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21.
Francisco J. Gonzlez-Vila Oliva Polvillo Tomasz Boski Delminda Moura Jos R. de Andrs 《Organic Geochemistry》2003,34(12):1601-1613
The vertical distribution of terrestrial and phytoplankton biomarker compounds in a sediment core from the coastal estuarine zone of the Guadiana river (southwest border between Portugal and Spain) was determined by gas chromatography–mass spectrometry. Significant downcore fluctuations were observed in the patterns of the most abundant alkyl series (n-alkanes and n-fatty acids), as well as in several biomarker ratios. In addition, a specific contribution from conifers is reflected in the presence of a resin acid series that first appears 6500 years BP. The observed changes in the lipid assemblage within the Holocene suggest recent variations in the planktonic and terrigenous supply, which are attributed mainly to the evolution of the circulation pattern in the estuary and to the alteration of vegetation cover within the Guadiana drainage basin. Our data suggest that on a 103–104 year time-scale, little or no diagenetic change occurred with respect to the compounds in question. 相似文献
22.
A search for cheap and efficient method to monitor atmospheric particulates in city centres has raised new interest to measure foliar element concentrations after the role of particulate pollution for respiratory illnesses was discovered. Leaf samples of Golden dewdrop (Duranta repens L.) collected in Palermo (South of Italy) between 1998 and 2000 were analysed to study the possible use of this shrub as a passive biomonitor for atmospheric pollution in urban areas. Concentrations of Ba, Cd, Cu, Fe, Mg, Mn, Pb and Zn were determined from leaf samples collected from six sampling sites representing either (a) areas of high traffic density or (b) areas not directly affected by the city traffic (e.g. gardens). Most of the elements showed a significant temporal variation but no consistent trends could be seen, i.e. the highest (or lowest) values were not detected consistently at some particular time of the year. Furthermore temporal changes were of same magnitude in polluted versus less polluted areas; no statistically significant interaction between pollution level and collection period was detected. Pollution level (traffic density) was the primary factor to explain spatial variation only in the case of foliar Mg concentrations. On the other hand, variation in foliar concentrations between sampling sites (irrespective of the pollution level) was large. Our results suggest that particulate deposition needs to be quite high before spatial segregation can be done on the basis of foliar element concentrations. 相似文献
23.
Franscisco?ValadezEmail author Guadalupe?Oliva Gloria?Vilaclara Margarita?Caballero Dení Claudia?Rodríguez 《Journal of Paleolimnology》2005,34(2):147-157
Stephanodiscus niagarae is frequently reported from late Pleistocene (>10,000 yr BP) sediments in central Mexico, with lower abundances through the Holocene. Its presence in Holocene and modern environments in central Mexico was not well documented until our study, where we report on three populations of S. niagarae, one middle Holocene population with particularly high abundance from the Upper Lerma Basin, and two modern sites, Valle de Bravo and Santa Elena. The three sites are located in the same geographical area, in the State of Mexico. The fossil material dates to ca. 6600–4900 yr BP, with S. niagarae reaching up to 90% of the diatom counts. Stephanodiscus niagarae is present in association with Fragilaria pinnata, F. brevistriata, and Aulacoseira granulata. In Valle de Bravo (ca. 30 m deep) S. niagarae is present in very low numbers in water column and surface sediments samples (<1%); the diatom assemblage is dominated by Fragilaria crotonensis in association with A. granulata, A. granulata var. curvata and Cyclotella ocellata. In Santa Elena, a shallow, intermittent irrigation channel, S. niagarae is the second most abundant alga; the diatom assemblage is dominated by S. niagarae in association with A. granulata, A. granulata var. curvata and F. crotonensis. Both modern sites show a trend to eutrophy and these diatom assemblages are taken as indicative of this trend. It is suggested researchers should be cautions when the presence of S. niagarae in sedimentary records is taken as indicative of deep waters conditions, as the present data show that this species can thrive in rather shallow environments in Mexico. 相似文献
24.
Aurélie Violette Jean Riotte Jean-Jacques Braun Priscia Oliva Jean-Christophe Marechal M. Sekhar Catherine Jeandel Jonathan Prunier Laurent Barbiero Bernard Dupre 《Geochimica et cosmochimica acta》2010,74(24):7059-7085
The influence of the pedogenic and climatic contexts on the formation and preservation of pedogenic carbonates in a climosequence in the Western Ghats (Karnataka Plateau, South West India) has been studied. Along the climosequence, the current mean annual rainfall (MAR) varies within a 80 km transect from 6000 mm at the edge of the Plateau to 500 mm inland. Pedogenic carbonates occur in the MAR range of 500-1200 mm. In the semi-arid zone (MAR: 500-900 mm), carbonates occur (i) as thick hardpan calcretes on pediment slopes and (ii) as nodular horizons in polygenic black soils (i.e. vertisols). In the sub-humid zone (MAR: 900-1500 mm), pedogenic carbonates are disseminated in the black soil matrices either as loose, irregular and friable nodules of millimetric size or as indurated botryoidal nodules of centimetric to pluricentimetric size. They also occur at the top layers of the saprolite either as disseminated pluricentimetric indurated nodules or carbonate-cemented lumps of centimetric to decimetric size.Chemical and isotopic (87Sr/86Sr) compositions of the carbonate fraction were determined after leaching with 0.25 N HCl. The corresponding residual fractions containing both primary minerals and authigenic clays were digested separately and analyzed. The trend defined by the 87Sr/86Sr signatures of both labile carbonate fractions and corresponding residual fractions indicates that a part of the labile carbonate fraction is genetically linked to the local soil composition. Considering the residual fraction of each sample as the most likely lithogenic source of Ca in carbonates, it is estimated that from 24% to 82% (55% on average) of Ca is derived from local bedrock weathering, leading to a consumption of an equivalent proportion of atmospheric CO2. These values indicate that climatic conditions were humid enough to allow silicate weathering: MAR at the time of carbonate formation likely ranged from 400 to 700 mm, which is 2- to 3-fold less than the current MAR at these locations.The Sr, U and Mg contents and the (234U/238U) activity ratio in the labile carbonate fraction help to understand the conditions of carbonate formation. The relatively high concentrations of Sr, U and Mg in black soil carbonates may indicate fast growth and accumulation compared to carbonates in saprolite, possibly due to a better confinement of the pore waters which is supported by their high (234U/238U) signatures, and/or to higher content of dissolved carbonates in the pore waters. The occurrence of Ce, Mn and Fe oxides in the cracks of carbonate reflects the existence of relatively humid periods after carbonate formation. The carbonate ages determined by the U-Th method range from 1.33 ± 0.84 kyr to 7.5 ± 2.7 kyr and to a cluster of five ages around 20 kyr, i.e. the Last Glacial Maximum period. The young occurrences are only located in the black soils, which therefore constitute sensitive environments for trapping and retaining atmospheric CO2 even on short time scales. The maximum age of carbonates depends on their location in the climatic gradient: from about 20 kyr for centimetric nodules at Mule Hole (MAR = 1100 mm/yr) to 200 kyr for the calcrete at Gundlupet (MAR = 700 mm/yr, Durand et al., 2007). The intensity of rainfall during wet periods would indeed control the lifetime of pedogenic carbonates and thus the duration of inorganic carbon storage in soils. 相似文献
25.
I. Carleo N. Sanna R. Gratton S. Benatti M. Bonavita E. Oliva L. Origlia S. Desidera R. Claudi E. Sissa 《Experimental Astronomy》2016,41(3):351-376
Radial velocities (RV) measured from near-infrared (NIR) spectra are a potentially excellent tool to search for extrasolar planets around cool or active stars. High resolution infrared (IR) spectrographs now available are reaching the high precision of visible instruments, with a constant improvement over time. GIANO is an infrared echelle spectrograph at the Telescopio Nazionale Galileo (TNG) and it is a powerful tool to provide high resolution spectra for accurate RV measurements of exoplanets and for chemical and dynamical studies of stellar or extragalactic objects. No other high spectral resolution IR instrument has GIANO’s capability to cover the entire NIR wavelength range (0.95-2.45 μm) in a single exposure. In this paper we describe the ensemble of procedures that we have developed to measure high precision RVs on GIANO spectra acquired during the Science Verification (SV) run, using the telluric lines as wavelength reference. We used the Cross Correlation Function (CCF) method to determine the velocity for both the star and the telluric lines. For this purpose, we constructed two suitable digital masks that include about 2000 stellar lines, and a similar number of telluric lines. The method is applied to various targets with different spectral type, from K2V to M8 stars. We reached different precisions mainly depending on the H-magnitudes: for H ～ 5 we obtain an rms scatter of ～ 10 m s?1, while for H ～ 9 the standard deviation increases to ～ 50 ÷ 80 m s?1. The corresponding theoretical error expectations are ～ 4 m s?1 and 30 m s?1, respectively. Finally we provide the RVs measured with our procedure for the targets observed during GIANO Science Verification. 相似文献
26.
Succession and seasonal onset of colonization in subtidal hard‐bottom communities off northern Chile
Aldo S. Pacheco Jürgen Laudien Martin Thiel Marcelo Oliva Olaf Heilmayer 《Marine Ecology》2011,32(1):75-87
Although there is extensive information concerning the colonization sequences of benthic communities, little is known about the successional development of subtidal hard‐bottom habitats in highly productive coastal upwelling areas. In these systems, succession is predicted to be fast due to high growth rate of the later dominant colonizers. Using artificial hard substrata a field experiment was conducted in a rocky subtidal area off Northern Chile (Humboldt Current System) and monitored at 3‐month intervals to test the following hypotheses: (i) epibenthic succession may proceed through consecutive replacement of species, (ii) there is a fast convergence rate towards natural communities, and (iii) different seasonal starting points for the colonization will produce different community structure over a 1‐year period of exposure. Panels were installed on a vertical wall at 17 m water depth. Three replicate panels were sampled every 3 months over a period of 27 months. As a reference, six haphazardly selected plots from the surrounding natural community were surveyed at each sampling date. To evaluate how seasonally varying substratum availability affects community development, further panels were exposed for a 12‐month period, starting in four different seasons (n = 3 replicates per season). Community succession was slow and occurred through progressive changes, between early encrusting red corallines, middle Balanus flosculus and late Lagenicella variabilis. After 27 months, the community composition, but not its structure, was similar between experimental and reference communities on surrounding rocky bottoms. Seasonality had no effects and after 1 year of exposure the experimental communities converged towards a common structure. This study indicates that succession of subtidal epibenthic communities follows a slow and predictable pattern with a dominant late colonial species. In addition, aseasonal variability might be more relevant during colonization and succession in this upwelling ecosystem. 相似文献
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28.
E. Oliva S. Drapatz D. Lutz E. Sturm A.F.M. Moorwood 《Astrophysics and Space Science》1997,255(1-2):211-219
ISO spectra of the supernova remnant RCW103 are presented. This object is the prototype of a SNR shock heavily interacting
with dense ISM (probably a molecular cloud). The spectra are dominated by prominent lines and show very little continuum at
λ < 40 μm suggesting that the 12 and 25 μm IRAS emission from these types of remnant could be dominated by lines rather than
continuum emission from warm dust heated by the shock as generally believed. The ISO data provide for the first time a simple
and reliable estimate of the gas phase abundances of Si and Fe which are found to be close to solar relative to non refractory
species such as Ne, S and Ar. This indicates that the shock is very effective in destroying the ISM dust and may therefore
explain the absence of warm dust behind the shock. Like the optical Nickel lines, [NiII]6.63 μm yields Ni/Fe abundances a
factor ≥ 10 above solar which we conclude results from a large underestimation of the computed Ni+ collision strengths.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
29.
Giulia Schettino Ernesto Oliva Massimo Inguscio Carlo Baffa Elisabetta Giani Andrea Tozzi Pablo Cancio Pastor 《Experimental Astronomy》2011,31(1):69-81
A spectrally filtered Optical Frequency Comb (OFC) laser is proposed as a versatile calibration source for astronomical spectrometers in the 1?C2 ??m spectral range. Such a source overcomes the limitations of current calibration lamps providing a uniform spectrum of equally spaced lines with similar intensity and extremely high long-term frequency stability. We present preliminary studies and results of a system which filters the OFC from a 100 MHz comb spacing to 16 GHz one, an adequate spacing for spectrometers with resolving power ????/???>30000. The first approach employs two Fabry-Perot cavities in series, made of dielectric coated mirrors, followed by a non-linear optical broadening system. The limitations of such a filtering process are discussed. These can be overcome by the second approach, based on filtering cavities with metallic coated mirrors. 相似文献
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