Investigation of the accelerated carbonation of a MgO-based binder used to treat contaminated sediment     

Hoang Q. H. Phan  Kyung-Yup Hwang  Jun-Young Ahn  Tae Yoo Kim  Cheolyong Kim  Inseong Hwang 《Environmental Earth Sciences》2017,76(22):771

A MgO-based binder developed to simultaneously solidify/stabilize contaminated sediment and store CO₂ has been described previously. The objectives of the study presented here were to investigate the kinetics of the carbonation reactions of the binder and the extent to which carbonation occurred and to identify the optimal conditions for using the binder. The carbonation reaction was clearly faster and the degree of carbonation higher at CO₂ concentrations of 50 and 100% than in the ambient atmosphere (which contains 0.04% CO₂). A modified unreactive core model adequately described the kinetics. The rate constants were 0.0217–0.319 h^?1 and were proportional to the degree of carbonation. A high degree of carbonation, 93.8%, was achieved at a CO₂ concentration of 100%. The water to sediment ratio strongly affected carbonation, the optimal ratio being around 0.7. The relative humidity did not strongly affect the carbonation performance. The carbonation products were magnesite (MgCO₃) and nesquehonite (MgCO₃·3H₂O). X-ray diffraction analysis showed that brucite (Mg(OH)₂) was not present, suggesting that brucite was very quickly transformed into magnesium carbonates, the presence of which was confirmed by thermal gravimetric analysis. The results indicated that, in 7 d, 1 kg of binder could sequester up to 0.507 kg of CO₂ in a 100% CO₂ atmosphere. The results indicate that the MgO-based binder has great potential to be used to sequester CO₂ under accelerated carbonation conditions.  相似文献   

Cluster Observes the High-Altitude CUSP Region     

B. Lavraud  H. Rème  M. W. Dunlop  J. -M. Bosqued  I. Dandouras  J. -A. Sauvaud  A. Keiling  T. D. Phan  R. Lundin  P. J. Cargill  C. P. Escoubet  C. W. Carlson  J. P. McFadden  G. K. Parks  E. Moebius  L. M. Kistler  E. Amata  M. -B. Bavassano-Cattaneo  A. Korth  B. Klecker  A. Balogh 《Surveys in Geophysics》2005,26(1-3):135-175

This paper gives an overview of Cluster observations in the high-altitude cusp region of the magnetosphere. The low and mid-altitude cusps have been extensively studied previously with a number of low-altitude satellites, but only little is known about the distant part of the magnetospheric cusps. During the spring-time, the trajectory of the Cluster fleet is well placed for dayside, high-altitude magnetosphere investigations due to its highly eccentric polar orbit. Wide coverage of the region has resulted and, depending on the magnetic dipole tilt and the solar wind conditions, the spacecraft are susceptible to encounter: the plasma mantle, the high-altitude cusp, the dayside magnetosphere (i.e. dayside plasma sheet) and the distant exterior cusp diamagnetic cavity. The spacecraft either exit into the magnetosheath through the dayside magnetopause or through the exterior cusp–magnetosheath interface. This paper is based on Cluster observations made during three high-altitude passes. These were chosen because they occurred during different solar wind conditions and different inter-spacecraft separations. In addition, the dynamic nature of the cusp allowed all the aforementioned regions to be sampled with different order, duration and characteristics. The analysis deals with observations of: (1) both spatial and temporal structures at high-altitudes in the cusp and plasma mantle, (2) signatures of possible steady reconnection, flux transfer events (FTE) and plasma transfer events (PTE), (3) intermittent cold (<100 eV) plasma acceleration associated with both plasma penetration and boundary motions, (4) energetic ions (5–40 keV) in the exterior cusp diamagnetic cavity and (5) the global structure of the exterior cusp and its direct interface with the magnetosheath. The analysis is primarily focused on ion and magnetic field measurements. By use of these recent multi-spacecraft Cluster observations we illustrate the current topics under debate pertaining to the solar wind–magnetosphere interaction, for which this region is known to be of major importance.  相似文献   

The Early Triassic Indosinian orogeny in Vietnam (Truong Son Belt and Kontum Massif); implications for the geodynamic evolution of Indochina   总被引：8，自引：0，他引：8  

C. Lepvrier  H. Maluski  Vu Van Tich  A. Leyreloup  Phan Truong Thi  Nguyen Van Vuong 《Tectonophysics》2004,393(1-4):87

New structural field data at various scale and ⁴⁰Ar–³⁹Ar geochronological results, from the basement rocks in the Truong Son belt and Kontum Massif of Vietnam, confirm that ductile deformation and high-temperature metamorphism were caused by the Early Triassic event of the Indosinian Orogeny in the range of 250–240 Ma. A compilation of isotopic data obtained in other countries along the Sibumasu–Indochina boundary broadly indicates same interval of ages. This tectonothermal event is interpreted as the result of a synchronous oblique collision of Indochina with both Sibumasu and South China, inducing dextral and sinistral shearing along E–W to NW–SE and N–S fault zones, respectively. The collision along Song Ma follows the northwards subduction of Indochina beneath South China and the subsequent development of the Song Da zone which in turn was affected by the Late Triassic Indosinian phase of shortening. Within the Indochina plate, internal collisions occurred coevally in the Early Triassic, as along the Poko suture, at the western border of the Kontum Massif.  相似文献   

华南、巽他和掸邦地块之间边界断裂的上新世—第四纪大规模构造反转     

Marie- Luce CHEVALIER  Paul TAPPONNIER  Phan Trong TRINH  Anne BRIAIS  李海兵  徐锐 《地质学报》2022,96(8):2833-2852

印度- 亚洲碰撞后，大陆板块沿着大型的左行走滑断裂挤出。规模最大的哀牢山- 红河剪切带(ASRR)将印支地块(巽他地块)与华南地块分隔开来。长约1000 km的红河活动断裂(RRF)沿哀牢山的北侧延伸，目前呈现出右行走滑兼正断的活动性质。本文在讨论了红河断裂系及其周缘的第三纪和现今变形特征(滑移性质反转、渐新世/第四纪位错、全新世滑动速率、GPS测量、地震机制等)基础之上，重点论述了其在上新世—第四纪从云南东南部到越南西北部、北部湾西部、再到更南的沙巴地区的断裂分布和运动学特征。新的数据证实，跨过三联点和越南西北部的奠边府断层之后，华南地块与巽他地块之间的现今大部分右行走滑主要沿着Da River断裂向Day Nui Con Voi(或称大象山)东南方向延伸。Da River断裂与RRF大致平行，是2020年M w 5. 0莫州地震的发震断层。进一步研究表明，Da River断裂很可能沿着渐新世—中新世莺歌海/宋红盆地西缘和越南东南海岸(归仁剪切带)向南延伸得更远，至少延伸到“Ile des Cendres”火山群，并可能继续延伸到沙巴- 文莱逆冲带的西端，靠近婆罗洲北部的近海活动边缘。最后，我们讨论了在菲律宾群岛、台湾岛和巽他群岛之间南海大部分地区大规模构造反转的运动学效应。  相似文献   

Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model     

Virginie Garnier  Gaston Giuliani  Daniel Ohnenstetter  Anthony E. Fallick  Jean Dubessy  David Banks  Hong Quang Vinh  Thrse Lhomme  Henri Maluski  Arnaud Pêcher  Kausar Allah Bakhsh  Pham Van Long  Phan Trong Trinh  Dietmar Schwarz 《Ore Geology Reviews》2008,34(1-2):169

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.  相似文献   

Groundwater flow in an arsenic-contaminated aquifer,Mekong Delta,Cambodia     

Shawn G. Benner  Matthew L. Polizzotto  Benjamin D. Kocar  Somenath Ganguly  Kongkea Phan  Kagna Ouch  Michael Sampson  Scott Fendorf 《Applied Geochemistry》2008

To advance understanding of hydrological influences on As concentrations within groundwaters of Southeast Asia, the flow system of an As-rich aquifer on the Mekong Delta in Cambodia where flow patterns have not been disturbed by irrigation well pumping was examined. Monitoring of water levels in a network of installed wells, extending over a 50 km² area, indicates that groundwater flow is dominated by seasonally-variable gradients developed between the river and the inland wetland basins. While the gradient inverts annually, net groundwater flow is from the wetlands to the river. Hydraulic parameters of the aquifer (K ≈ 10⁻⁴ ms⁻¹) and overlying clay aquitard (K ≈ 10⁻⁸ ms⁻¹) were determined using grain size, permeameter and slug test analyses; when coupled with observed gradients, they indicate a net groundwater flow velocity of 0.04–0.4 ma⁻¹ downward through the clay and 1–13 ma⁻¹ horizontally within the sand aquifer, producing aquifer residence times on the order 100–1000 a. The results of numerical modeling support this conceptual model of the flow system and, when integrated with observed spatial trends in dissolved As concentrations, reveal that the shallow sediments (upper 2–10 m of fine-grained material) are an important source of As to the underlying aquifer.  相似文献   

High Plains groundwater isotopic composition in northeastern New Mexico (USA): relationship to recharge and hydrogeologic setting     

Phan  Victoria A.  Zeigler  Kate E.  Vinson  David S. 《Hydrogeology Journal》2021,29(4):1445-1461

Hydrogeology Journal - In the High Plains (HP) region of northeastern New Mexico (NE NM), USA, underlying bedrock aquifers are utilized where the High Plains Aquifer is thin, absent, or...  相似文献   

The October 13, 2020, deadly rapid landslide triggered by heavy rainfall in Phong Dien,Thua Thien Hue,Vietnam     

Van Tien  Pham  Trinh  Phan Trong  Luong  Le Hong  Nhat  Le Minh  Duc  Dao Minh  Hieu  Tran Trung  Cuong  Tran Quoc  Nhan  Tran Thanh 《Landslides》2021,18(6):2329-2333

Landslides - At about 12:00 a.m., on October 13, 2020, a rapid rotational landslide induced by rainfall swept over Ranger Station-7 in Phong Xuan commune, Phong Dien district, Thua Thien Hue...  相似文献   

Seismic vulnerability mitigation of liquefied gas tanks using concave sliding bearings     

H. N. Phan  F. Paolacci  D. Corritore  B. Akbas  E. Uckan  J. J. Shen 《Bulletin of Earthquake Engineering》2016,14(11):3283-3299

The aim of this paper is to evaluate the effectiveness of a concave sliding bearing system for the seismic protection of liquefied gas storage tanks through a seismic fragility analysis. An emblematic case study of elevated steel storage tanks, which collapsed during the 1999 ?zmit earthquake at Habas Pharmaceutics plant in Turkey, is studied. Firstly, a fragility analysis is conducted for the examined tank based on a lumped-mass stick model, where the nonlinear shear behaviour of support columns is taken into account by using a phenomenological model. Fragility curves in terms of an efficient intensity measure for different failure modes of structural components demonstrate the inevitable collapse of the tank mainly due to insufficient shear strength of the support columns. A seismic isolation system based on concave sliding bearings, which has been demonstrated a superior solution to seismically protect elevated tanks, is then designed and introduced into the numerical model, accounting for its non-linear behaviour. Finally, a vulnerability analysis for the isolated tank is performed, which proves a high effectiveness of the isolation system in reducing the probability of failure within an expected range of earthquake intensity levels.  相似文献   

A fractal model for streaming potential coefficient in porous media          下载免费PDF全文

Luong Duy Thanh  Phan Van Do  Nguyen Van Nghia  Nguyen Xuan Ca 《Geophysical Prospecting》2018,66(4):753-766

Streaming potential is the result of coupling between a fluid flow and an electric current in porous rocks. The modified Helmholtz–Smoluchowski equation derived for capillary tubes is mostly used to determine the streaming potential coefficient of porous media. However, to the best of our knowledge, the fractal geometry theory is not yet applied to analyse the streaming potential in porous media. In this article, a fractal model for the streaming potential coefficient in porous media is developed based on the fractal theory of porous media and on the streaming potential in a capillary. The proposed model is expressed in terms of the zeta potential at the solid?liquid interface, the minimum and maximum pore/capillary radii, the fractal dimension, and the porosity of porous media. The model is also examined by using another capillary size distribution available in published articles. The results obtained from the model using two different capillary size distributions are in good agreement with each other. The model predictions are then compared with experimental data in the literature and those based on the modified Helmholtz–Smoluchowski equation. It is shown that the predictions from the proposed fractal model are in good agreement with experimental data. In addition, the proposed model is able to reproduce the same result as the Helmholtz–Smoluchowski equation, particularly for high fluid conductivity or large grain diameters. Other factors influencing the streaming potential coefficient in porous media are also analysed.  相似文献