Growth-maturation interactions of Acadian redfish (Sebastes fasciatus Storer) in the Gulf of Maine-Georges Bank region of the Northwest Atlantic     

Mayo  R. K.; Burnett  J.; Smith  T. D.; Muchant  C. A. 《ICES Journal of Marine Science》1990,46(3):287-305

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Excess protactinium in phosphate nodules from a coastal upwelling zone     

K.K. Roe  W.C. Burnett  K.H. Kim  M.J. Beers 《Earth and Planetary Science Letters》1982,60(1):39-46

Measurements of²³¹Pa/²³⁵U and²³⁰Th/²³⁴U activity ratios have been made for a suite of Quaternary age phosphate nodules from the upwelling zone off Peru and Chile. Many of these samples contain more²³¹Pa than would be predicted based on closed-system²³⁰Th/²³⁴U ages unlike samples from non-upwelling environments which have been shown to have concordant²³¹Pa and²³⁰Th ages. Peru/Chile phosphate nodules apparently pick up²³¹Pa preferentially to²³⁰Th. This is most likely a result of prior fractionation of protactinium and thorium in the open ocean. Highly productive coastal upwelling zones may be added to the growing list of localities where fractionation between thorium and protactinium isotopes has been observed in marine sediments.  相似文献   

Engineering properties and slope stability of lower coal measures rocks from monk wood cutting,Unstone-Dronfield by-pass,Derbyshire     

D.S. Buist  A.D. Burnett  M.K. Sanders 《Engineering Geology》1979,14(1):11-28

This 30 m deep cutting has been the subject of a detailed geotechnical analysis, in view of mass-sliding wedge failures which had occurred in cuttings in similar geological situations in other parts of Britain.The sequence of rocks includes two coal seams, the upper being thin (0.3 m) and the lower thick (2 m), the latter with a recognisable seatearth (underclay). There is a thick sandstone at the top of the succession, with siltstone, mudstone and black mudstone also present.Both field and laboratory testing was carried out. The most probable failure mechanism within the more competent sandstone sequence to the south of the site would probably have been in the form of wedge failures on pre-existing discontinuities within the rock mass. It was necessary to evaluate the shear strength which could be mobilised along these planes and a field rock shear box was used. Drained-soil shear tests were also made on potential failure-surface materials, namely seatearth and clay shear zones. Weathered mudstone samples were tested to provide design parameters for the analysis of rotational slips. Additional laboratory testing carried out comprised bulk density, classification tests, slake durability and point-load indices. X-ray diffraction analyses were made on a range of materials such as seatearth, mudstone, shear zone and sandstone bedding-plane shear surface. This extensive test programme enabled parameters to be accurately determined for use in stability analyses. The latter show the critical effects of water conditions on the factor of safety.The performance of the cut has been monitored since early 1974 and no recordable movement has been noted.  相似文献   

Laboratory actinide partitioning: Whitlockite/liquid and influence of actinide concentration levels     

T.M. Benjamin  J.H. Jones  W.R. Heuser  D.S. Burnett 《Geochimica et cosmochimica acta》1983,47(10):1695-1705

Fission and alpha track radiography techniques have been used to measure partition coefficients (D) at trace (ppm) concentration levels for the actinide elements Th, U, and Pu between synthetic whitlockite and coexisting “haplobasaltic” silicate liquid at 1 bar pressure and 1250°C at oxygen fugacities from 10^?8.5 and 10^?0.7 bars. Pu is much more readily incorporated into crystalline phases than is U or Th under reducing conditions (fO₂ = 10^?8.5), because Pu is primarily trivalent, whereas U and Th are tetravalent. Definitive valence state assignments cannot be made, but our best estimates of corrected partition coefficients for Pu⁺³, Pu⁺⁴, Th⁺⁴, U⁺⁴, and U⁺⁶ are, for whitlockite 3.6/<?0.6/1.2/0.5/?0.002. The effect of changing pressure and liquidus temperature is relatively small, which probably reflects a weak temperature dependence for D (whitlockite) but possibly could be due to cancellation of opposing temperature and pressure effects. Comparison of experiments at trace U levels with those containing percent concentrations of UO₂ indicate that Si is involved in the substitution of U in whitlockite with U + 2Si ? Ca + 2P being the most likely mechanism. D_u is lower. 0.3 vs 0.5. at percent levels compared to 20 ppm. This is best explained by the effect of U on melt structure or by a decrease in the fraction of tetravalent U at high U concentrations.  相似文献   

Amino acid biogeochemistry and dating of offshore Peru/Chile phosphorites     

Robert Cunningham  William C. Burnett 《Geochimica et cosmochimica acta》1985,49(6):1413-1419

Amino acid biogeochemical results for a suite of indurated sea-floor phosphate nodules from the Peru/Chile margin confirm the youthful nature of these deposits as previously indicated by uranium-series disequilibrium dating. Isoleucine epimerization is significant in the hydrolyzed acid soluble fraction of the nodules with a range in the D-alloisoleucine/L-isoleucine ratio from 0.06 to 0.32. Amino acid compositional patterns are uniform for all nodules and are similar to unlithified surface sediments from the region suggesting that the nodules and sediments constitute a single genetic series.  相似文献   

Further studies of the nature,composition and ages of contemporary phosphorite from the Namibian Shelf     

J. Thomson  S.E. Calvert  S. Mukherjee  W.C. Burnett  J.M. Bremner 《Earth and Planetary Science Letters》1984,69(2):341-353

Major and minor element and radiochemical data are examined for a set of phosphorite concretions and other phosphatic material from the Namibian Shelf. The concretions were separated on a morphological basis from grab samples taken in a transect of shallowing depth over the diatomaceous ooze belt. Compositional data indicate that the samples are fairly pure carbonate-fluorapatite, and trend towards a maximum 32% P₂O₅ content. A range of compositional variability similar to other samples from the Namibian Shelf is observed.Radiochemical systematics confirm that pelletal phosphorite and glauconitized pelletal phosphorite from depths > 170 m are at radioactive equilibrium, and are therefore old and reworked. The concretions, collected from depths shallower than 78 m, are entirely Recent, with maximum ages in the range 500–3800 years. They may be much younger. Despite distinct textural and small compositional differences, similar ages are found for separates from the same grab. Samples of fish scales and an unidentified high-magnesian phosphate mineral are also shown to have incorporated uranium recently.  相似文献   

Reduction in organic contaminant exposure and resultant hepatic hydropic vacuolation in winter flounder (Pseudopleuronectes americanus) following improved effluent quality and relocation of the Boston sewage outfall into Massachusetts Bay, USA: 1987-2003     

Moore M  Lefkovitz L  Hall M  Hillman R  Mitchell D  Burnett J 《Marine pollution bulletin》2005,50(2):156-166

Effluent upgrades for metropolitan Boston have included toxicant reduction, primary and secondary treatment and outfall extension. Between 1992 and 2003 winter flounder at five stations were surveyed annually for liver and muscle burden and chronic hepatic sub-lethal impacts of polynuclear and halogenated aromatic hydrocarbons, and metals. Trends in flounder availability and fin condition were also examined. In 1988 12% of the adult winter flounder in Boston Harbor exhibited hepatic neoplasms and up to 80% had hepatic hydropic vacuolation (HV). Tumor prevalence fell to 0-2% and HV to <50% by 1996. Since then tumors have been absent, while a steady prevalence of HV has persisted, consistent with lower hydrocarbon loading and tissue levels. Contaminants and HV also fell with distance from the Boston outfall. After the outfall extension was activated in 2000, there has been no significant change in flounder liver health at the new outfall site.  相似文献   

The effect of pH and ionic strength on proton adsorption by the thermophilic bacterium Anoxybacillus flavithermus     

Peta-Gaye Burnett  Hannah Heinrich  Phil J. Bremer  Christopher J. Daughney 《Geochimica et cosmochimica acta》2006,70(8):1914-1927

Numerous studies have utilized surface complexation theory to model proton adsorption behaviour onto mesophilic bacteria. However, few experiments, to date, have investigated the effects of pH and ionic strength on proton interactions with thermophilic bacteria. In this study, we characterize proton adsorption by the thermophile Anoxybacillus flavithermus by performing acid-base titrations and electrophoretic mobility measurements in NaNO₃ (0.001-0.1 M). Equilibrium thermodynamics (Donnan model) were applied to describe the specific chemical reactions that occur at the water-bacteria interface. Acid-base titrations were used to determine deprotonation constants and site concentrations for the important cell wall functional groups, while electrophoretic mobility data were used to further constrain the model. We observe that with increasing pH and ionic strength, the buffering capacity increases and the electrophoretic mobility decreases. We develop a single surface complexation model to describe proton interactions with the cells, both as a function of pH and ionic strength. Based on the model, the acid-base properties of the cell wall of A. flavithermus can best be characterized by invoking three distinct types of cell wall functional groups, with pK_a values of 4.94, 6.85, and 7.85, and site concentrations of 5.33, 1.79, and 1.42 × 10⁻⁴ moles per gram of dry bacteria, respectively. A. flavithermus imparts less buffering capacity than pure mesophilic bacteria studied to date because the thermophile possesses a lower total site density (8.54 × 10⁻⁴ moles per dry gram bacteria).  相似文献   

Cd adsorption onto Anoxybacillus flavithermus: Surface complexation modeling and spectroscopic investigations     

Peta-Gaye G. Burnett  Christopher J. Daughney 《Geochimica et cosmochimica acta》2006,70(21):5253-5269

Several recent studies have applied surface complexation theory to model metal adsorption behaviour onto mesophilic bacteria. However, no investigations have used this approach to characterise metal adsorption by thermophilic bacteria. In this study, we perform batch adsorption experiments to quantify cadmium adsorption onto the thermophile Anoxybacillus flavithermus. Surface complexation models (incorporating the Donnan electrostatic model) are developed to determine stability constants corresponding to specific adsorption reactions. Adsorption reactions and stoichiometries are constrained using spectroscopic techniques (XANES, EXAFS, and ATR-FTIR). The results indicate that the Cd adsorption behaviour of A. flavithermus is similar to that of other mesophilic bacteria. At high bacteria-to-Cd ratios, Cd adsorption occurs by formation of a 1:1 complex with deprotonated cell wall carboxyl functional groups. At lower bacteria-to-Cd ratios, a second adsorption mechanism occurs at pH > 7, which may correspond to the formation of a Cd-phosphoryl, CdOH-carboxyl, or CdOH-phosphoryl surface complex. X-ray absorption spectroscopic investigations confirm the formation of the 1:1 Cd-carboxyl surface complex, but due to the bacteria-to-Cd ratio used in these experiments, other complexation mechanism(s) could not be unequivocally resolved by the spectroscopic data.  相似文献   

Does the Social Capital in Networks of “Fish and Fire” Scientists and Managers Suggest Learning?     

A. Paige Fischer  Ken Vance-Borland  Kelly M. Burnett  S. Hummel  Janean H. Creighton  Sherri L. Johnson 《社会与自然资源》2014,27(7):671-688

Patterns of social interaction influence how knowledge is generated, communicated, and applied. Theories of social capital and organizational learning suggest that interactions within disciplinary or functional groups foster communication of knowledge, whereas interactions across groups foster generation of new knowledge. We used social network analysis to examine patterns of social interaction reported in survey data from scientists and managers who work on fish and fire issues. We found that few fish and fire scientists and managers interact with one another, suggesting low bridging social capital and thus, limited opportunity for generation of new knowledge. We also found that although interaction occurs among scientists—suggesting modest bonding social capital—few managers interact with other managers, indicating limited opportunity for communication of scientific knowledge for the purposes of application. We discuss constraints and opportunities for organizational learning evident in these patterns of social interaction among fish and fire scientists and managers.  相似文献