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11.
Time domain electromagnetic (TDEM) soundings were utilized in site assessment studies for the purpose of accomplishing two objectives: (1) measuring the migration of brines from oil and gas field evaporation pits, and (2) mapping the continuity of clay strata. Both case histories are representative of common objectives in site assessment. The data for both examples were analyzed by one-dimensional ridge regression inversions.
Both case histories illustrate that TDEM is an effective method for determining the lateral and vertical resistivity distribution (geoelectric section) of the subsurface in the depth range from about 5 m to 100 m, and it is known from other investigations that depths of investigations up to 2500 m can be achieved with TDEM.
Frequently, the lateral extent of contaminant plumes emanating from localized sources are of limited areal extent. The case history involving the use of TDEM to map a brine plume shows that a TDEM measurement has a relatively small zone of influence, so that meaningful information about the lateral and vertical extent of the plume can be obtained. Both case histories demonstrate the ability of TDEM to determine geoelectric sections below layers of low resistivity.  相似文献   
12.
A number of major European rivers (especially the Rhine) have a prevailing influence on the nutrient cycling of most Dutch estuaries. Owing to the increased loading of the estuaries with nitrogen and phosphorus compounds, effects of eutrophication on the biological communities are most evident in the tidal Western Wadden Sea and in a nontidal brackish lagoon, Veerse Meer. Whether the relation between changed nutrient loadings and changed biomass and production of primary and secondary producers in the turbid tidal Dutch ecosystems should be considered as a causal relation is questionable. The very widespread practice of lagoon modification confuses the effects of nutrient loading.  相似文献   
13.
U-Th rich mineral inclusions in apatite are often held responsible for erroneously old (U-Th)/He ages, because they produce “parentless” He. Three aspects associated with this problem are discussed here. First, simple dimensional considerations indicate that for small mineral inclusions, the parentless helium problem might not be as serious as generally thought. For example, a mineral inclusion that is 10% the length, width and height of its host apatite needs to be a thousand times more concentrated in U and Th to produce an equal amount of He. Therefore, single isolated inclusions smaller than a few μm are unlikely to contribute significant helium. For larger or more abundant inclusions, the parentless helium problem can be solved by dissolution of the apatite and its inclusions in hot HF. Second, besides creating parentless helium, inclusions also complicate α-ejection corrections. Mathematical exploration of this latter problem for spherical geometries reveals that for randomly distributed inclusions, the probability distribution of single-grain ages is predicted to have a sharp mode at the mean age, with tails towards younger and older ages. Multiple-grain measurements will yield accurate and precise age estimates if 10 or more randomly distributed α-emitting mineral inclusions are present in a sample. Third, thermal modeling indicates that mineral inclusions have a non-trivial but minor (<5 °C) effect on the closure temperature. These predictions were tested on apatites from rapidly cooled migmatites of Naxos (Greece) which contain abundant U-rich zircon inclusions. Thirty-seven samples were subjected to two kinds of treatment. The “pooled” age (i.e., the synthetic multi-grain age computed from a number of single-grain analyses) of four inclusion-free samples (13 apatites), prepared in HNO3 is 10.9 Ma, close to apatite and zircon fission-track ages from the same rock. (U-Th)/He ages of 14 inclusion-bearing samples dissolved in HNO3 range between 9 and 45 Ma, with a pooled age of 22.6 Ma. The ages of 19 HF-treated samples range between 5 and 16 Ma, with 10 of 14 single-grain samples between 9 and 13 Ma and a pooled age of 10.9 Ma. These observations agree with the theoretical predictions and support the addition of HF-treated apatite (U-Th)/He dating to the thermochronological toolbox.  相似文献   
14.
Surf Scoters and Greater Scaup and samples of species which comprise the major part of their diets, from Iona Island and Roberts Bank tidal flats, near Vancouver, British Columbia, were analysed for metal residues. Significantly higher silver, copper, lead and zinc levels were found in Greater Scaup than Surf Scoters. The latter species had higher mercury levels. Differences in residue levels between the species reflect interspecific variation in prey as well as feeding habitat. Significantly higher silver, mercury, lead and zinc in Surf Scoters and silver and lead in Greater Scaup observed at Iona Island than at Roberts Bank can be explained by higher levels of those metals occurring in a more metal-contaminated prey and sediment near the Iona Island sewer outfall. Ducks feeding on organisms in different intertidal zones show different accumulation of metal residues and constitute valuable indicators of pathways of toxic chemicals in specific estuarine regions.  相似文献   
15.
Cross-country comparison of DDE and PCB residue levels in cormorant, gull and tern eggs in Canada reveal that bird populations at the Great Lakes are most contaminated with those pollutants. DDE levels have been correlated with reproductive failure in Double-crested Cormorants in the Great Lakes with eggshell thinning as a major factor. Low reproductive success in Herring Gull colonies at Lake Ontario is associated with high chlorinated hydrocarbon levels in eggs. Fish-eating birds in the Wabigoon River system, northwestern Ontario, are among the most known mercury contaminated birds. It is suggested that the effects of mercury on the reproduction of fish-eating birds should be further examined there.Fish-eating birds occupy the highest levels of the food web and magnification of toxic chemicals through prey organisms in this web makes those birds vulnerable to the effects of environmental contaminants. Since fish-eating birds are present everywhere in Canada's freshwater and marine habitats and occupy various niches there, they may serve as pollution indicators in various food chains of our aquatic environment. Colonial birds are especially valuable indicators as pollution effects on total bird populations can be studied. Baseline information on fish-eating bird populations should now be collected everywhere in Canada for measuring present and future effects of environmental pollutants, as well as other man-made disturbances on their populations.  相似文献   
16.
There are various types of the windblown sediment traps developed for wind tunnel and field studies. One of the main supports expected from these traps is in measuring surface dust concentrations to appropriately derive flux equations. The measurement performance and accuracy of a trap is very important and depends strictly upon the physical characteristics and the behaviors of dust grains with air flows. This paper presents the measurement results of static pressure distribution (SPD) of wind flow around Vaseline-coated slide (VCS) catchers with an aim of finding out whether or not particle trapping efficiency (η) of the VCS is related to the SPD. The SPD was evaluated by a wind reduction coefficient (R c) in a series of wind tunnel experiments with different VCS settings which have different attachment configurations on a pole. Three VCS configurations were considered: a configuration on a circular plastic pole (CPP) and two configurations on wooden square poles (WSP1 and WSP2, respectively). Thus, the primary contribution of this work was to experimentally analyze the effect of the different attachment configurations on the SPD, and the secondary objective was to determine the effect of the SPD on the η. It was shown that spatial correlation and spatial pattern of the R c were different in the surrounding area of each configuration, and ANOVA and DUNCAN tests indicated that η(s) of WSP1, WSP2, and CPP were different at the significant level of P ≤ 0.05 with the mean of 0.94 ± 0.09, 0.63 ± 0.14, and 1.13 ± 0.07, respectively. Additionally, the amount of PM20, PM40, PM60, PM80, and PM100 trapped by the configurations of WSP1, WSP2, and CPP considerably varied depending upon the particular aerodynamic circumstances associated with every configuration.  相似文献   
17.
The 18O/16O ratio of CO2 is a potentially powerful tracer of carbon dioxide fluxes from the soil to the atmosphere, which is influenced by complex interactions involving both biotic and abiotic soil processes. We use a simplified experimental approach and numerical simulations to examine in isolation the 18O exchange between CO2 and soil water associated with the abiotic invasion of atmospheric CO2 into soil. This allowed us to verify, in particular, whether the 18O of the retro-diffusion flux of CO2 from the soil reflects 18O equilibration with water at the soil surface, or at some depth. Sterile soil samples with known water isotopic composition were placed in a closed box attached to a specially designed flow chamber and the changes in δ18O of CO2 between the chamber inlet and outlet, due only to invasion effects, were determined. Numerical simulations constrained by the laboratory gas exchange measurements indicated that between the two commonly used diffusion models [Penman, H.L. (1940). Gas and vapor movements in soil, 1: the diffusion of vapors through porous solids. Int. J. Agric. Sci.30, 437-462; Moldrup, P., Olesen, T., Yamaguchi, T., Schjonning, P., Rolston, D.E. (1999). Modeling diffusion and reaction in soils, IX, the Backingham-Burdine-Campbell equation for gas diffusivity in undisturbed soil. Soil Sci.164, 542-551], only the former provided good agreement with the measurements over a wide range of soil water contents. Based on the model calculations constrained by experimental data, and on comparison of characteristic diffusion/reaction times, we conclude that the depth required for full CO2-water 18O equilibration ranges between 2 and 8.5 cm. The depth depends, in order of importance, on (1) soil moisture content; (2) temperature, which dominates the rate of hydration isotopic exchange; (3) CO2 residence time, which is determined by the time of replacement of the column air above the soil; and (4) soil structure, including porosity, tortuosity and grain size, with the later probably influencing the water surface area exposed to CO2 exchange. Using field data from a semi-arid forest site in Israel, numerical simulations indicated that the 18O full equilibrium depth varied at this site between 4 cm (January) and 8 cm (November), being sensitive mostly to temperature and soil water content. Deepening of the equilibration depth as the soil dries should limit the effects of 18O evaporative enrichment at the surface on the isotopic composition of the soil-atmosphere CO2 flux.  相似文献   
18.
The Bonneville Basin is a continental lacustrine system accommodating extensive microbial carbonate deposits corresponding to two distinct phases: the deep Lake Bonneville (30 000 to 11 500 14C bp ) and the shallow Great Salt Lake (since 11 500 14C bp ). A characterization of these microbial deposits and their associated sediments provides insights into their spatio‐temporal distribution patterns. The Bonneville phase preferentially displays vertical distribution of the microbial deposits resulting from high‐amplitude lake level variations. Due to the basin physiography, the microbial deposits were restricted to a narrow shoreline belt following Bonneville lake level variations. Carbonate production was more efficient during intervals of relative lake level stability as recorded by the formation of successive terraces. In contrast, the Great Salt Lake microbial deposits showed a great lateral distribution, linked to the modern flat bottom configuration. A low vertical distribution of the microbial deposits was the result of the shallow water depth combined with a low amplitude of lake level fluctuations. These younger microbial deposits display a higher diversity of fabrics and sizes. They are distributed along an extensive ‘shore to lake’ transect on a flat platform in relation to local and progressive accommodation space changes. Microbial deposits are temporally discontinuous throughout the lake history showing longer hiatuses during the Bonneville phase. The main parameters controlling the rate of carbonate production are related to the interaction between physical (kinetics of the mineral precipitation, lake water temperature and runoff), chemical (Ca2+, Mg2+ and HCO3? concentrations, Mg/Ca ratio, dilution and depletion) and/or biological (trophic) factors. The contrast in evolution of Lake Bonneville and Great Salt Lake microbial deposits during their lacustrine history leads to discussions on major chemical and climatic changes during this interval as well as the role of physiography. Furthermore, it provides novel insights into the composition, structure and formation of microbialite‐rich carbonate deposits under freshwater and hypersaline conditions.  相似文献   
19.
The Late Pleistocene stratigraphy from the Severnaya Dvina‐Vychegda region of northwestern Russia is revised based on investigations of new localities, revisiting earlier localities, introduction of about 110 new OSL dates and burial depth corrections of earlier published OSL dates, in addition to six new radiocarbon dates. Most of the OSL samples studied here are from fluvial and subaquaeous sediments, which we found to be well bleached. Six chronostratigraphical units and their sedimentary environment are described, with the oldest unit consisting of pre‐Eemian glacial beds. For the first time, Early Weichselian sediments are documented from the region and a fluvial environment with some vegetation and permafrost conditions is suggested to have persisted from the end of the Eemian until at least about 92 ka ago. The period in which a Middle Weichselian White Sea Lake could have existed is constrained to 67?62 ka, but as the lake level never reached the thresholds of the drainage basin, the lake probably existed only for a short interval within this time‐span. Blocking and reversal of fluvial drainage started again around 21?20 ka ago when the Fennoscandian Ice Sheet advanced into the area, reaching its maximum 17?15 ka ago. At that time, an ice‐dammed lake reached its maximum water level, which was around 135 m above present sea level. Drainage of the lake started shortly after 15 ka ago, and the lake was emptied within 700 years. Severe periglacial conditions, with permafrost and aeolian activity, prevailed in the area until about 10.7 ka.  相似文献   
20.
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