Tectonic discrimination of basalts with classification trees   总被引：5，自引：0，他引：5  

Pieter Vermeesch 《Geochimica et cosmochimica acta》2006,70(7):1839-1848

Traditionally, geochemical classification of basaltic rocks of unknown tectonic affinity has been performed by discrimination diagrams. Although easy to use, this method is fairly inaccurate because it only uses bi- or trivariate data. Furthermore, many popular discrimination diagrams are statistically not very rigorous because the decision boundaries are drawn by eye, and they ignore closure, thus violating the rules of compositional data analysis. Classification trees approximate the data space by a stepwise constant function, and are a more rigorous and potentially more effective way to determine tectonic affinity. Trees allow the simultaneous use of an unlimited number of geochemical features, while still permitting visualization by an easy-to-use, two-dimensional graph. Two classification trees are presented for the discrimination of basalts of mid-ocean ridge, ocean island, and island arc affinities. The first tree uses 51 major, minor, and trace elements and isotopic ratios and should be used for the classification of fresh basalt samples. A second tree only uses high field strength element analyses and isotopic ratios, and can also be used for basalts that have undergone alteration. The probability of successful classification is 89% for the first and 84% for the second tree, as determined by 10-fold cross-validation. Even though the trees presented in this paper use many geochemical features, it is not a problem if some of these are missing in the unknown sample. Classification trees solve this problem with surrogate variables, which give more or less the same decision as the primary variables. The advantages of the classification tree approach over discrimination diagrams are illustrated by a comparative test on a sample dataset of known tectonic affinities. Although arguably better than discrimination diagrams, classification trees are not perfect, and the limitations of the method are illustrated on a published dataset of basalts from the Pindos Basin (Greece).  相似文献   

A detailed post‐IR IRSL dating study of the Niuyangzigou loess site in northeastern China          下载免费PDF全文

Shuangwen Yi  Jan‐Pieter Buylaert  Andrew S. Murray  Huayu Lu  Christine Thiel  Lin Zeng 《Boreas: An International Journal of Quaternary Research》2016,45(4):644-657

In this study, we report standard quartz SAR OSL and post‐IR infrared (IR) stimulated luminescence (post‐IR IRSL; pIRIR₂₉₀) measurements made on sand‐sized quartz and K‐feldspar extracts from the loess‐palaeosol sequence at Niuyangzigou in northeastern China. The quartz OSL characteristics are satisfactory. Extensive pIRIR_50,290 dose recovery tests were performed by adding doses on top of the natural dose. We found that dose recovery ratios improve significantly when the test dose ranges between ~15 and ~80% of the total dose, and good dose recovery (within ±5% of unity) can be obtained up to ～800 Gy. Otherwise, the dose recovery ratio deviates from unity. The D_e values also depend on the test dose size and so we conclude that the effect of test dose size should be routinely considered in pIRIR dating. First IR stimulation plateau pIRIR₂₉₀ results are compared with multiple elevated temperature ‐pIRIR (MET‐pIRIR) data. It appears that the low temperature MET‐pIRIR data are strongly affected by poor dose recovery, but this is not the case for the pIRIR₂₉₀ results. Natural signal measurements at the highest (first IR) stimulation temperature on a sample expected to be in field saturation suggest that ~10% signal loss occurs in pIRIR signals. Long‐term laboratory bleaching experiments (>80 days) show that a constant (or very difficult to bleach) residual pIRIR₂₉₀ signal is reached after ~300 h, corresponding to a dose of 6.2±0.7 Gy. Quartz OSL and feldspar pIRIR_50,290 ages are in good agreement at least back to c. 70 ka. Beyond this the quartz ages begin to underestimate but the feldspar ages are in agreement with the expected Last Interglacial age palaeosol.  相似文献   

Numerical Analysis of the Effects of Wind and Sprayer Type on Spray Distribution in Different Orchard Training Systems     

Ashenafi T. Duga  Donald Dekeyser  Kris Ruysen  Dany Bylemans  David Nuyttens  Bart M. Nicolai  Pieter Verboven 《Boundary-Layer Meteorology》2015,157(3):517-535

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The thermal impact of aquifer thermal energy storage (ATES) systems: a case study in the Netherlands,combining monitoring and modeling     

Philip W. Visser  Henk Kooi  Pieter J. Stuyfzand 《Hydrogeology Journal》2015,23(3):507-532

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GPS-derived orbits for the GOCE satellite   总被引：5，自引：4，他引：1  

Heike Bock  Adrian Jäggi  Ulrich Meyer  Pieter Visser  Jose van den IJssel  Tom van Helleputte  Markus Heinze  Urs Hugentobler 《Journal of Geodesy》2011,85(11):807-818

The first ESA (European Space Agency) Earth explorer core mission GOCE (Gravity field and steady-state Ocean Circulation Explorer) was launched on 17 March 2009 into a sun-synchronous dusk–dawn orbit with an exceptionally low initial altitude of about 280 km. The onboard 12-channel dual-frequency GPS (Global Positioning System) receiver delivers 1 Hz data, which provides the basis for precise orbit determination (POD) for such a very low orbiting satellite. As part of the European GOCE Gravity Consortium the Astronomical Institute of the University of Bern and the Department of Earth Observation and Space Systems are responsible for the orbit determination of the GOCE satellite within the GOCE High-level Processing Facility. Both quick-look (rapid) and very precise orbit solutions are produced with typical latencies of 1 day and 2 weeks, respectively. This article summarizes the special characteristics of the GOCE GPS data, presents POD results for about 2 months of data, and shows that both latency and accuracy requirements are met. Satellite Laser Ranging validation shows that an accuracy of 4 and 7 cm is achieved for the reduced-dynamic and kinematic Rapid Science Orbit solutions, respectively. The validation of the reduced-dynamic and kinematic Precise Science Orbit solutions is at a level of about 2 cm.  相似文献   

Influence of topography on tide propagation and amplification in semi-enclosed basins   总被引：3，自引：2，他引：1  

Pieter C. Roos  Henk M. Schuttelaars 《Ocean Dynamics》2011,61(1):21-38

An idealized model for tide propagation and amplification in semi-enclosed rectangular basins is presented, accounting for depth differences by a combination of longitudinal and lateral topographic steps. The basin geometry is formed by several adjacent compartments of identical width, each having either a uniform depth or two depths separated by a transverse topographic step. The problem is forced by an incoming Kelvin wave at the open end, while allowing waves to radiate outward. The solution in each compartment is written as the superposition of (semi)-analytical wave solutions in an infinite channel, individually satisfying the depth-averaged linear shallow water equations on the f plane, including bottom friction. A collocation technique is employed to satisfy continuity of elevation and flux across the longitudinal topographic steps between the compartments. The model results show that the tidal wave in shallow parts displays slower propagation, enhanced dissipation and amplified amplitudes. This reveals a resonance mechanism, occurring when the length of the shallow end is roughly an odd multiple of the quarter Kelvin wavelength. Alternatively, for sufficiently wide basins, also Poincaré waves may become resonant. A transverse step implies different wavelengths of the incoming and reflected Kelvin wave, leading to increased amplitudes in shallow regions and a shift of amphidromic points in the direction of the deeper part. Including the shallow parts near the basin’s closed end (thus capturing the Kelvin resonance mechanism) is essential to reproduce semi-diurnal and diurnal tide observations in the Gulf of California, the Adriatic Sea and the Persian Gulf.  相似文献   

V oxidation state in Fe–Ti oxides by high-energy resolution fluorescence-detected X-ray absorption spectroscopy     

Amélie Bordage  Etienne Balan  Johan P. R. de Villiers  Robert Cromarty  Amélie Juhin  Claire Carvallo  Georges Calas  P. V. Sunder Raju  Pieter Glatzel 《Physics and Chemistry of Minerals》2011,38(6):449-458

The oxidation state of vanadium in natural and synthetic Fe–Ti oxides is determined using high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). Eleven natural magnetite-bearing samples from a borehole of the Main Magnetite Layer of the Bushveld Complex (South Africa), five synthetic Fe oxide samples, and three natural hematite-bearing samples from Dharwar supergroup (India) are investigated. V K edge spectra were recorded on the ID26 beamline at the European Synchrotron Radiation Facility (Grenoble, France), and the pre-edge features were used to determine the local environment and oxidation state of vanadium. In the case of the magnetite samples (natural and synthetic), we show that vanadium is incorporated in the octahedral site of the spinel structure under two oxidation states: +III and +IV. The variations of the pre-edge area are interpreted as various proportions in V³⁺ and V⁴⁺ (between 9.5 and 16.3% of V⁴⁺), V³⁺ being the main oxidation state. In particular, the variations of the V⁴⁺/V³⁺ ratio along the profile of the Main Magnetite Layer seem to follow the crystallization sequence of the layer. In the case of the hematite samples from India, the pre-edge features indicate that vanadium is substituted to Fe and mainly incorporated as V⁴⁺ (between 40 and 72% of V⁴⁺). We also demonstrate the potentiality of HERFD-XAS for mineralogical studies, since it can filter out the unwanted fluorescence and give better resolved spectra than conventional XAS.  相似文献   

Single Column Sequential Extraction of Ra,Nd, Th,Pa and U from a Natural Sample     

Catherine Jeandel  Celia Venchiarutti  Michael Bourquin  Catherine Pradoux  François Lacan  Pieter van Beek  Jean Riotte 《Geostandards and Geoanalytical Research》2011,35(4):449-459

A new procedure allowing the sequential extraction of Ra, Nd, Th, Pa and U from the same initial natural sample (sea or river waters, particles, sediments, rocks) is proposed. Extraction recoveries were better than 90%. Procedural blanks ranged from 80 pg (for Nd) to below 1 fg, the detection limit of the MC‐ICP‐MS used (for Pa); all were negligible compared with the amounts of elements currently determined. Based on classical anionic resins attached to a peristaltic pump allowing precise flow rate control, this procedure allowed a consequent reduction of the sample size, which improved the sampling resolution and reduced the sampling cost. It also ensured a better consistency of the samples for the five tracers.  相似文献   

Hydrogeology and groundwater flow in a basalt-capped Mesozoic sedimentary series of the Ethiopian highlands     

Ine Vandecasteele  Jan Nyssen  Wim Clymans  Jan Moeyersons  Kristine Martens  Marc Van Camp  Tesfamichael Gebreyohannes  Florimond Desmedt  Jozef Deckers  Kristine Walraevens 《Hydrogeology Journal》2011,19(3):641-650

A hydrogeological study was undertaken in the Zenako-Argaka catchment, near Hagere Selam in Tigray, northern Ethiopia, during the rainy season of 2006. A geological map was produced through geophysical measurements and field observations, and a fracture zone identified in the north west of the catchment. A perched water table was found within the Trap Basalt series above the laterized upper Aram Aradam Sandstones. A map of this water table was compiled. Water-level variation during the measurement period was at least 4.5?m. Variation in basal flow for the whole catchment for the measurement period was between 12 and 276?m³/day. A groundwater flow model was produced using Visual MODFLOW, indicating the general direction of flow to be towards the south, and illustrating that the waterways have only a limited influence on groundwater flow. The soil water budget was calculated for the period 1995?C2006, which showed the important influence of the distribution of rainfall in time. Although Hagere Selam received some 724?mm of rainfall per year over this period, the strong seasonal variation in rainfall meant there was a water deficit for on average 10?months per year.  相似文献   

Provenance and reconnaissance study of detrital zircons of the Palaeozoic Cape Supergroup in South Africa: revealing the interaction of the Kalahari and R��o de la Plata cratons     

Pieter H. Fourie  Udo Zimmermann  Nicolas J. Beukes  Thanusha Naidoo  Katsuro Kobayashi  Jan Kosler  Eizo Nakamura  Jenny Tait  Johannes N. Theron 《International Journal of Earth Sciences》2011,100(2-3):527-541

In order to facilitate the understanding of the geological evolution of the Kalahari Craton and its relation to South America, the provenance of the first large-scale cratonic cover sequence of the craton, namely the Ordovician to Carboniferous Cape Supergroup was studied through geochemical analyses of the siliciclastics, and age determinations of detrital zircon. The Cape Supergroup comprises mainly quartz-arenites and a Hirnantian tillite in the basal Table Mountain Group, subgreywackes and mudrocks in the overlying Bokkeveld Group, while siltstones, interbedded shales and quartz-arenites are typical for the Witteberg Group at the top of the Cape Supergroup. Palaeocurrent analyses indicate transport of sediment mainly from northerly directions, off the interior of the Kalahari Craton with subordinate transport from a westerly source in the southwestern part of the basin near Cape Town. Geochemical provenance data suggest mainly sources from passive to active continental margin settings. The reconnaissance study of detrital zircons reveals a major contribution of Mesoproterozoic sources throughout the basin, reflecting the dominance of the Namaqua-Natal Metamorphic Belt, situated immediately north of the preserved strata of Cape Supergroup, as a source with Archaean-aged zircons being extremely rare. We interpret the Namaqua-Natal Metamorphic Belt to have been a large morphological divide at the time of deposition of the Cape Supergroup that prevented input of detrital zircons from the interior early Archaean Kaapvaal cratonic block of the Kalahari Craton. Neoproterozoic and Cambrian zircons are abundant and reflect the basement geology of the outcrops of Cape strata. Exposures close to Cape Town must have received sediment from a cratonic fragment that was situated off the Kalahari Craton to the west and that has subsequently drifted away. This cratonic fragment predominantly supplied Meso- to Neoproterozoic, and Cambrian-aged zircon grains in addition to minor Silurian to Lower Devonian zircons and very rare Archaean (2.5?Ga) and late Palaeoproterozoic (1.8-2.0?Ga) ones. No Siluro-Devonian source has yet been identified on the Kalahari Craton, but there are indications for such a source in southern Patagonia. Palaeozoic successions in eastern Argentina carry a similar detrital zircon population to that found here, including evidence of a Silurian to Lower Devonian magmatic event. The Kalahari and Río de la Plata Cratons were thus in all likelihood in close proximity until at least the Carboniferous.  相似文献