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891.
The main sediment depocenter along the Oman margin is the Al Batha turbidite system that develops in the Gulf of Oman basin. It is directly connected to the wadi Al Batha, and forms a typical sand and mud rich point source system that acts as regional sediment conduit and feeds a ~ 1000 km2 sandy lobe.The Al Batha lobe depositional architecture has been investigated in detail using very high-resolution seismic, multibeam echosounder data and sediment cores. Several scales of depositional architecture can be observed. The Al Batha lobe is composed of several depositional units, made of stacked elementary sediment bodies (thinner than 5 m) that are each related to a single flow event. The lobe is connected to the feeder system through a channel-lobe transition zone (CLTZ) that extends on more than 25 km. The lobe can be divided into proximal, middle and distal lobe areas. The proximal lobe is an area of erosion and by-pass with small axial feeder channels that rapidly splay into several small distributaries. They disappear in the mid-lobe area where deposits consist of vertically stacked tabular to lens-shaped sediment bodies, with a lateral continuity that can exceed 10 km. The distal lobe fringe shows a classical facies transition towards thin-bedded basin plain deposits.Sub-surface deposits consist of sandy turbidites and hyperpycnites, interbedded with fine-grained deposits (thin turbidites, hyperpycnites, or hemipelagites). Although these distal deposits are mainly related to flow transformations and concentration evolution, they highlight the importance of flooding of the wadi Al Batha on the sediment transfer to the deep basin. The thick sandy hyperpycnites recovered in such a distal area are also possibly related to the initial properties of gravity flows, in relation to the flooding characteristics of mountainous desert streams.Finally, the Al Batha lobe depositional architecture is typical of sand-rich lobes found within “small”, sand and mud rich turbidite systems fed by mountainous “dirty” rivers. Turbidite sedimentation in the Al Batha system appears to be primarily controlled by the strong climatic and geomorphic forcing parameters (i.e. semi-arid environment with ephemeral, mountainous rivers subjected to flash-flooding).  相似文献   
892.
In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.  相似文献   
893.
Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
Sample Chemical composition S o/(J mol−1 K−1)
K-jarosite K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 427.4 ± 0.7
Na-jarosite Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 436.4 ± 4.4
Rb-jarosite RbFe2.98(SO4)2(OH)5.95(H2O)0.05 411.9 ± 4.1
NH4-jarosite (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 447.2 ± 4.5
Defect jarosite K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 412.7 ± 4.1
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T C p was fit with the expression C p = γT + ΣB j T j , where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C p. Surprisingly, the C p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below their Néel transition temperature.  相似文献   
894.
A simplest equation within the framework of the Mie-Grüneisen–Einstein approach is considered. Pressure estimation values are presented that are derived by conventional arithmetic and algebraic calculations as a function of temperature and volume. The equation under consideration complies with the Mie-Grüneisen–Debye model at high temperature. Different versions of an equation of state (EoS) of MgO proposed by Speziale et al. (J Geophys Res 106B:515–528, 2001) as a pressure standard at high temperatures are subject to analyses. In the literature, at least four versions of Speziale et al. EoS of MgO are discussed; the discrepancy between them reaching a few GPa at T > 2,000 K and P > 100 GPa. Our analyses of these equations suggest that the volume dependence of the Debye temperature is accepted arbitrarily and does not agree with the definition of the Grüneisen parameter, γ = −(∂lnΘ/∂lnV) T . Pressure as a function of temperature and volume in the Mie-Grüneisen–Einstein approach or the Gao pressure calculator can be used to estimate true pressure at compression x = V/V 0 < 1 with the Speziale et al. EoS of MgO.  相似文献   
895.
In this paper, central elements of the Solar Shield project, launched to design and establish an experimental system capable of forecasting the space weather effects on high-voltage power transmission system, are described. It will be shown how Sun–Earth system data and models hosted at the Community Coordinated Modeling Center (CCMC) are used to generate two-level magnetohydrodynamics-based forecasts providing 1–2 day and 30–60 min lead-times. The Electric Power Research Institute (EPRI) represents the end-user, the power transmission industry, in the project. EPRI integrates the forecast products to an online display tool providing information about space weather conditions to the member power utilities. EPRI also evaluates the economic impacts of severe storms on power transmission systems. The economic analysis will quantify the economic value of the generated forecasting system. The first version of the two-level forecasting system is currently running in real-time at CCMC. An initial analysis of the system’s capabilities has been completed, and further analysis is being carried out to optimize the performance of the system. Although the initial results are encouraging, definite conclusions about system’s performance can be given only after more extensive analysis, and implementation of an automatic evaluation process using forecasted and observed geomagnetically induced currents from different nodes of the North American power transmission system. The final output of the Solar Shield will be a recommendation for an optimal forecasting system that may be transitioned into space weather operations.  相似文献   
896.
Ultramafic–mafic- and ultramafic-hosted Cu (Co, Ni, Au) volcanogenic massive sulfide (VMS) deposits from ophiolite complexes of the Main Uralian Fault, Southern Urals, are associated with island arc-type igneous rocks. Trace element analyses show that these rocks are geochemically analogous to Early Devonian boninitic and island arc tholeiitic rocks found at the base of the adjacent Magnitogorsk volcanic arc system, while they are distinguished both from earlier, pre-subduction volcanic rocks and from later volcanic products that were erupted in progressively more internal arc settings. The correlation between the sulfide host-rocks and the earliest volcanic units of the Magnitogorsk arc suggests a connection between VMS formation and infant subduction-driven intraoceanic magmatism.  相似文献   
897.
In recent years, debris flows have represented a severe natural hazard in South-Gargano watersheds (Puglia Region, Southern Italy). Hill slopes erosion, caused by the inadequate protection of the degraded forests, produces large amounts of soil and debris that are conveyed downstream during heavy rainstorms. The involved material is characterized by limestone fragments and blocks in a sandy-silt matrix. In this paper, the rheological properties of such debris-flow materials have been investigated. Eight specimens of particulated sediments of particle diameter of d ≤ 4 mm have been analysed using a rheometric tool for large particle suspensions, the ball measuring system (BMS). The influence of sediment concentration on the bulk rheological behaviour has been evaluated at concentrations by volume obtained in fully water-saturated conditions (volumetric sediment concentration C V ~ 0.8) and with fixed water content (C V = 0.42). The rheological data were fitted to the Bingham, Herschel–Bulkley, and O’Brien and Julien models to define viscosity and yield stress dependency on sediment concentration, to provide viscosity information for hazard mitigation as well as for comparison to other debris-flow events.  相似文献   
898.
899.
In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations (PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method.  相似文献   
900.
A numerical groundwater model of the Nubian Aquifer System was established to prove the influence of rising seawater levels on the groundwater salinity in northern Egypt over the last 140,000 years. In addition, the impact of a groundwater recharge scenario for these 140,000 years, involving climatic change, on the saltwater/freshwater interface was investigated. Saltwater intrusion induced by rising water levels of the Mediterranean Sea led to salinisation from the Mediterranean Sea to the Qattara depression. This modeling approach was supported by a density-driven model setup and calculation. The modelled saltwater/freshwater interfaces partially fitted the observed ones, especially in the southern half of the Qattara depression. In other parts of the northern Nubian Aquifer System, the ingression of salt water was modelled adequately, but in the west, small regions of the measured interface were not. The development in the Qattara depression (Egypt) and Sirte basin (Libya) were investigated in more detail. The different behaviour in the Sirte basin may be due to high evapotranspiration rates in some former periods, salt solutions from the pre-Quaternary layers or saltwater infiltration from sabkha-like recent salt-bearing sediments.  相似文献   
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