Relationship of manganese-iron oxides and associated heavy metals to grain size in stream sediments     

Philip R. Whitney 《Journal of Geochemical Exploration》1975,4(2):251-263

The distribution of ammonium citrate-leachable lead, zinc and cadmium among size fractions in stream sediments is strongly influenced by the presence of hydrous Mn-Fe oxides in the form of coatings on sediment grains. Distribution curves showing leachable metals as a function of particle size are given for eight samples from streams in New York State. These show certain features in common; in particular two concentrations of metals, one in the finest fractions, and a second peak in the coarse sand and gravel fraction. The latter can be explained as a result of the increasing prevalence and thickness of oxide coatings with increasing particle size, with the oxides serving as collectors for the heavy metals. The distribution of Zn and Cd in most of the samples closely parallels that of Mn; the distribution of Pb is less regular and appears to be related to Fe in some samples and Mn in others. The concentration of metals in the coarse fractions due to oxide coatings, combined with the common occurrence of oxide deposition in streams of glaciated regions, raises the possibility of using coarse materials for geochemical surveys and environmental heavy-metal studies.  相似文献   

Dissolved chromium in the St. Lawrence estuary     

John A. Campbell  Philip A. Yeats 《Estuarine, Coastal and Shelf Science》1984,19(5):513-522

A study of dissolved chromium in the St. Lawrence estuary and Gulf of St. Lawrence has been carried out. A chromium concentration of 0·7 μg l^?1 was found in the St. Lawrence River. In the turbidity maximum of the upper estuary, chromium is removed from solution onto fine-grained resuspended sediments and internally produced organic-rich floccules. A simple flux calculation shows that these processes remove ～50% of the total dissolved chromium input of the river. At salinities greater than 5‰ dissolved chromium mixes conservatively.  相似文献   

Geophysical response of filled sinkholes,soil pipes and associated bedrock fractures in thinly mantled karst,east-central Illinois     

Shawkat?Ahmed  Philip?J.?CarpenterEmail author 《Environmental Geology》2003,44(6):705-716

Karst aquifers are often protected by a thin mantle of unconsolidated sediment. Soil pipes and sinkholes may breach this natural protective barrier and open pathways for contaminants to quickly reach bedrock aquifers. Geophysical surveys offer a quick and noninvasive way to identify these features; such surveys may also be sequenced to reveal increasing detail in critical areas. At a study site in east-central Illinois, electromagnetic (EM) surveys mapped high conductivity anomalies over filled sinkholes and soil pipes that penetrated the unconsolidated cover. Two-dimensional inverted resistivity sections, made over these anomalies, depict filled sinkholes and soil pipes as conductive zones above deeply weathered bedrock fractures. Borings verified the geophysical models and suggest high conductivities associated with the filled sinkholes are the result of enhanced moisture near active soil pipes. EM surveys also identified conductive zones in the overburden above a probable bedrock fracture linking sinkhole areas 0.5 km apart. Resistivity and EM methods, used in a phased and sequential manner, thus proved useful in mapping filled sinkholes and in delineating the vertical and lateral connections between soil pipes and hydraulically active bedrock fractures.  相似文献   

Wide-Field Camera for Gravitational Microlensing Survey: MOA-cam2     

Toshifumi Yanagisawa  Yasushi Muraki  Yutaka Matsubara  Fumio Abe  Kimiaki Masuda  Sachiyo Noda  Takahiro Sumi  Yuji Kato  Mitsuaki Fujimoto  Shuji Sato  Ian Bond  Nicholas Rattenbury  Philip Yock  Pam Kilmartin  John Hearnshaw  Micheal Reid  Denis Sullivan  Brian Carter  Richard Dodd  Garry Nankivell  Noiman Rumsey  Morihiro Honda  Maki Sekiguchi  Masanori Yoshizawa  Takashi Nakamura  Humitaka Sato  Seiji Kabe  Makoto Kobayashi  Yoshiyuki Watase  Jun Jugaku  Toshiharu Saito  Barbel Koribalsky 《Experimental Astronomy》2000,10(4):519-535

We have constructed a large, mosaic CCD camera called MOA-cam2 which has 4096 × 6144-pixelsto search for gravitational microlensing events. MOA-cam2 has three4096 × 2048-pixel SITe CCD chips, which have a very high quantum efficiency (nearly 80% in the wave region 500 to 800 nm),and three buttable sides. We have placed the threechips side by side with 100 m dead space. MOA-cam2 has been installed on the 61 cm Boller and Chivens telescope of the MOA collaboration at the Mt. John University Observatory (MJUO) in NewZealand since July 1998. The field coverage is 0.92° × 1.38° per exposure. The technical details of MOA-cam2 and the first images obtained with the Boller and Chivens telescope are presented. MOA-cam2 introduces a second phase of research on gravitational microlensing by the MOA collaboration.  相似文献   

Influence of wave groups on SSC patterns over vortex ripples     

Paul V. Villard  Philip D. Osborne  Christopher E. Vincent 《Continental Shelf Research》2000,20(17):1

Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group.  相似文献   

The relationships between tropical Atlantic sea level variability and major climate indices     

Jennifer A. M. Andrew  Harry Leach  Philip L. Woodworth 《Ocean Dynamics》2006,56(5-6):452-463

Relationships were examined between variability in tropical Atlantic sea level and major climate indices with the use of TOPEX/POSEIDON altimeter and island tide gauge data with the aim of learning more about the external influences on the variability of the tropical Atlantic ocean. Possible important connections were found between indices related to the El Niño–Southern Oscillation (ENSO) and the sea levels in all three tropical regions (north, equatorial, and south), although the existence of only one major ENSO event within the decade of available altimetry means that a more complete investigation of the ENSO-dependence of Atlantic sea level changes has to await for the compilation of longer data sets. An additional link was found with the Indian Ocean Dipole (IOD) in the equatorial region, this perhaps surprising observation is probably an artifact of the similarity between IOD and ENSO time series in the 1990s. No evidence was obtained for significant correlations between tropical Atlantic sea level and North Atlantic Oscillation or Antarctic Oscillation Index. The most intriguing relationship observed was between the Quasi-Biennial Oscillation and sea level in a band centered approximately on 10°S. A plausible explanation for the relationship is lacking, but possibilities for further research are suggested.  相似文献   

Particle trapping in stratified estuaries: consequences of mass conservation     

David A. Jay  Philip M. Orton  Thomas Chisholm  Douglas J. Wilson  Annika M. V. Fain 《Estuaries and Coasts》2007,30(6):1095-1105

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Oceanography of Glacier Bay,Alaska: Implications for biological patterns in a glacial fjord estuary     

Lisa L. Etherington  Philip N. Hooge  Elizabeth R. Hooge  David F. Hill 《Estuaries and Coasts》2007,30(6):927-944

Alaska, U.S.A, is one of the few remaining locations in the world that has fjords that contain temperate idewater glaciers. Studying such estuarine systems provides vital information on how deglaciation affects oceanographic onditions of fjords and surrounding coastal waters. The oceanographic system of Glacier Bay, Alaska, is of particular interest ue to the rapid deglaciation of the Bay and the resulting changes in the estuarine environment, the relatively high oncentrations of marine mammals, seabirds, fishes, and invertebrates, and the Bay’s status as a national park, where ommercial fisheries are being phased out. We describe the first comprehensive broad-scale analysis of physical and iological oceanographic conditions within Glacier Bay based on CTD measurements at 24 stations from 1993 to 2002. easonal patterns of near-surface salinity, temperature, stratification, turbidity, and euphotic depth suggest that freshwater nput was highest in summer, emphasizing the critical role of glacier and snowmelt to this system. Strong and persistent tratification of surface waters driven by freshwater input occurred from spring through fall. After accounting for seasonal nd spatial variation, several of the external physical factors (i.e., air temperature, precipitation, day length) explained a large mount of variation in the physical properties of the surface waters. Spatial patterns of phytoplankton biomass varied hroughout the year and were related to stratification levels, euphotic depth, and day length. We observed hydrographic atterns indicative of strong competing forces influencing water column stability within Glacier Bay: high levels of freshwater ischarge promoted stratification in the upper fjord, while strong tidal currents over the Bay’s shallow entrance sill enhanced ertical mixing. Where these two processes met in the central deep basins there were optimal conditions of intermediate tratification, higher light levels, and potential nutrient renewal. These conditions were associated with high and sustained hlorophylla levels observed from spring through fall in these zones of the Bay and provide a framework for understanding he abundance patterns of higher trophic levels within this estuarine system.  相似文献   

A three-dimensional finite-element model of wind effects upon higher harmonics of the internal tide     

Philip Hall  Alan M. Davies 《Ocean Dynamics》2007,57(4-5):305-323

A non-linear three-dimensional unstructured grid model of the M₂ tide in the shelf edge area off the west coast of Scotland is used to examine the spatial distribution of the M₂ internal tide and its higher harmonics in the region. In addition, the spatial variability of the tidally induced turbulent kinetic energy and associated mixing in the area are considered. Initial calculations involve only tidal forcing, although subsequent calculations are performed with up-welling and down-welling favourable winds to examine how these influence the tidal distribution (particularly the higher harmonics) and mixing in the region. Both short- and long-duration winds are used in these calculations. Tidal calculations show that there is significant small-scale spatial variability particularly in the higher harmonics of the internal tide in the region. In addition, turbulence energy and mixing exhibit appreciable spatial variability in regions of rapidly changing topography, with increased mixing occurring above seamounts. Wind effects significantly change the distribution of the M₂ internal tide and its higher harmonics, with appreciable differences found between up- and down-welling winds and long- and short-duration winds because of differences in mixing and the presence of wind-induced flows. The implications for model validation, particularly in terms of energy transfer to higher harmonics, and mixing are briefly discussed.  相似文献   

International Association of Geoanalysts' Protocol for the Certification of Geological and Environmental Reference Materials: A Supplement     

Jean S. Kane  Philip J. Potts  Thomas Meisel  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2007,31(3):285-288

The International Association of Geoanalysts (IAG) published a protocol for the certification of reference materials in close accord with the International Organisation for Standardisation (ISO) guidelines (Kane et al. 2003). This article supplements that protocol, providing additional discussion of best approaches for pre-selecting laboratories for participation in certification projects. This discussion also makes a distinction between inter-laboratory certifications, where n = 15 is the general standard, and expert laboratory certifications, where a much smaller number of laboratories will be deemed qualified to provide data of the quality needed for certification.  相似文献