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981.
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983.
984.
Jennifer S. Le Blond Claire J. Horwell Peter J. Baxter Sabina A. K. Michnowicz Maura Tomatis Bice Fubini Pierre Delmelle Christina Dunster Herman Patia 《Bulletin of Volcanology》2010,72(9):1077-1092
The continuous ash and gas emissions from the Tavurvur cone in Rabaul caldera, Papua New Guinea, during 2007–08, raised concerns
regarding how exposure would affect the respiratory health of nearby populations and impact on the environment. As part of
a formal evaluation of the effects of volcanic emissions on public health, we investigated the potential health hazard of
the ash using a suite of selected mineralogical analyses and in vitro toxicity screening tests. The trachy-andesitic ash comprised 2.1–6.7 vol.% respirable (sub-4 μm diameter) particles. The crystalline silica content was 1.9–5.0 wt.% cristobalite (in the bulk sample) with trace amounts
of quartz and/or tridymite. Scanning electron microscopy showed that the ash particles were angular with sparse, fibre-like particles (∼3–60 μm max. diameter) observed in some samples, which we confirmed to be CaSO4 (gypsum, at <6 wt.% in the bulk samples) and not asbestiform fibres. The ash specific surface area was low (0.1–2.7 m2 g−1). The leached solution from one of the ash samples was slightly acidic (pH 5.6), but did not contain high levels of toxic
metals (such as F, Cu, Zn, Mn, As, Ni and Cd) when compared to previously tested volcanic ash leachates. Ash samples generated
potentially-harmful hydroxyl radicals through an iron-mediated catalytic reaction, in the range of 0.15–2.47 μmol m−2 (after 30 min of reaction). However, measurement of particle oxidative capacity (potential oxidative stress reaction using
ascorbic acid) and silica-like injury to red blood cells (erythrolysis assay, i.e. measurement of cell death) nevertheless revealed low biological reactivity.
The findings suggest that acute exposure to the ash would have a limited potential to exacerbate pre-existing conditions such as asthma or chronic bronchitis, and the potential for chronic exposure leading to silicosis was
low. 相似文献
985.
Trap Pierre Roger Françoise Cenki-Tok Bénédicte Paquette Jean-Louis 《International Journal of Earth Sciences》2017,106(2):453-476
International Journal of Earth Sciences - Unravelling the detailed pressure–temperature–time-deformation (P–T–t-D) evolution of magmatic and metamorphic rocks provides... 相似文献
986.
Luigi Folco Pierre Rochette Jrme Gattacceca Natale Perchiazzi 《Meteoritics & planetary science》2006,41(3):343-353
Abstract— We report on the effectiveness of using magnetic measurements in the search for meteorites on the Antarctic ice sheet, which is thus far the Earth's most productive terrain. Magnetic susceptibility measurements carried out with a pocket meter (SM30) during the 2003/04 PNRA meteorite collection expedition to northern Victoria Land (Antarctica) proved to be a rapid, sensitive, non‐destructive means for the in situ identification, pairing, and classification of meteorites. In blue ice fields characterized by the presence of moraines and glacial drifts (e.g., Miller Butte, Roberts Butte, and Frontier Mountain), magnetic susceptibility measurements allowed discrimination of meteorites from abundant terrestrial stones that look like meteorites thanks to the relatively high magnetic susceptibility of the former with respect to terrestrial rocks. Comparative measurements helped identify 16 paired fragments found at Johannessen Nunataks, thereby reducing unnecessary duplication of laboratory analyses and statistical bias. Following classifications schemes developed by us in this and previous works, magnetic susceptibility measurements also helped classify stony meteorites directly in the field, thereby providing a means for selecting samples with higher research priority. A magnetic gradiometer capable of detecting perturbations in the Earth's magnetic field induced by the presence of meteorites was an efficient tool for locating meteorites buried in snow along the downwind margin of the Frontier Mountain blue ice field. Based on these results, we believe that magnetic sensors should constitute an additional payload for robotic search for meteorites on the Antarctic ice sheet and, by extension, on the surface of Mars where meteorite accumulations are predicted by theoretical works. Lastly, magnetic susceptibility data was successfully used to crosscheck the later petrographic classification of the 123 recovered meteorites, allowing the detection of misclassified or peculiar specimens. 相似文献
987.
Sylvie Gobert Stphane Sartoretto Valrie Rico-Raimondino Bruno Andral Aurelia Chery Pierre Lejeune Pierre Boissery 《Marine pollution bulletin》2009,58(11):1727-1733
This paper describes the PREI (Posidonia oceanica Rapid Easy Index), a method used to assess the ecological status of seawater along Mediterranean French coasts. The PREI was drawn up according to the requirements of the Water Framework Directive (WFD 2000/60/EC) and was tested on 24 and 18 stations in PACA (Provence-Alpes-Côtes d’Azur) and Corsica, respectively. The PREI is based on five metrics: shoot density, shoot leaf surface area, E/L ratio (epiphytic biomass/leaf biomass), depth of lower limit, and type of this lower limit. The 42 studied stations were classified in the first four levels of status: high, good, moderate and poor. The PREI values ranged between 0.280 and 0.847; this classification is in accordance with our field knowledge and with our knowledge of the literature. The PREI was validated regarding human pressure levels (r2 = 0.74). (http://eurex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2000:327:0001:0072:EN:PDF). 相似文献
988.
Frederic Moynier Pierre Beck Fred Jourdan Qing-Zhu Yin Uwe Reimold Christian Koeberl 《Earth and Planetary Science Letters》2009,277(3-4):482-489
Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime. 相似文献
989.
Chapelle FH Bradley PM Goode DJ Tiedeman C Lacombe PJ Kaiser K Benner R 《Ground water》2009,47(1):108-121
The bioavailability of total organic carbon (TOC) was examined in ground water from two hydrologically distinct aquifers using biochemical indicators widely employed in chemical oceanography. Concentrations of total hydrolyzable neutral sugars (THNS), total hydrolyzable amino acids (THAA), and carbon-normalized percentages of TOC present as THNS and THAA (referred to as "yields") were assessed as indicators of bioavailability. A shallow coastal plain aquifer in Kings Bay, Georgia, was characterized by relatively high concentrations (425 to 1492 μM; 5.1 to 17.9 mg/L) of TOC but relatively low THNS and THAA yields (∼0.2%–1.0%). These low yields are consistent with the highly biodegraded nature of TOC mobilized from relatively ancient (Pleistocene) sediments overlying the aquifer. In contrast, a shallow fractured rock aquifer in West Trenton, New Jersey, exhibited lower TOC concentrations (47 to 325 μM; 0.6 to 3.9 mg/L) but higher THNS and THAA yields (∼1% to 4%). These higher yields were consistent with the younger, and thus more bioavailable, TOC being mobilized from modern soils overlying the aquifer. Consistent with these apparent differences in TOC bioavailability, no significant correlation between TOC and dissolved inorganic carbon (DIC), a product of organic carbon mineralization, was observed at Kings Bay, whereas a strong correlation was observed at West Trenton. In contrast to TOC, THNS and THAA concentrations were observed to correlate with DIC at the Kings Bay site. These observations suggest that biochemical indicators such as THNS and THAA may provide information concerning the bioavailability of organic carbon present in ground water that is not available from TOC measurements alone. 相似文献
990.
The ECOLOPHY experiments aimed at investigating physical exchanges between coastal and open sea. They were carried out in June and December 2005 over the shelf-break in the North-eastern part of the Gulf of Lions (Northwestern Mediterranean Sea). This area is considered to be the generation zone for the eddy and meandering structures of the Northern Current (NC). The objective of the present work is to examine mesoscale variability of this coastal slope current in the light of available data. Numerical modeling is used to support the field data analysis. ADCP current measurements over a one-year period show that mesoscale activity is maximal in late winter, correlating with the seasonal variability of the NC and, also, partly with local winds. Measured currents exhibit mesoscale fluctuations with periods ranging from 3 to 30 days, in agreement with previous analyses. Fluctuations of periods longer than 10 days are found to be mainly oriented in the direction of the mean current, whereas more frequently observed high frequency fluctuations tend to be oriented cross-slope, suggesting a relationship with the NC mesoscale meandering. Moreover, trajectories of surdrift buoys launched in the NC vein exhibit mesoscale phenomena, such as current meanders or eddies and on-shelf intrusions. Numerical modeling provides a synoptic point of view and is used hereafter to support physical interpretation of punctual eulerian or lagrangian measurements. Therefore, modeled hydrodynamic fields are used to analyze surdrift buoy trajectories and computed vertically averaged current and Ertel potential vorticity provide a better understanding of these behaviors. 相似文献