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121.
Two different contamination processes have been identified as having been operative in the genesis of a plutonic suite: initial contamination of a mantle source, and subsequent crustal contamination of uprising partial melts from the mantle. These processes are indicated by a detailed analyses of Nd, Sr, and oxygen isotopes together with major-and trace-elements of the 32–30 Ma calc-alkaline Bergell intrusion. This intrusion is located at the suture of the Alpine continental collision zone and contains rock types capable of discriminating between mantle and intracrustal processes. A range from basaltic-andesitic dykes in the surrounding country rocks, cumulitic hornblendites, gabbros, tonalite, granodiorite and lamprophyres, to pegmatites and aplites, is exposed in this single intrusion. The results of REE modelling and isotopic compositions of the basic members suggest that the cumulates were fractionated from a picrobasaltic liquid originating by partial melting of enriched subcontinental mantle (Nd=+4). Increases in 87Sr/86Sr (0.7055) and 18O(+6.7) in these samples relative to the mantle array and compositions of other Periadriatic intrusions are most likely the result of an initial contamination of the mantle source by dehydration or partial melting of altered subducted oceanic crust. Slight differentiation of such a picrobasaltic liquid produced the basaltic-andesitic dykes. Simultaneous fractional crystallization and contamination of the uprising magma by continental crust produced crustal isotopic signatures which increase with acidity to values of (Nd=-7.6), 87Sr/86Sr=0.716 and 18O=+10. The crustal imprint and LREE enrichment in the dominating tonalite increase with decreasing crystallization depth which indicates that the tonalites were emplaced in several distinct batches with different degrees of contamination. Shoshonitic lamprophyres, which intruded into the partly solidified granodiorite, were generated in a deep, strongly contaminated mantle source. The posttectonic 26 Ma Novate leucogranite is not cogenetic with the main Bergell body, but rather formed from a predominantly crustal source. If the described features are indeed due to mantle source contamination processes, which are well known for volcanic arcs, it must be concluded that these may also play a significant role in the genesis of calcalkaline plutonic suites.  相似文献   
122.
Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5–19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary 18O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in 18O. Initial 87Sr/86Sr ratios (0.705 to 0.708), 18O values (-2 to-7), and 206Pb/204Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial 87Sr/86Sr and 206Pb/204Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial 87Sr/86Sr and 206Pb/204Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (25 Ma) and Rio Hondo (21 Ma) plutons have relatively homogeneous initial 87Sr/86Sr and 206Pb/204Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. 18O values for all the postcaldera plutons overlap those of the precaldera rocks and Amalia Tuff, except for those for two late-stage rhyolite dikes associated with the Rio Hondo pluton that have 18O values of-8.6 and-9.5; these dikes are the only Latir rocks which may be largely crustal melts.Chemical and isotopic data from the Latir field suggest that large fluxes of mantle-derived basaltic magma are necessary for developing and sustaining large-volume volcanic centers. Development of a detailed model suggests that 6–15 km of new crust may have been added beneath the volcanic center; such an addition may result in significant changes in the chemical and Sr and Nd isotopic compositions of the crust, although Pb isotope ratios will remain relatively unchanged. If accompanied by assimilation, crystallization of pooled basaltic magma near the MOHO may produce substantial cumulates beneath the MOHO that generate large changes in the isotopic composition of the upper mantle. The Latir field may be similar to other large-volume, long-lived intracratonal volcanic fields that fundamentally owe their origins to extensive injection of basaltic magma into the lower parts of their magmatic systems. Such fields may overlie areas of significant crustal growth and hybridization.  相似文献   
123.
124.
In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH4, NH3, and H2S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6RJ from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.  相似文献   
125.
Identical equations of motion are shown to emerge for a system ofn+1 rigid bodies all interconnected byn points, each of which is common to two bodies, by means of each of the following derivation procedures, all of which employ a kinematical identity developed by Hooker and Margulies: The Hooker-Margulies/Hooker equations; Kane's quasicoordinate formulation of D'Alembert's principle; the combination of Lagrange's generalized coordinate equations and Lagrange's quasicoordinate equations; and the combination of Lagrange's generalized coordinate equations and the vector rotational equationM=H applied to the total system and resolved into a vector basis fixed in a reference body of the system. Thus the previously published Hooker-Margulies/Hooker equations are shown to be the natural result of several derivation procedures other than the Newton-Euler method originally used, provided that the central kinematical identity of the original derivation of Hooker and Margulies is employed.  相似文献   
126.
A new approach is proposed for incorporating solid solution reactions into mass conservation equations describing reaction paths in both closed and open systems. The method is applicable to problems involving advective, dispersive, and diffusive transport in a porous medium. By representing the continuously variable solid solution composition with a discrete set of stoichiometric solids that span composition space, combined with a kinetic formulation of their rates of reaction, a self-determining spatial and temporal evolution of the solid solution concentration and composition is obtained. It is demonstrated that equilibrium of an aqueous solution with a stoichiometric solid derived from a solid solution corresponds to equilibrium of the solid solution itself if and only if equilibrium of the stoichiometric solid is stable. One advantage of this approach is that it is unnecessary to introduce any additional compositional variables to represent the solid solution. Discretization may be over the entire range of composition space, or over some subset depending on the system. A major consequence of the kinetic discrete-composition solid solution representation is that modeling solid solutions is similar to modeling pure mineral phases with the exception of a weighting factor applied to reaction rates of stoichiometric solids corresponding to a common solid solution. With this approach, precipitation leads to a discrete zonation of the solid solution that approximates the continuous variation in composition expected for the actual solid solution. The approach is demonstrated for a hypothetical ideal and non-ideal binary solid solution AxB1−xC for a reaction path formulation and reactive transport involving advection and diffusion.  相似文献   
127.
A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).  相似文献   
128.
Editorial     
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130.
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.  相似文献   
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