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21.
New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.  相似文献   
22.
The development of biorefineries is the key for access to an integrated production of food, feed, chemicals, materials, goods, fuels and energy of the future. This communication considers an integrated green biorefinery combined with today's production of feed in the green agriculture. Special attention is given to the combination of physical and biotechnological processes for the production of proteins as well as platform chemicals such as lactic acid and lysine. Mass and energy flows (steam and electricity) are given for the biorefining of green biomass to produce platform chemicals, proteins, feed and biogas from residues.  相似文献   
23.
Durbachites–Vaugnerites are K–Mg‐rich magmatic rocks derived from an enriched mantle source. Observed throughout the European Variscan basement, their present‐day geographical distribution does not reveal any obvious plate‐tectonic context. Published geochronological data show that most durbachites–vaugnerites formed around 335–340 Ma. Plotted in a Visean plate‐tectonic reconstruction, the occurrences of durbachites–vaugnerites are concentrated in a hotspot like cluster in the Galatian superterrane, featuring a distinctive regional magmatic province. Reviewing the existing local studies on Variscan durbachite–vaugnerite rocks, we interpret their extensive appearance in the Visean in terms of two factors: (i) long‐term mantle enrichment above early Variscan subduction systems; and (ii) melting of this enriched subcontinental mantle source during the Variscan collision stage due to thermal anomalies below the Galatian superterrane, possibly created by slab windows and and/or the sinking of the subducted Rheic slab into the mantle. The tectonic reorganization of Europe in the Late Palaeozoic and during the Alpine orogeny has torn apart and blurred this marked domain of durbachites–vaugnerites.  相似文献   
24.
25.
Investigations of fluid inclusions in granulitefacies metapelites of southern Calabria enable characterization of the fluid composition of these lower crustal rocks, and constrain the petrologically deduced retrograde P-T path characterized by isothermal uplift prior to isobaric cooling in middle crustal levels. Fluid inclusions in cordierite, garnet and sillimanite have a CO2-rich composition. Inclusions in cordierite rarely contain minor amounts of N2 and H2O, and in garnets some CO2–CH4–N2 inclusions have been analyzed by Raman microprobe. Quartz reveals the most complex fluid melusion compositions (1) CO2-rich, (2) CO2–CH4–N2, (3) CH4–N2, (4) H2O–MgCl2–CaCl2–NaCl, (5) H2O–NaCl and (6) H2O–CO2. The earliest fluid inclusions after peak metamorphism are rich in CO2 with minor amounts of N2 and H2O. An early CO2–(H2O–N2) fluid composition has been confirmed by detection of CO2, H2O and N2 in the channels of the cordierite structure. Most of the early CO2-rich fluid inclusions were modified during the uplift from the lower to the middle crustal level, resulting in a density decrease with CO2 still dominant. The subsequent isobaric cooling led to further modifications of the fluid inclusions. High-density inclusions around implosion textures or scattered amongst lower-density ones must have formed during this cooling episode. Aqueous inclusions in quartz are mostly formed late and are consistent with trapping during retrograde rehydration.This project has been supported by the DFG as contribution to the special program Continental Lower Crust  相似文献   
26.
Calcareous fens are unique environments whose history is almost unexplored. The radiocarbon dates of the basal layers of 49 undisturbed calcareous fens showed that in the Western Carpathians (central Europe) many of the extant fen sites originated fairly recently, with two peaks in the High Middle and Roman Ages, the former corresponding to human‐induced changes of the landscape. Conspicuous number of fens also appeared in the Lateglacial and later in the Bronze Age owing to suitable environmental conditions. The Lateglacial calcareous fens were of semi‐open character with coniferous trees, a heliophilous understorey, and mollusc communities composed of several snail species typical of glacial landscapes. We found wood of Taxus baccata in six localities between 7390 and 600 cal. a BP, suggesting that calcareous fens could have represented a refugial habitat for this red‐listed species during the middle Holocene. Using plant macrofossil and mollusc analyses of three representative profiles we illustrate the most common developmental types: (i) fens originating in the Lateglacial, having an open or semi‐open character during the whole Holocene; (ii) open fens originating as wooded wetlands; and (iii) open fens starting their development de novo in the late Holocene. Human activities were responsible for the formation of a high number of calcareous fens, especially in the Outer Western Carpathians, and became important drivers of fen biodiversity development. Only a few recently existing calcareous fens contain old sequences of calcareous deposits. They represent unique natural archives and harbour highly endangered relic populations of fen specialists, making their strict protection urgent.  相似文献   
27.
The main goal of this study is to determine the oceanic regions corresponding to variability in African rainfall and seasonal differences in the atmospheric teleconnections. Canonical correlation analysis (CCA) has been applied in order to extract the dominant patterns of linear covariability. An ensemble of six simulations with the global atmospheric general circulation model ECHAM4, forced with observed sea surface temperatures (SSTs) and sea ice boundary variability, is used in order to focus on the SST-related part of African rainfall variability. Our main finding is that the boreal summer rainfall (June–September mean) over Africa is more affected by SST changes than in boreal winter (December–March mean). In winter, there is a highly significant link between tropical African rainfall and Indian Ocean and eastern tropical Pacific SST anomalies, which is closely related to El Niño-Southern Oscillation (ENSO). However, long-term changes are found to be associated with SST changes in the Indian and tropical Atlantic Oceans, thus, showing that the tropical Atlantic plays a critical role in determining the position of the intertropical convergence zone (ITCZ). Since ENSO is less in summer, the tropical Pacific and the Indian Oceans are less important for African rainfall. The African summer monsoon is strongly influenced by SST variations in the Gulf of Guinea, with a response of opposite sign over the Sahelian zone and the Guinean coast region. SST changes in the subtropical and extratropical oceans mostly take place on decadal time scales and are responsible for low-frequency rainfall fluctuations over West Africa. The modelled teleconnections are highly consistent with the observations. The agreement for most of the teleconnection patterns is remarkable and suggests that the modelled rainfall anomalies serve as suitable predictors for the observed changes.  相似文献   
28.
The article evaluates the water quality in rural areas in the Czech part of Labe River catchment using the example of Slapanka River catchment. This river drains a typical landscape of Ceskomoravska Highland. Water quality in rural areas is still very low and the attention is paid to organic substances and nutrients. Increased amount of them in streams is caused mainly by agriculture and production of municipal wastewater resulting in increased eutrophication. A significant part of the article consists in the evaluation of point and non-point sources of water pollution. Identifying the type of the pollution source is helped by regression analysis using data from the public monitoring network. Eleven sampling sites were selected for evaluating the water quality. Physical and chemical analyses were made 12 times during the field monitoring in the years 2001–2003.In long-term development water quality has improved in all monitored parameters during the last 15 years. Least significant improvement has been found with the concentration of nitrate nitrogen. The water quality within the whole catchment area still remains low.To reduce the influence of pollution sources, we recommend the sanitation of diffuse sources of pollution from small settlements with less than 2000 inhabitants, and a successive change from agricultural management and intensive mass production to extensive ways, especially in mountain and sub-mountain areas.  相似文献   
29.
The forest succession model FORSKA was applied to a west-east transect across Central Europe using points from a global climate data set. Climate change experiments were undertaken for two general circulation model scenarios and two different site classes. The simulated climate changes lead to reduced forest productivity and a changed species composition on most sites. Under current climate, the broad scale pattern of the climatically driven distribution of forest communities is quite realistically reproduced. However, the resolution of climate data imposes limitations on the simulation of forest dynamics in subcontinental climate, because climate variability and extreme events are not well represented.  相似文献   
30.
A new assessment system for macrophytes and phytobenthos in German rivers meeting the requirements of the Water Framework Directive (WFD) of the European Community is described. Biocoenotic types based on biological, chemical and hydromorphological data from over 200 river sites covering the main ecoregions, hydromorphological stream types and degradation forms have been defined. For developing a classification system the quality element macrophytes and phytobenthos was divided into three components: macrophytes, benthic diatoms and remaining phytobenthos. For macrophytes seven types including one subtype, for benthic diatoms 14 types including three subtypes and for the remaining phytobenthos five river types were identified. The benthic vegetation at reference condition was described for most of the river types. Degradation is characterised as deviation in benthic vegetation species composition and abundance from the reference biocoenosis. For classification in five ecological status classes, several metrics were developed and used in combination with existing indices. For some of the described river types additional investigations are necessary before a classification system can be developed.  相似文献   
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