Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems     

Liyuan Liang  James J. Morgan 《Aquatic Sciences - Research Across Boundaries》1990,52(1):32-55

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.  相似文献   

察尔汗盐湖低品位卤水自然蒸发试验研究   总被引：1，自引：3，他引：1       下载免费PDF全文

张兆广  祁燕 《盐湖研究》2006,14(1):17-23

察尔汗盐湖是一个以卤水钾镁盐矿为主的大型综合性盐类矿床,盐湖东部潜卤水水化学类型为氯化物型,从KCl等组份含量来看,属低钾高钠低镁的卤水。对该类型卤水进行自然蒸发试验,确定盐类结晶析出顺序和光卤石矿物的最佳分离点,取得光卤石矿的产率和光卤石中KCl含量等基础数据,以对该卤水工业利用性能作出评价。  相似文献   

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes     

Zachary Morgan  Yan Liang  Paul Hess 《Geochimica et cosmochimica acta》2006,70(13):3477-3491

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.  相似文献   

云南元-磨公路某高堑坡灾害发生机制及防治对策     

齐明柱 《中国地质灾害与防治学报》2006,17(2):19-22

论文根据现场地质调查,应用地质力学分析方法,分析了元-磨公路K235 160~600段高堑坡地质条件、病害发生机制和诱发因素。堑坡所在区域位于红河深大断裂与哀牢山深大断裂所夹持的哀牢山褶皱带内,属强烈侵蚀切割的低中山区,河流下切严重,河流阶地不发育。南溪河及其支流小曼萨河、叉河依附于不同时期生成的构造发育而成,堑坡位于小曼萨河注入南溪河的交汇部位小曼萨河的左岸。小曼萨河及南溪河所夹持的山体,尤其是堑坡所在的部位,已严重破碎、松弛,岩石似大块石堆垒状,坡面上的树木均明显地向小曼萨河方向倾倒。经地质力学配套分析,堑坡所依附的山梁形成于红河深大断裂生成期(γ4),堑坡岩体受多期构造活动的作用,其中NW65/°SW64°及NW63/°SW35°两组倾向临空的构造面控制坡体的稳定。堑坡具备发生变形破坏的地质条件,分析认为由于组成坡体的岩土强度不足而引起既有构造面的大型坍塌。连续降雨及温差是诱发因素。基于目前国内边坡防治技术、施工能力,提出了以“治”或“避”为主的防治对策。  相似文献   

弯道超高法在泥石流流速计算中的应用——以四川省汶川县G317国道磨子沟泥石流为例     

丁明涛  陈宁生  韦方强  齐云龙 《中国地质灾害与防治学报》2006,17(3):147-149,164

选取四川省汶川至马尔康公路线的磨子沟作为试验对象,采用弯道超高法推算其泥石流流速。进而可以计算出该次泥石流的平均流量,为公路的改建工程提供设计依据。经过实地调查,用此方法计算磨子沟2005年8月17日暴发的泥石流流速为4.4m/s。同其他流速方法计算的结果相比较,前者值偏大,且偏向于工程安全值。弯道超高法可以解决泥石流观测的局限性和泥石流发生的不可重复性。此方法简便易行,对泥石流防治工程具有一定的实用价值。  相似文献   

下庄铀矿田337矿床成矿流体稀土元素示踪     

张国玉  王正其  梁良 《华东地质学院学报》2006,29(1):27-31

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。  相似文献   

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit     

梁华英  喻亨祥  莫测辉  张玉泉  谢应雯 《中国地球化学学报》2006,25(3):223-229

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…  相似文献   

鄱阳盆地构造—沉积特征及其演化史   总被引：3，自引：3，他引：3       下载免费PDF全文

梁兴  叶舟  吴根耀  郑华平  徐克定  张廷山  刘家铎 《地质科学》2006,41(3):404

 鄱阳盆地是发育在江南—九岭和怀玉—官帽基底拆离造山带上的白垩-古近纪张扭性断陷盆地,明显受近南北走向的赣江走滑断裂系和前白垩系逆冲断裂系晚期反转的双重因素控制,呈“两坳夹一隆”的区域构造格局。受赣江、进贤—石门街走滑断裂夹持的南昌凹陷,呈近南北向凹凸相间展布格局。进贤—石门街走滑断裂以东地区,“南断北超”型断陷自南而北由北东走向渐转为北北东向展布,其源于晚印支-燕山期北东向逆冲断裂在晚期的反转作用,西缘和北部受赣江断裂系东枝走滑断裂影响明显而发生转向。鄱阳盆地经历了早白垩世晚期(冷水坞组沉积期)拉分盆地、晚白垩世早-中期(周家店组—南雄组沉积早期)走滑张扭断(坳)陷盆地、晚白垩世晚期(南雄组沉积中-晚期)走滑伸展盆地和古近纪坳陷盆地等演化阶段,东南部断陷区(江埠—二甲村凹陷)由于喜马拉雅期的隆升剥蚀而只残存周家店组早期坳陷和周家店组中期—南雄组中期断陷两个发育阶段的沉积。  相似文献   

用BP神经网络预测土抗剪强度指标c、ψ   总被引：1，自引：0，他引：1  

张高峰  梁宾桥  谌会芹 《岩土工程技术》2006,20(1)

提出了应用BP神经网络来预测土抗剪强度指标c、ψ.结合工程实例,详细介绍了该方法的建模过程,结果表明预测结果和实测结果很接近,神经网络在土性参数方面应用前景很广阔.  相似文献   

全数字摄影测量系统DEM生产的质量控制     

戴腾  童忠富  祁信舒  陈春华 《地理空间信息》2005,3(1):51-52,56

目前,数字高程模型(DEM)在理论研究和实践应用方面都有了很大的进展,已在测绘、地质、农业、工程、建筑、军事、导航等多个领域得到了广泛应用,因此高效快捷地生产高精度的DEM是十分必要和迫切的。全数字摄影测量系统DEM生产方案是解决这一问题的有效途径,文章针对该系统的特点,提出了加强质量控制的策略和方法,并阐述了对一些实践问题的解决。  相似文献