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101.
Multiphase flow modelling is a major issue in the assessment of groundwater pollution. Three-phase flows are commonly governed by mathematical models that associate a pressure equation with two saturation equations. These equations involve a number of secondary variables that reflect the fluid behaviour in a porous medium. To improve the computational efficiency of multiphase flow simulators, several simplified reformulations of three-phase flow equations have been proposed. However, they require the construction of new secondary variables adapted to the reformulated flow equations. In this article, two different approaches are compared to quantify these variables. A numerical example is given for a typical fine sand.  相似文献   
102.
103.
Due to its intensive data processing and highly distributed organization, the multidisciplinary Earth Science applications community is uniquely positioned for the uptake and exploitation of Grid technologies. Currently Enabling Grids for E-sciencE, and other large Grid infrastructures are already deployed and capable of operational services. So far however, the adoption and exploitation of Grid technology throughout the Earth Science community has been slower than expected. The Dissemination and Exploitation of GRids in Earth sciencE project, proposed by the European Commission to assist and accelerate this process in a number of different ways, had between its main goals the creation of a roadmap towards Earth Science Grid platform. This paper presents the resulting roadmap.  相似文献   
104.
The diffusive wave approximation of the Saint-Venant equations is commonly used in hydrological models to describe surface flow processes. Numerous numerical approaches can be used to solve this highly nonlinear equation. Nonlinear time integration schemes—also called methods of lines (MOL)—were proven very efficient to solve other nonlinear problems in geosciences but were never considered to deal with surface flow modeling with the diffusive wave equation. In this paper, we study the relative performance of different time and space integration schemes by comparing the results obtained with classical approaches and with nonlinear time integration approaches. The results show that (i) the integration method with a higher order in space shows high accuracy regarding an integrated indicator such as the global mass balance error but is less accurate regarding local indicators, and (ii) nonlinear time integration techniques perform better than classical ones. Overall, it seems that integration techniques combining nonlinear time integration and a low spatial order need to be considered when developing hydrological modeling tools owing to their simplicity of implementation and very good performance.  相似文献   
105.
106.
We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q® water. We obtained an average reference value rK (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg?1)/(g kg?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to rNa, rCa and rMg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.  相似文献   
107.
In situ monitoring of karst springs in Wallonia (southern Belgium)   总被引:1,自引:1,他引:0  
The implementation of the Water Framework Directive, as well as the forthcoming entry into force of other European water policies focusing on water resources, require a thorough reorganization of groundwater resources monitoring in most European countries. In Wallonia, monitoring programs were initiated in 2005 to control the quantitative and chemical statuses of groundwater bodies, as well as the effectiveness of management plans aimed at achieving environmental objectives. In karst aquifers, springs are preferential monitoring targets even if, as a result of the high heterogeneity of this type of aquifer, the interpretation of time series and spatial data remains a challenge. Since 2006, a “springs” monitoring network has been progressively set up in the southern part of Belgium. Currently, in situ measurements of discharge, temperature, conductivity, turbidity and fluorescence of water are conducted at nine karstic outlets in the Devonian and the Carboniferous limestone aquifers of Wallonia. The main objective of this ongoing research is to evaluate the suitability and the robustness of such standard measurements to discriminate anthropogenic impacts from natural variations, at both short- and long-term scales. Discharge and temperature data revealed being useful in the assessment of regional hydro-climatic trends. Groundwater proved to be a better natural filter for the assessment of long-term climatic changes than mathematical filtering of noisy surface signals. Investigations of such data at a European scale could therefore give additional insight into the impacts of climate change on groundwater resources. Conductivity, turbidity and fluorescence data characterize the particulate, mineral and organic health of water and a better understanding of their natural dynamics could help in the early detection of anthropogenic deviations. However, the current reproducibility of these measurements is too low to ascertain observed trends and fluctuations, and further research is still needed.  相似文献   
108.
109.
This study investigates the effect of fine-scale clay drapes on tracer transport. A tracer test was performed in a sandbar deposit consisting of cross-bedded sandy units intercalated with many fine-scale clay drapes. The heterogeneous spatial distribution of the clay drapes causes a spatially variable hydraulic conductivity and sorption coefficient. A fluorescent tracer (sodium naphthionate) was injected in two injection wells and ground water was sampled and analyzed from five pumping wells. To determine (1) whether the fine-scale clay drapes have a significant effect on the measured concentrations and (2) whether application of multiple-point geostatistics can improve interpretation of tracer tests in media with complex geological heterogeneity, this tracer test is analyzed with a local three-dimensional ground-water flow and transport model in which fine-scale sedimentary heterogeneity is modeled using multiple-point geostatistics. To reduce memory needs and calculation time for the multiple-point geostatistical simulation step, this study uses the technique of direct multiple-point geostatistical simulation of edge properties. Instead of simulating pixel values, model cell edge properties indicating the presence of irregularly shaped surfaces are simulated using multiple-point geostatistical simulations. Results of a sensitivity analysis show under which conditions clay drapes have a significant effect on the concentration distribution. Calibration of the model against measured concentrations from the tracer tests reduces the uncertainty on the clay-drape parameters. The calibrated model shows which features of the breakthrough curves can be attributed to the geological heterogeneity of the aquifer and which features are caused by other processes.  相似文献   
110.
The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO2. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.  相似文献   
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