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The proportion of water younger than 2–3 months (young water fraction, Fyw) has become increasingly investigated in catchment hydrology. Fyw is typically estimated by comparing seasonal tracer cycles in precipitation and streamflow, through water sampling. However, some open research questions remain, such as: (i) whether part of the summer precipitation should be discarded because the high evapotranspiration demand, (ii) how well Fyw serves as a metric to compare catchments, and (iii) how sampling frequency affects Fyw estimates. To address these questions, we investigated Fyw in soil-, ground- and stream waters for the small Mediterranean Can Vila catchment. Rainfall was sampled at 5-mm intervals. Mobile soil water and groundwater were sampled fortnightly. Stream water was sampled depending on flow at variable time intervals (30 min to 1 week). Over 58 months, this sampling provided 1,529 δ18O determinations. Isotopic analyses results led us to include summer precipitation in the input signal. We found the highest Fyw in mobile soil waters (34%), while this was almost zero for groundwater except during wet periods. For stream waters, Fyw depended on the discharge variations, so that the flow-weighted young water fraction () was 22.6%, whereas the time-weighted Fyw was just 6.2%. Both and its discharge sensitivity (Sd) varied when different 12-month sampling periods were investigated. The young water fraction that would be obtained from a virtual thorough sampling () was estimated from the Sd and the observed stream flow. This showed an underestimation of by 25% for the frequent dynamic sampling and 66% for weekly sampling, due to missing high flows. Our results confirm that Fyw and its discharge sensitivity are metrics very sensitive to meteorological forcing during the analysed period. Thus, comparisons between catchments need long-term mean annual values and their variability. Our findings also support the dependence of Fyw estimates on the sampling rate and show the advantages of flow-weighted analysis. Finally, catchment water turnover investigations should be accompanied by the analysis of flow duration curves.  相似文献   
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ABSTRACT

Data on land use and land cover (LULC) are a vital input for policy-relevant research, such as modelling of the human population, socioeconomic activities, transportation, environment, and their interactions. In Europe, CORINE Land Cover has been the only data set covering the entire continent consistently, but with rather limited spatial detail. Other data sets have provided much better detail, but either have covered only a fraction of Europe (e.g. Urban Atlas) or have been thematically restricted (e.g. Copernicus High Resolution Layers). In this study, we processed and combined diverse LULC data to create a harmonised, ready-to-use map covering 41 countries. By doing so, we increased the spatial detail (from 25 to one hectare) and the thematic detail (by seven additional LULC classes) compared to the CORINE Land Cover. Importantly, we decomposed the class ‘Industrial and commercial units’ into ‘Production facilities’, ‘Commercial/service facilities’ and ‘Public facilities’ using machine learning to exploit a large database of points of interest. The overall accuracy of this thematic breakdown was 74%, despite the confusion between the production and commercial land uses, often attributable to noisy training data or mixed land uses. Lessons learnt from this exercise are discussed, and further research direction is proposed.  相似文献   
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Although the galvanic distortion due to local, near-surface inhomogeneities is frequency-independent, its effect on the magnetotelluric data becomes, in a 3-D structure, frequency-dependent. Therefore, both the apparent resistivity and the phase responses are disturbed, and a correction should be carried out prior to the 3-D interpretation in order to retrieve the 3-D regional impedance tensor. In many cases, the structure is 2-D for depths corresponding to a first range of periods and 3-D for longer periods (called 2-D/3-D). For these cases, a simple method which allows us to retrieve the 3-D regional impedance tensor (except the static shift) is presented. The method proposed uses the Groom & Bailey decomposition of the distortion matrix for the short periods. Three examples are presented: two using synthetic data and one employing real data. These examples show the effect of the galvanic distortion over a regional 2-D/3-D model and the retrieval of the regional transfer functions from the distorted ones.  相似文献   
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Several two-dimensional structures are modelled for vertical electrical soundings in arrays parallel and perpendicular to the strike of the structure. The models are a horst and a graben within a three-layer medium, a cliff over two layers, and heterogeneities around the electrodes. Apparent resistivity curves are shown for different model parameters and different distances to the two-dimensional structures. Some of the features on the shape of these curves are inflections that may be misinterpreted as fictitious layers, of slopes greater than 45°; some features are simply anomalous peaks. One-dimensional interpretation of a two-dimensional graben model has been performed, in order to show typical errors when 2D structures are interpreted as one-dimensional. A real case corresponding to a landfill near Barcelona and showing strong lateral and topographic effects is presented. This represents combined effects of the above theoretical 2D models.  相似文献   
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Une méthode spectrométrique d'émission atomique à plasma conductif a été appliquée pour l'analyse multiélementaire des échantillons USGS GXR-1 à 6. Cette méthode permet de déterminer simultanément 22 éléments: Ag, As, B, Ba, Be, Cd, Co, Cr, Cu, Fe, Mn, Mo, Nb, Ni, P, Pb, Sb, Sn, V, W, Y et Zn, au niveau de traces (ppm) et le Fe en (%). Les résultats obtenus démontrent une bonne concordance avec les valeurs préalablement publiées.  相似文献   
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