changes, soil erosion showed a significant increasing trend in wheat fields (up to 150% in the humid watersheds), well above the recovery capacity of the soil. Overall, the results indicate a shift of the humid watersheds to acquire semi‐arid characteristics, such as more irregular river flows and increasingly marginal conditions for agricultural production. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Solar Magnetograms at 12 μm Using the Celeste Spectrograph     

Thomas G. Moran  Donald E. Jennings  L. Drake Deming  George H. McCabe  Pedro V. Sada  Robert J. Boyle 《Solar physics》2007,241(2):213-222

We present the first solar vector magnetogram constructed from measurements of infra-red Mg I 12.32-μm line spectra. Observations were made at the McMath-Pierce Telescope using the Celeste spectrometer/polarimeter. Zeeman-split Stokes line spectra were fitted with Seares profiles to obtain the magnetic field parameters. Maps of absolute field strength, line-of-sight angle, and azimuth are presented. Analysis shows that the variation in field strength within a spatial resolution element, 2 arcseconds, is greatest in the sunspot penumbra and that this is most likely caused by vertical field strength gradients, rather than horizontal image smearing. Widths of the Zeeman-split σ components, assuming a formation layer thickness of 200 km, indicate that vertical field strength gradients can be as large as 6.5 G/km in a penumbra.  相似文献   

Diffuse Emission of Hydrogen from Poás Volcano,Costa Rica,America Central     

Gladys V. Melián  Inés Galindo  Nemesio M. Pérez  Pedro A. Hernández  Mario Fernández  Carlos Ramírez  Raúl Mora  Guillermo E. Alvarado 《Pure and Applied Geophysics》2007,164(12):2465-2487

We report the results of four soil H₂ surveys carried out in 2000–2003 at Poás volcano, Costa Rica, to investigate the soil H₂ distribution and evaluate the diffuse H₂ emission as a potential surveillance tool for Poás volcano. Soil gas H₂ contents showed a wide range of concentration from 0.2 to 7,059 ppmV during the four surveys. Maps of soil gas H₂ based on Sequential Gaussian Simulation showed low H₂ concentration values in the soil atmosphere (<0.7 ppmV) for most of the study area, whereas high soil gas H₂ values were observed inside the active crater of Poás. A significant increase in soil gas H₂ concentration was observed inside the active crater during 2001 and 2002 with respect to year 2000, followed by a decrease in 2003. The observed spatial and temporal variations of soil H₂ concentration have been well correlated with seismicity, microgravimetry and fumarolic chemistry changes which occurred during this study. These observations evidence changes in the shallow magmatic-hydrothermal system of Poás, and it might be related to a potential magmatic intrusion during the period 1998–2004. Therefore, monitoring diffuse H₂ emission of Poás has become an important geochemical tool for the monitoring of its volcanic activity.  相似文献   

Anomalous Emissions of SO2 During the Recent Eruption of Santa Ana Volcano, El Salvador, Central America   总被引：1，自引：0，他引：1  

Rodolfo Olmos  José Barrancos  Claudia Rivera  Francisco Barahona  Dina L. López  Benancio Henriquez  Agustín Hernández  Efrain Benitez  Pedro A. Hernández  Nemesio M. Pérez  Bo Galle 《Pure and Applied Geophysics》2007,164(12):2489-2506

Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO₂ degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO₂ flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO₂ flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1^st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO₂ flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO₂ flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO₂ fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO₂ and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO₂ flux can provide important warning signals for incoming explosive activity in active volcanoes.  相似文献