Thallium isotope composition of the upper continental crust and rivers—An investigation of the continental sources of dissolved marine thallium     

Sune G. Nielsen  Mark Rehkämper  Per Andersson  Peter W. Swarzenski  Detlef Günther 《Geochimica et cosmochimica acta》2005,69(8):2007-2019

The thallium (Tl) concentrations and isotope compositions of various river and estuarine waters, suspended riverine particulates and loess have been determined. These data are used to evaluate whether weathering reactions are associated with significant Tl isotope fractionation and to estimate the average Tl isotope composition of the upper continental crust as well as the mean Tl concentration and isotope composition of river water. Such parameters provide key constraints on the dissolved Tl fluxes to the oceans from rivers and mineral aerosols.The Tl isotope data for loess and suspended riverine detritus are relatively uniform with a mean of ε²⁰⁵Tl = −2.0 ± 0.3 (ε²⁰⁵Tl represents the deviation of the ²⁰⁵Tl/²⁰³Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 10⁴). For waters from four major and eight smaller rivers, the majority were found to have Tl concentrations between 1 and 7 ng/kg. Most have Tl isotope compositions very similar (within ±1.5 ε²⁰⁵Tl) to that deduced for the upper continental crust, which indicates that no significant Tl isotope fractionation occurs during weathering. Based on these results, it is estimated that rivers have a mean natural Tl concentration and isotope composition of 6 ± 4 ng/kg and ε²⁰⁵Tl = −2.5 ± 1.0, respectively.In the Amazon estuary, both additions and losses of Tl were observed, and these correlate with variations in Fe and Mn contents. The changes in Tl concentrations have much lower amplitudes, however, and are not associated with significant Tl isotope effects. In the Kalix estuary, the Tl concentrations and isotope compositions can be explained by two-component mixing between river water and a high-salinity end member that is enriched in Tl relative to seawater. These results indicate that Tl can display variable behavior in estuarine systems but large additions and losses of Tl were not observed in the present study.  相似文献   

Fourier-transform Infrared Spectroscopy (FTIRS), a New Method to Infer Past Changes in Tree-line Position and TOC using Lake Sediment     

Peter Rosén  Per Persson 《Journal of Paleolimnology》2006,35(4):913-923

This study tests the hypothesis that Fourier-transform infrared spectroscopy (FTIRS) of lake sediments can be used to infer past changes in tree-line position and total organic carbon (TOC) content of lake water. A training set of 100 lakes from northern Sweden spanning a broad altitudinal and TOC gradient from 0.7 to 14.9 mg/l was used to assess whether vegetation zones and TOC can be modelled from FTIR spectra of surface sediments (0–1 cm) using principal component analysis (PCA) and partial least squares (PLS) regression. Preliminary results show that FTIRS of lake sediments can be used to reconstruct past changes in tree line and the TOC content of lake water, which is hardly surprising since FTIRS registers the properties of organic and minerogenic material derived from the water mass and the drainage area. The FTIRS model for TOC gives a root mean squared error (RMSECV) of calibration of 1.4 mg/l (10% of the gradient) assessed by internal cross-validation (CV) yielding an R_cv² of 0.64. This should be compared with a near-infrared spectroscopy (NIRS) and diatom transfer function for TOC from the same set of lakes, which have a R_cv² of 0.61 and 0.31, and RMSECV of 1.6 and 2.3 mg/l, respectively. The FTIRS-TOC model was applied to a Holocene sediment core from a tree-line lake and the results show similar trends as inferences from NIRS and pollen from the same core. Overall, the results indicate that changes in FTIR spectra from lake sediments reflect differences in catchment vegetation and TOC, and that FTIRS-models based on surface-sediment samples can be applied to sediment cores for retrospective analysis.  相似文献   

Regional geological and tectonic structures of the North Sea area from potential field modelling   总被引：2，自引：1，他引：2  

S.B. Lyngsie  H. Thybo  T.M. Rasmussen   《Tectonophysics》2006,413(3-4):147-170

The spatial distribution of large-scale crustal domains and their boundaries are investigated in the North Sea area by combining gravity, magnetic and seismic data. The North Sea is situated on the plates of three continents, Avalonia, Laurentia and Baltica, which collided during the Caledonian orogeny in the middle Palaeozoic. The location and continuation of the collisional sutures are debated. We apply filters and transformations to potential field data to focus on the crystalline crust and uppermost mantle on a regional scale in order to extract new information on continental sutures. The transformations reveal intrinsic features of crustal transitions between the Caledonian plates and their relation to later extensional structures. The transformations include the Hough Transform applied to the gravity field, calculation of fractional derivatives and integrals of the gravity and magnetic fields, the pseudogravity field and the horizontal gradient field as well as upward continuation. The results indicate a fundamental difference between the lithosphere of Avalonia, Laurentia and Baltica. The location of the Mesozoic rift system (the Central Graben and Viking Graben), may have been partly determined by the presence of the sutures between these three plate, indicative of extensional reactivation of compressional structures. A significant lineament across the entire North Sea between Scotland and North Germany indicates that the lower crust of Baltica provenance may extend as far south-westward as to this lineament. Comparison of the power spectra of the gravity field in five selected areas shows significant differences in the long wavelength components between the areas north and south of the lineament corresponding to differences in crustal properties. This lineament could represent the suture between lithosphere of Caledonian origin (Avalonia) versus lithosphere of Precambrian origin (Baltica) in the lower crust and upper mantle. If this is the case, the lineament is the missing link in the reconstruction of the triple plate collision.  相似文献   

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 1: constructing the time scale     

Katrine K. Andersen  Anders Svensson  Sigfus J. Johnsen  Sune O. Rasmussen  Matthias Bigler  Regine Rthlisberger  Urs Ruth  Marie-Louise Siggaard-Andersen  Jrgen Peder Steffensen  Dorthe Dahl-Jensen  Bo M. Vinther  Henrik B. Clausen 《Quaternary Science Reviews》2006,25(23-24):3246

The Greenland Ice Core Chronology 2005, GICC05, is extended back to 42 ka b2k (before 2000 AD), i.e. to the end of Greenland Stadial 11. The chronology is based on independent multi-parameter counting of annual layers using comprehensive high-resolution measurements available from the North Greenland Ice Core Project, NGRIP. These are measurements of visual stratigraphy, conductivity of the solid ice, electrolytical melt water conductivity and the concentration of Na⁺, Ca²⁺, SO₄²⁻, NO₃⁻, NH₄⁺. An uncertainty estimate of the time scale is obtained from identification of ‘uncertain’ annual layers, which are counted as 0.5±0.5 years. The sum of the uncertain annual layers, the so-called maximum counting error of the presented chronology ranges from 4% in the warm interstadial periods to 7% in the cold stadials. The annual accumulation rates of the stadials and interstadials are on average one-third and half of the present day values, respectively, and the onset of the Greenland Interstadials 2, 3, and 8, based on 20 year averaged δ¹⁸O values, are determined as 23,340, 27,780, and 38,220 yr b2k in GICC05.  相似文献   

An overview of trace metals in the environment, from mobilization to remediation   总被引：10，自引：0，他引：10  

A. C. L. Larocque  Patricia E. Rasmussen 《Environmental Geology》1998,33(2-3):85-91

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Performance of the In Situ Microcosm Technique for Measuring the Degradation of Organic Chemicals in Aquifers     

Per H. Nielsen  Thomas H. Christensen  Hans-Jørgen Albrechtsen  Robert W. Gillham 《Ground Water Monitoring & Remediation》1996,16(1):130-140

An in situ microcosm (ISM) consists of a stainless steel cylinder isolating about 2 L of the aquifer and is equipped with valves allowing for loading and sampling from the ground surface. During the last five years, this technique has been used frequently to study the degradation of organic chemicals in polluted and pristine aquifers representing different redox environments. The ISM technique has great potential for providing field-relevant degradation potentials and rate constants, but care must be taken in using the equipment and interpreting the results. This paper provides details concerning the installation and operation of an ISM and presents experiences concerning data interpretation and monitoring of redox conditions.  相似文献   

Time dependence of organic matter decay and mixing processes in Framvaren, a permanently anoxic fjord in South Norway     

David W. Dyrssen  Per O. J. Hall  Conny Haraldsson  Melissa Chierici  Jens M. Skei  H. Göte östlund 《Aquatic Geochemistry》1996,2(2):111-129

Three different layers have been identified in Framvaren, which has a maximum water depth of 184 m. One oxic layer above the redoxcline at 18–20 m. One anoxic layer from 20 to 100 m which is occasionally ventilated by a flow over the sill (which has a depth of 2.5 m), and finally a stagnant layer below 100 m. Using the release rate of silica from the bottom and measurements of the concentration of HTO it is possible to make some calculations on the annual volume of interleaving in the layers 25–50 m, 50–75 m, and 75–100 m together with the advective flows. Reliable values of the sulfide concentration were obtained by precipitating and weighing HgS together with careful protection of all anoxic water samples with argon. The light yellow color of the precipitate in the depth range 25 to 80 m indicates that the occasional ventilation will cause such reactions as 0.50₂ + H₂S S(colloidal) + H₂O. The elemental sulfur, being stabilized with HS^–, is set free upon the precipitation of HgS. The new data for the concentration of sulfide give an acceptable stoichiometry for the decay reaction of organic matter. This is not the case with the data of Yao and Millero. The mean values for the concentrations of ammonium and phosphate agree with the new data of Yao and Millero. The mol/mol C/N ratio of 10.1 found in trapped material by Naess and coworkers (1988) agrees with the stoichiometry of the dissolved constituents, i.e. C/N = 9.92 ± 0.45. A denitrification reaction is suggested to explain the high values of C/N. The vertical diffusion coefficient at 100 m calculated from the depth profile of silica was 0.92 × 10^–6 m² s^–1 which lies in the range of values given by Fröyland. Finally, the ¹⁴C age of the total dissolved inorganic carbon (Ct) in the water below 90 m was about 1600 years indicating a bioproduction in the period 8000 years B.P. to A.D. 1853 when a channel was opened between the fjord outside (Helvikfjord) and Framvaren.  相似文献   

CHARACTERISTICS OF MESOSCALE FLOOD-MAKING TORRENTIAL RAIN SYSTEM SIMULATED BY HIGH RESOLUTION LIMITED AREA MODEL—NUMERICAL SIMULATION OF A HEAVY RAIN PROCESS DURING MEIYU SEASON IN 1991   总被引：1，自引：0，他引：1  

朱禾  E.Rasmussen 《Acta Meteorologica Sinica》1996,(3)

An experimental work on the transplant of high resolution limited area model(HIRLAM) isfirstly introduced into China.For the implementation,first of all is to adjust a new geographicalcoordination and to remove the instability caused by the Tibetan Plateau,the roof of the world.Then,we have applied this model to simulate a flood-making torrential rain process which occurredin the Changjiang-Huaihe River Valley in July 1991.That revealed the formation,development andmovement of a mesoseale heavy rain system which had made a disastrous flood event in the middleand lower reaches of Changjiang River Valley.The result encourages us to use the HIRLAM for the researches on the Meiyu belt,the salientfeature of precipitation of East Asia,and the numerical prediction of heavy rains in China.  相似文献   

ON THE SENSITIVITY OF PRECIPITATION FORECASTS TO THE MOIST PHYSICS AND THE HORIZONTAL RESOLUTION OF NUMERICAL MODEL     

俞小鼎  Leif Laursen  Erik Rasmussen 《Acta Meteorologica Sinica》1997,(4)

The impacts of the enhanced model's moist physics and horizontal resolution upon the QPFs(quantitative precipitation forecasts)are investigated by applying the HIRLAM(high resolutionlimited area model)to the summer heavy-rain cases in China.The performance of the control run,for which a 0.5°×0.5°grid spacing and a traditional“grid-box supersaturation removal+Kuo typeconvective paramerization”are used as the moist physics,is compared with that of the sensitivityruns with an enhanced model's moist physics(Sundqvist scheme)and an increased horizontalresolution(0.25°×0.25°),respectively.The results show:(1)The enhanced moist physics scheme(Sundqvist scheme),by introducing the cloud watercontent as an additional prognostic variable and taking into account briefly of the microphysicsinvolved in the cloud-rain conversion,does bring improvements in the model's QPFs.Althoughthe deteriorated QPFs also occur occasionally,the improvements are found in the majority of thecases,indicating the great potential for the improvement of QPFs by enhancing the model's moistphysics.(2)By increasing the model's horizontal resolution from 0.5°×0.5°,which is already quitehigh compared with that of the conventional atmospheric soundings,to 0.25°×0.25°without thesimultaneous enhancement in model physics and objective analysis,the improvements in QPFs arevery limited.With higher resolution,although slight amelioration in locating the rainfall centersand in resolving some finer structures of precipitation pattern are made,the number of the mis-predicted fine structures in rainfall field increases with the enhanced model resolution as well.  相似文献   

Methane,carbon monoxide and methylchloroform in the southern hemisphere   总被引：1，自引：0，他引：1  

P. J. Fraser  P. Hyson  R. A. Rasmussen  A. J. Crawford  M. A. K. Khalil 《Journal of Atmospheric Chemistry》1986,4(1):3-42

New observational data on CH₄, CO and CH₃CCl₃ in the southern hemisphere are reported. The data are analysed for long term trends and seasonal cycles. CH₃CCl₃ data are used to scale the OH fields incorporated in a two dimensional model, which in turn, is used to constrain the magnitude of a global CH₄ source function. The possible causes of observed seasonality of CH₃CCl₃, CH₄ and CO are identified, and several other aspects of observed CH₄ variability are discussed.Possible future research directions are also given.  相似文献