Diagenetic disturbances of marine sedimentary records from methane‐influenced environments in the Fram Strait as indications of variation in seep intensity during the last 35 000 years     

Kamila Sztybor  Tine L. Rasmussen 《Boreas: An International Journal of Quaternary Research》2017,46(2):212-228

The effect of seeping of methane on marine sediment records has been studied in four gravity cores from Vestnesa Ridge, Svalbard margin. The area shows acoustic signs in the form of flares indicating active methane gas seepage. For a better understanding of the timing and variability of the flux of methane in the past and the effects on potential proxies, a detailed study of the diagenetic processes that may affect the composition and structure of both sediments and foraminiferal shells is needed. Here we discuss deep‐sea records from methane‐influenced environments in three cores from an active and very heterogeneous seep‐area (pockmark) and one core from outside the pockmark for background. The results include the distribution and stable isotopes of authigenic carbonates and of benthic and planktonic foraminifera, magnetic susceptibility, AMS‐¹⁴C dates, sedimentary data and biostratigraphy. Extremely low δ¹³C values recorded in both benthic and planktonic foraminifera during the Bølling‐Allerød interstadials indicate possible increased methane flux beginning at late Heinrich event H1. The recorded low values are mainly a result of diagenetic overprint by methane‐derived authigenic carbonates. The δ¹⁸O signals of authigenic carbonates are close to those of foraminiferal calcite and thus the δ¹⁸O records remain a valid stratigraphical tool in methane seep sites, except in the case of severely encrusted samples. In addition, the records from the active pockmark show nearly constant values of low magnetic susceptibility in contrast to higher and more variable magnetic susceptibility values from the control station and other published records from normal sediments west of Svalbard. This phenomenon is probably caused by dissolution of magnetic minerals in the reducing environmental conditions of methane seep sediments, associated with anaerobic oxidation of methane and formation of paramagnetic minerals (pyrite). This process enables magnetic susceptibility to be used as a common diagnostic tool for identifying methane‐related palaeo‐reductive environments.  相似文献   

SHRIMP U–Pb geochronology of authigenic xenotime and its potential for dating sedimentary basins     

I. R. Fletcher  B. Rasmussen  N. J. McNaughton 《Australian Journal of Earth Sciences》2013,60(5):845-859

SHRIMP (Sensitive High‐Resolution Ion MicroProbe) analytical procedures have been developed to enable dating of the small, early diagenetic xenotime overgrowths that commonly occur on zircons in siliciclastic sedimentary rocks. The method will be particularly useful in Precambrian terranes, where diagenetic xenotime dating could play a role equivalent to biostratigraphic dating in the Phanerozoic. Reliable ²⁰⁷Pb/²⁰⁶Pb data are more readily obtained than ²⁰⁶Pb/²³⁸U, which also favours application to the Precambrian. However, it is demonstrated that ²⁰⁶Pb/²³⁸U dating of larger overgrowths (>10 μm) is also viable and applicable to Phanerozoic samples. SHRIMP Pb/Pb geochronology of authigenic xenotime in an unmetamorphosed Palaeoproterozoic sandstone in the Kimberley Basin has constrained diagenesis to a precision of ± 7 Ma. In contrast, greenschist‐facies metasediments of the Archaean Witwatersrand Basin, South Africa, contain both authigenic and alteration xenotime that record a complex history of growth from early diagenesis to the last major thermal event to affect the basin.  相似文献   

Evaluation of risk concepts in partial duration series     

P. F. Rasmussen  D. Rosbjerg 《Stochastic Hydrology and Hydraulics》1991,5(1):1-16

Conventional design practice aims at obtaining optimal estimates of floods with specified exceedance probabilities. Such estimates are, however, known on the average to be exceeded more frequently than expected. Alternatively, methods focusing on the expected exceedance probability can be used. Two different methods are considered here; the first is based on the sample distribution of true exceedance probabilities. The second is a Bayesian analogue using the likelihood function and a noninformative prior to describe the variability of exceedance probabilities. Appropriate analytical solutions are presented in both cases using the partial duration series approach.  相似文献   

Solution chemistry studies and flotation behaviour of apatite,calcite and fluorite minerals with sodium oleate collector     

Robert Pugh  Per Stenius 《International Journal of Mineral Processing》1985,15(3):193-218

The maximum flotation response for three naturally occurring calcium minerals, apatite, calcite and fluorite with sodium oleate collector correlated directly with the minimum interfacial tension of the air/solution interface. For fluorite and apatite the minimum surface tension occurred about the mid-pH region and was attributed to the formation of pre-micellar associated species in solution. In the case of calcite the minimum was observed at high pH since the presence of high concentrations of calcium ions in solution appeared to reduce the concentration of amphililic species in the low and mid-pH regions.Microelectrophoresis data demonstrated that the three minerals acquired a negative charge in sodium oleate solution, resulting from adsorption of oleate species on the mineral surfaces.The flotation behaviour of the systems were shown to be related to the species distribution diagrams suggesting that the role of the acid soap dimer, soap dimer, molecular and lattice species could make a significant contribution to the character and composition of the interfacial films.High flotation response was explained by strong adhesion between the hydrophobic particle and bubble. It was suggested that the reduction in surface tension may not be the major factor contributing to the flotation efficiency but indicated the presence of associated surfactant species in solution which could also synergistically adsorb at the solid/liquid interface, increasing the hydrophobic character of the mineral surface. This would maximize the magnitude of the contact angle and hence the strength of the adhesion between particle and bubble. This adsorption behaviour is not in general agreement with conventionally non-hydrolyzable collector theory which is usually based on electrostatic models.  相似文献   

Tropospheric methane in the mid-latitudes of the Southern Hemisphere     

P. J. Fraser  M. A. K. Khalil  R. A. Rasmussen  L. P. Steele 《Journal of Atmospheric Chemistry》1984,1(2):125-135

Results of more than 800 new measurements of methane (CH₄) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH₄ increased throughout the entire troposphere over the measurement period, adding further support to the view that CH₄ concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH₄ data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements.  相似文献   

Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants,effective surface area,and the hydrolysis of feldspar     

Harold C. Helgeson  William M. Murphy  Per Aagaard 《Geochimica et cosmochimica acta》1984,48(12):2405-2432

Analysis of experimental data reported by Lagache (1965, 1976), Evans (1965), Busenberg (1975), Busenberg and Clemency (1976), Holdren and Berner (1979), Siegel and Pfannkuch (1984), and Chou and Wollast (1984) with the aid of irreversible thermodynamics and transition state theory (Aagaard and Helgeson, 1977, 1982) suggests that at temperatures at least up to 650°C, the rate of both congruent and incongruent feldspar hydrolysis in aqueous solutions far from equilibrium at pH ? 10.6 ? (2300/T), where T stands for temperature in kelvins, is a function solely of effective surface area and pH at constant pressure and temperature. At higher pH, the rate is apparently pH-independent up to ~pH 8 at 25°C, where it again becomes pH-dependent at higher pH. Observations of scanning electron micrographs indicate that the cross-sectional area of etch pits on hydrolyzed feldspar grains is of the order of 10^?9 to 10^?8 cm² and that the ratio of the effective to total surface area (which may or may not change with reaction progress) ranges from <0.01 to 1, depending on the grain size, dislocation density, and the extent of comminution damage on the surfaces of the grains. Apparent rate constants retrieved from experimental data reported in the literature for feldspar hydrolysis in the lower pH-dependent range extend from ~10^?13 to ~10^?7 moles cm^?2 sec^?1 at temperatures from 25° to 200°C, which is consistent with activation enthalpies for albite and adularia of the order of 20 kcal mole^?1. In contrast, the apparent rate constants for the pH-independent rate law range from ~10^?16 to ~10^?11 moles cm^?2 sec^?1 at temperatures from 25° to 650°C, which requires an activation enthalpy for adularia of ~ 9 kcal mole^?1. These observations are consistent with surface control of reaction rates among minerals and aqueous solutions. The rate-limiting step in the pH-dependent case apparently corresponds at the lower end of the pH scale to breakdown of a protonated configuration of atoms on the surface of the reactant feldspar, but at higher pH the rate is limited by decomposition of an activated surface complex corresponding in stoichiometry to hydrous feldspar. In highly alkaline solutions, an activated complex containing hydroxyl ions apparently controls the rate of feldspar hydrolysis. Nevertheless, near equilibrium, regardless of pH the rate is proportional to the chemical affinity of the overall hydrolysis reaction.  相似文献   

The global distribution of methane in the troposphere   总被引：6，自引：0，他引：6  

L. P. Steele  P. J. Fraser  R. A. Rasmussen  M. A. K. Khalil  T. J. Conway  A. J. Crawford  R. H. Gammon  K. A. Masarie  K. W. Thoning 《Journal of Atmospheric Chemistry》1987,5(2):125-171

Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984.  相似文献   

Preface     

Gordon McBean  Erik Rasmussen 《Dynamics of Atmospheres and Oceans》1987,10(4)

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Termites and global methane—another assessment     

P. J. Fraser  R. A. Rasmussen  J. W. Creffield  J. R. French  M. A. K. Khalil 《Journal of Atmospheric Chemistry》1986,4(3):295-310

New CH₄ emission data from a number of Northern and Southern Hemispheric, tropical and temperate termites, are reported, which indicate that the annual global CH₄ source due to termites is probably less than 15 Tg. The major uncertainties in this estimate are identified and found to be substantial. Nevertheless, our results suggest that termites probably account for less than 5% of global CH₄ emissions.  相似文献   

A numerical study of the heat transfer through a fluid layer with recirculating flow between concentric and eccentric spheres     

R. M. Rasmussen  V. Levizzani  H. R. Pruppacher 《Pure and Applied Geophysics》1982,120(4):702-720

A numerical study has been made of the heat transfer through a fluid layer with recirculating flow. The outer fluid surface was assumed to be spherical, while the inner surface consisted of a sphere concentrically or eccentrically located with respect to the outer spherical surface. The recirculating flow was assumed to be driven by a gas flow creating stress on the fluid's outer surface so that creeping (low Reynolds number) flow developed in its interior. The present study solves the Stokes equation of motion and the convective diffusion equation in bispherical coordinates and presents the streamline and isotherm patterns.Nomenclature a _i inner sphere radius - a _d outer sphere radius - A ₁ defined by equation (5) - A ₂ defined by equation (6) - B ₁ defined by equation (7) - B ₂ defined by equation (8) - c dimensional factor for bispherical coordinates - C constant in equation (4) - d narrowest distance between the two eccentric spheres - E ² operator defined by equation (1) in spherical coordinates and by equation (21) in bispherical coordinates - G modified vorticity, defined in equation (22) - G ^* non-dimensional modified vorticity, defined in equation (28) - h metric coefficient of bispherical coordinate system, defined in equation (18) - k _w thermal conductivity of water - K ₁ defined by equation (9) - K ₂ defined by equation (10) - N _Re Reynolds number=2a _dU/gn - N _Pe,h Peclet number=2a _dU/ - n integer counter - q heat flux - r radius - r ^* non-dimensional radius=r/a _d - S surface area - t time - t ^* non-dimensional time=t/a _d ² - T temperature - T _o temperature at inner sphere surface - T _a temperature at outer sphere surface - T ^* non-dimensional temperature;=(T–T _o)/(T_a–T_o) - u velocity - u _r radial velocity in spherical coordinates - u angular velocity in spherical coordinates - u radial velocity in bispherical coordinates - u angular velocity in bispherical coordinates - U free stream velocity - u _r ^* =u _r/U - u ^* =u /U - u ^* =u /U - u ^* =u /U Greek symbols a ₁ small displacement - vorticity, defined in equation (17) - ^* non-dimensional vorticity, defined in equation (27) - radial bispherical coordinates - _o bispherical coordinate of inner sphere - _a bispherical coordinate of outer sphere - angular coordinate in spherical coordinates - thermal diffusivity - _w thermal diffusivity of water - kinematic viscosity - angular bispherical coordinate - spherical coordinate - streamfunction - non-dimensional streamfunction for spherical coordinates, = /(U a _d ² ) - ^* non-dimensional streamfunction for bispherical coordinates, defined in equation (26)  相似文献