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131.
An outdoor experiment testing the effect of water flea (Daphnia longispina) and zebra mussels (Dreissena polymorpha) on physical and chemical water parameters and chlorophyll concentration changes was carried out in 12 containers filled with 150 l of unfiltered water from a lowland reservoir. During the 11 weeks of the experiment, the following physical, chemical and biological measurements were recorded: temperature (°C), oxygen concentration (mg dm−3), pH, conductivity (S cm−1), concentration of phosphate phosphorus (PO4-P) and ammonia nitrogen (NH4-N) (g dm−3), total nitrogen (TN) and total phosphorus (TP) (g dm−3), phytoplankton community structure and chlorophyll a concentration (g dm−3). The amount of ammonia ions was the highest in the treatment with zooplankton, while phosphate ions reached the highest values in treatments with zebra mussels. The results confirmed the ability of Daphnia to increase the NH4:PO4 ratio, whereas excretion from zebra mussels resulted in a decrease in both the N:P ratio (ranging from 9 to 13) and the NH4:PO4 ratio in water. In both treatments containing zebra mussels, P-rich water enabled sudden growth of Chlorophyta, resulting in blooms of Hydrodictyon reticulatum after 3–4 weeks of the experiment. Such phenomena were not observed in the control and Daphnia treatments. Our results indicate that zebra mussels, in contrast to Daphnia, may increase the symptoms of water eutrophication and contribute to blooms of expansive phytoplankton species.  相似文献   
132.
The mass-dependent equilibrium stable isotope fractionation between different materials is an important geochemical process. Here we present an efficient method to compute the isotope fractionation between complex minerals and fluids at high pressure, P, and temperature, T, representative for the Earth’s crust and mantle. The method is tested by computation of the equilibrium fractionation of lithium isotopes between aqueous fluids and various Li bearing minerals such as staurolite, spodumene and mica. We are able to correctly predict the direction of the isotope fractionation as observed in the experiments. On the quantitative level the computed fractionation factors agree within 1.0‰ with the experimental values indicating predictive power of ab initio methods. We show that with ab initio methods we are able to investigate the underlying mechanisms driving the equilibrium isotope fractionation process, such as coordination of the fractionating elements, their bond strengths to the neighboring atoms, compression of fluids and thermal expansion of solids. This gives valuable insight into the processes governing the isotope fractionation mechanisms on the atomic scale. The method is applicable to any state and does not require different treatment of crystals and fluids.  相似文献   
133.
Measurements of erythemal irradiance have been carried out continuously at Belsk since May 1975. We present a homogenization procedure of the UV time series for the period of 1976–2008. Long-term oscillations discovered in the homogenized data set agree with those extracted from the reconstructed UV data for all-sky and clear-sky conditions. The UV climatology was established and the UV variability was determined. Positive UV trends were found for the period of 1976-2008 in the annual mean (5.6±0.9% per decade), in the seasonal mean for the warm subperiod of the year (April–October, 5.5±1.0% per decade), and in monthly means (∼2–9% per decade). A satisfactory agreement between the trend extracted from the homogenized ground-based data and that found in satellite UV data for Belsk (1979–2008) supports the reliability of satellite trend analyses over wider areas during snowless periods.  相似文献   
134.
The Densu River Basin (DRB) is an important agricultural area in Ghana and has a high population density. Water shortages have occurred in the basin due to drying out of surface water, heavy pollution and low yield in most of the production wells, which are crucial factors restricting sustainable socioeconomic development. This study was carried out to investigate the geochemical characteristics and evolution, as well as recharge processes in the DRB system with regard to the tectonics, geomorphology, lithology and flow system. It mainly used hydrochemistry, environmental isotopes and a series of comprehensive data interpretation, e.g., statistics, ionic ratios and Piper diagram to obtain a better understanding of the functioning of the system. The following hydrochemical processes were identified as the main factors controlling the water quality of the groundwater system: weathering of silicate minerals, dissolution, ion exchange and, to a lesser extent, evaporation, which seems to be more pronounced downgradient of the flow system. As groundwater flows from the recharge to discharge areas, chemical patterns evolve in the order of Ca2+–HCO3 ?, Ca2+/Mg2+–HCO3 ? to Ca2+/Na+–Cl?, Ca2+–Na+–HCO3 ? and Na+–Cl? according to lithology. The environmental isotope (δ18O, δ2H, 3H) measurements further revealed that groundwater in the DRB was a relatively well-mixed system as evidenced by the encoded narrow range of values. However, deviation from the rainwater signature indicates combined local processes such as direct percolation through preferential channels, evaporation, and probable surface water and anthropogenic contribution to the system.  相似文献   
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137.
In this study, the CDOM absorption coefficient at 350 nm [aCDOM(350)] and CDOM excitation emission matrix (EEM) fluorescence were used to estimate annual fluxes of dissolved organic carbon (DOC) from the Cape Fear River to Long Bay in the South Atlantic Bight. Water samples were collected during a 3.5 year period, from October 2001 through March 2005, in the vicinity of the Cape Fear River (CFR) outlet and adjacent Onslow Bay (OB). Parallel factor analysis (PARAFAC) of CDOM EEM spectra identified six components: three terrestrial humic-like, one marine humic-like and two protein-like. Empirical relationships were derived from the PARAFAC model between DOC concentration and aCDOM(350), total fluorescence intensity and the intensities of respective EEM components. DOC concentration and CDOM optical parameters were very well correlated and R2 values ranged from 0.77 to 0.90. Regression analyses revealed that the non-absorbing DOC fraction, in DOC concentration estimated from CDOM optical parameters, varied with the qualitative composition of the CDOM. DOC concentration and intensity of the humic-like CDOM components characterized by excitation maxima at longer wavelengths have significantly higher estimated non-absorbing DOC compared to the analogous relationships between DOC and intensity of the humic-like CDOM components characterized by excitation maxima at shorter wavelengths. The relationships between DOC concentration and intensity of one of the protein-like components resulted in significantly reduced non-absorbing DOC fraction in DOC concentration estimation. Results of regression analyses between fluorescence intensities of specific EEM components and CDOM-specific absorption coefficients suggest that the relative proportion of humic-like CDOM components (characterized by excitation maximum at longer wavelengths) and the main protein-like component have the most impact on the values of a?CDOM(350). Based on the relationships between aCDOM(350), Cape Fear River flow, and DOC concentrations, DOC fluxes were estimated for 2002, 2003 and 2004. DOC fluxes varied from 1.5 to 6.2 × 1010 g C yr? 1, depending on river flow.  相似文献   
138.
I explore the consequences of making the RR Lyrae and clump giant distance scales consistent in the solar neighbourhood, Galactic bulge and Large Magellanic Cloud (LMC). I employ two major assumptions: (i) that the absolute magnitude–metallicity, M V (RR)–[Fe/H], relation for RR Lyrae stars is universal, and (ii) that absolute I magnitudes of clump giants, M I (RC), in Baade's Window are known (e.g. can be inferred from the local Hipparcos -based calibration or theoretical modelling). A comparison between the solar neighbourhood and Baade's Window sets M V (RR) at [Fe/H]=−1.6 in the range (0.59±0.05, 0.70±0.05), somewhat brighter than the statistical parallax solution. More luminous RR Lyrae stars imply younger globular clusters, which would be in better agreement with the conclusions from the currently favoured stellar evolution and cosmological models. A comparison between Baade's Window and the LMC sets M LMC(RC) I in the range (−0.33±0.09,−0.53±0.09). The distance modulus to the LMC is μ LMC∈(18.24±0.08,18.44±0.07). Unlike M LMC(RC) I , this range in μ LMC does not depend on the adopted value of the dereddened LMC clump magnitude, I LMC(RC)0. I argue that the currently available information is insufficient to select the correct distance scale with high confidence.  相似文献   
139.
It is examined whether the destruction of heterogeneous cometary grains can explain the variation of cometary brightness and comet outburst.Calculations were carried out for water ice grains with carbonoxideinclusions. It was shown that for realistic chosen values of parametersthe comet luminosity can increase by even a few stellar magnitudes.  相似文献   
140.
The Schmidt hammer is a useful tool applied by geomorphologists to measure rock strength in field conditions. The essence of field application is to obtain a sufficiently large dataset of individual rebound values, which yields a meaningful numerical value of mean strength. Although there is general agreement that a certain minimum sample size is required to proceed with the statistics, the choice of size (i.e. number of individual impacts) was usually intuitive and arbitrary. In this paper we show a simple statistical method, based on the two‐sample Student's t‐test, to objectively estimate the minimum number of rebound measurements. We present the results as (1) the ‘mean’ and ‘median’ solutions, each providing a single estimate value, and (2) the empirical probability distribution of such estimates based on many field samples. Schmidt hammer data for 14 lithologies, 13–81 samples for each, with each sample consisting of 40 individual readings, have been evaluated, assuming different significance levels. The principal recommendations are: (1) the recommended minimum sample size for weak and moderately strong rock is 25; (2) a sample size of 15 is sufficient for sandstones and shales; (3) strong and coarse rocks require 30 readings at a site; (4) the minimum sample size may be reduced by one‐third if the context of research allows for higher significance level for test statistics. Interpretations based on less than 10 readings from a site should definitely be avoided. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
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