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51.
The quantitative significance of organic matter degradation in bringing about the early diagenetic mobility of anthropogenic trace metals (Cu, Zn, Pb) is assessed specifically in relation to the use of estuarine sediments as historical records of pollution. A 1,500 mm salt-marsh sediment depth profile from Tites Point, Severn Estuary, England, was sampled at 10-mm intervals. Organic carbon determinations were carried out by a wet oxidation technique, and ‘organic fraction’ metals were separated by sequential leaching. Results demonstrated that organic phase metals are quantitatively significant in Severn Estuary sediments, particularly Cu and Zn (Cu>Zn), and that metals are probably released from this fraction during early diagenesis. The degree of release, and the apparent loss of the released trace metals from the sediment, would suggest that the use of estuarine sediments as historical records of pollution requires qualification.  相似文献   
52.
A technique for determining the height of the convective atmospheric boundary layer (CBL) with a 915 MHz boundary-layer profiler is discussed. The results are compared with CBL heights determined from radiosonde measurements. The profiler provides continuous CBL height measurements with very good time resolution (30 minutes or less), allowing for detailed understanding of the growth and fluctuations of the CBL. In addition, the profiler provides information about the degree of definition of the CBL top and the thickness of the entrainment zone. The measurements discussed were taken during the Rural Oxidants in the Southern Environment II (ROSE II) experiment.  相似文献   
53.
A regional fluid inclusion study of Cu-Au (+Zn-Pb) mineralisation in the Harlech Dome area, North Wales, gives support to the concept of two distinct metallogenic episodes. The inclusion assemblages associated with the porphyry copper mineralisation at Coed-y-Brenin are consistent with a genetic model of early potassic-propylitic alteration overprinted by later phyllic alteration. High salinity fluids, normally characteristic of potassic alteration, are confined to the host rock quartz. The meteoric/hydrothermal system is closely linked to the emplacement of late-Cambrian diorites. Integrated fluid inclusion and mineralogical studies of the Gold-belt veins suggest that the mineralising fluids were probably dehydration waters released from weakly metamorphosed Cambrian and perhaps Precambrian sediments during hydraulic fracturing in a tensional zone at the close of the Caledonian orogeny. Localisation of economic concentrations of gold in veins at the level of the Clogau Formation is ascribed to a destabilisation of metal complexes caused by a change in fluid buffering from a pyrite-magnetite assemblage in the Lower Cambrian sediments to a pyrite-pyrrhotite-graphite assemblage in the Upper Cambrian sediments. Veining associated with the Coed-y-Brenin porphyry copper deposit and related breccia pipes can be distinguished from the copper-gold veins of the coextensive Dolgellau Gold-belt by the presence in the former of inclusions notably richer in CO2. Furthermore the Gold-belt fluids have a distinctive low CO2/CH4+N2+H2 ratio.  相似文献   
54.
Abstract. WMPLUME is an analytic dispersion model based on the Wilson and Miller equation presented here in a program for the HP-41CV handheld, programmable calculator, the HP-41CX, or the HP-41C with four memory modules. The user specifies the spacing and extent of the field of observation points. The calculator can handle up to 36 fully penetrating, continuous injection well sources or a lesser number of discontinuous wells. The time of observation can be changed easily and sources can be added or deleted readily. The code is prepared for use with or without a printer attached to the calculator.  相似文献   
55.
A new experimental method is introduced for determining the relative magnitudes of liquid and vapor diffusion by using a small amount of soluble chemical as a tracer. The theoretical justification of the method is presented for the case where ice is absent. The feasibility of the method is demonstrated by an experiment using marine-deposited clay.  相似文献   
56.
Taxon calibrations based on eastern North America or on the southeastern United States alone suggest a different forest composition from that based on Wisconsin/Michigan, which is argued as preferable. Questions are raised about how well comparison with modern analogues distinguishes forest characteristics. The simulation model used by Delcourt and Delcourt is thought to be inappropriate, partly because it is constrained by faulty climatic data. Models are seen as complementary to other techniques rather than as an alternative methodology.  相似文献   
57.
Dan H. Allen 《Ground water》1986,24(6):791-797
Abstract. Hantush (1967) provided time-dependent equations for describing ground-water mounds resulting from axisymmetric recharge. Because these equations contain the well function, they cannot be solved explicitly for the several variables employed in terms of the known mound height. Newton's method provides a means to achieve solutions for specific yield, hydraulic conductivity, time, or radius. An additional routine is provided which searches for the second solution in the case in which the inverse solution for hydraulic conductivity is doublevalued. The iterations can be performed on an HP-41C handheld calculator with three memory modules. The code is provided and will run with or without the printer attached.  相似文献   
58.
On February 8, 1993, the NASA DC-8 aircraft profiled from 10,000 to 37,000 feet (3.1–11.3 km) pressure altitude in a stratified section of tropical cyclone “Oliver” over the Coral Sea northeast of Australia. Size, shape and phase of cloud and precipitation particles were measured with a 2-D Greyscale probe. Cloud/ precipitation particles changed from liquid to ice as soon as the freezing level was reached near 17,000 feet (5.2 km) pressure altitude. The cloud was completely glaciated at −5°C. There was no correlation between ice particle habit and ambient temperature. In the liquid phase, the precipitation-cloud drop concentration was 4.0 × 103 m−3, the geometric mean diameter Dg=0.5−0.7 mm, and the liquid water content 0.7−1.9 g m−3. The largest particles anywhere in the cloud, dominated by fused dendrites at concentrations similar to that of raindrops (2.5 × 103 m−3) but a higher condensed water content (5.4 g m−3 estimated) were found in the mixed phase; condensed water is removed very effectively from the mixed layer due to high settling velocities of the large mixed particles. The highest number concentration (4.9 × 104 m−3), smallest size (Dg=0.3−0.4 mm), largest surface area (up to 2.6 × 102 cm2 m−3 at 0.4−1.0 g m−3 of condensate) existed in the ice phase at the coldest temperature (−40°C) at 35,000 feet (10.7 km). Each cloud contained aerosol (haze particles) in addition to cloud particles. The aerosol total surface area exceeded that of the cirrus particles at the coldest temperature. Thus, aerosols must play a significant role in the upscattering of solar radiation. Light extinction (6.2 km−1) and backscatter (0.8 sr−1 km−1) was highest in the coldest portion of the cirrus cloud at the highest altitude.  相似文献   
59.
60.
A new experimental method for measuring the soil-water diffusivity of frozen soil under isothermal conditions is introduced. The theoretical justification of the method is presented and the feasibility of the method is demonstrated by experiments conducted using marine deposited clay. The measured values of the soil-water diffusivity are found comparable to reported experimental data.  相似文献   
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