高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态   总被引：3，自引：3，他引：0  

秦冲  施畅  万秋月  王磊  刘爱琴  安彩秀 《岩矿测试》2018,37(6):664-670

土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%～95. 8%之间,相对标准偏差为1. 4%～5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。  相似文献   

西藏冈底斯带昂仁县差绒—丁欧复式花岗岩的成因：锆石U-Pb年代学及地球化学制约     

秦臻  佘朋涛  易鹏飞  张继军  张若愚  于恒彬  姚肖博  康琴琴 《地质论评》2018,64(6):1557-1574

西藏冈底斯带昂仁县措迈乡差绒—丁欧复式花岗岩岩石类型为石英闪长岩、黑云二长花岗岩和二长花岗岩,各侵入体之间为突变接触关系,闪长岩U- Pb同位素年龄为155.4±2.7Ma;黑云二长花岗岩U- Pb同位素年龄为152.0±13Ma、153.96±0.92Ma,时代均为晚侏罗世。岩石地球化学显示三者均为高钾钙碱性系列岩石,石英闪长岩为弱铝质―准铝质;黑云二长花岗岩和二长花岗岩则为准铝质—过铝质。黑云二长花岗岩和二长花岗岩相比石英闪长岩表现为富硅、富碱、贫Ca、Ti、Mg,轻稀土元素更富集,轻稀土分馏程度更高,分异更加明显的特点,微量元素二长花岗岩Ba、Sr、P、Ti亏损最为明显,黑云二长花岗岩的Rb、Th、K富集最为明显,石英闪长岩相比黑云二长花岗岩和二长花岗岩的Rb/Sr（0.18~0.46）、Rb/Ba值（0.13~0.26）最低,指示其分异演化程度较低。差绒—丁欧花岗岩应是同时代不同期次侵入的复式岩体,早期为I型的石英闪长岩和黑云二长花岗岩,晚期为S型二长花岗岩,该复式岩体并非产出于单一的俯冲环境,二长花岗岩可能为弧陆碰撞时的产物。  相似文献   

大兴安岭十八站—韩家园地区中酸性侵入岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义     

柴明春  赵国英  覃小锋  王泉  高溯  曹昆 《地质论评》2018,64(3):569-583

大兴安岭北部塔河县十八站—呼玛县韩家园地区发育早古生代中酸性侵入岩。文章选取二长闪长岩和二长花岗岩开展岩石年代学与地球化学研究。二长闪长岩LA-ICP-MS锆石U-Pb年龄为512.4±3.5 Ma,为早—中寒武世岩浆作用的产物。岩石地球化学分析表明,中酸性侵入岩归属于准铝质—弱过铝质(A/CNK=0.77~1.04)钙碱性—高钾钙碱性系列。岩石稀土总量∑REE=69.51×10~(-6)~275.83×10~(-6),轻重稀土分异明显(La/Yb)_N=9.11~26.64。在稀土元素配分图上,显示为LREE富集、HREE相对平缓的右倾型,Eu异常不显著(δEu=0.90~1.35)。微量元素组成具明显富集大离子亲石元素Ba、Sr,显著亏损高场强元素Nb、Ta、Ti的特征。结合区域资料和本文研究,初步分析认为早古生代侵入体形成于活动大陆边缘或岛弧环境,为前古亚洲洋闭合背景下萨拉伊尔造山作用的产物。  相似文献   

基于GIPL2模型的青藏高原活动层土壤热状况模拟研究   总被引：5，自引：5，他引：0  

秦艳慧  吴通华  李韧  胡国杰  乔永平  朱小凡  杨淑华  余文君  王蔚华 《冰川冻土》2018,40(6):1153-1166

青藏高原活动层土壤热状况,对深入了解高原活动层的厚度变化特征、下垫面的热力作用以及对气候变化预测均有重要意义。利用GIPL2模型模拟青藏高原多年冻土区不同植被状况下活动层土壤热状况。模拟结果表明：模型在高寒草原（QT06）试验点模拟效果较好,高寒沼泽草甸（QT03）试验点的模拟效果较差,高寒草甸（QT01）、高寒荒漠草原（QT05）和高寒草原化草甸（QT04）试验点的模拟效果介于高寒草原试验点和高寒沼泽草甸试验点之间。QT01、QT03、QT04、QT05和QT06的土壤温度模拟值与观测值相比,均方根误差分别为0.67、1.29、0.73、0.7和0.56℃;相关系数分别为0.99、0.87、0.98、0.98和0.96;平均误差分别为0.37、0.61、0.31、0.45和0.16℃。QT06模拟结果较好,原因在于此点土壤质地变化不大,模型的分层与所取的参数更加接近此点的实际状况。QT03模拟结果较差,可能由于此地区土壤中存在砾石,在导热率参数化方案中没有考虑砾石含量,导致模拟结果偏差较大。总体而言,GIPL2模型对青藏高原活动层土壤热状况的模拟具有一定的优势,是一种模拟多年冻土区活动层土壤热状况较为理想的模型。  相似文献   

Geological Controls on the CBM Productivity of No.15 Coal Seam of Carboniferous–Permian Taiyuan Formation in Southern Qinshui Basin and Prediction for CBM High-yield Potential Regions     

ZHANG Zheng  QIN Yong  ZHUANG Xinguo  LI Guoqing  LIU Donghai 《《地质学报》英文版》2018,92(6):2310-2332

Coalbed methane (CBM) resources in No.15 coal seam of Taiyuan Formation account for 55% of the total CBM resources in southern Qinshui Basin (SQB), and have a great production potential. This study aims at investigating the CBM production in No.15 coal seam and its influence factors. Based on a series of laboratory experiments and latest exploration and development data from local coal mines and CBM companies, the spatial characteristics of gas production of No.15 coal seam were analyzed and then the influences of seven factors on the gas productivity of this coal seam were discussed, including coal thickness, burial depth, gas content, ratio of critical desorption pressure to original coal reservoir pressure (RCPOP), porosity, permeability, and hydrogeological condition. The influences of hydrological condition on CBM production were analyzed based on the discussions of four aspects: hydrogeochemistry, roof lithology and its distribution, hydrodynamic field of groundwater, and recharge rate of groundwater. Finally, a three-level analytic hierarchy process (AHP) evaluation model was proposed for predicting the CBM potentials of the No.15 coal seam in the SQB. The best prospective target area for CBM production of the No.15 coal seam is predicted to be in the districts of Panzhuang, Chengzhuang and south of Hudi.  相似文献   

Development Phases and Mechanisms of Tectonic Fractures in the Longmaxi Formation Shale of the Dingshan Area in Southeast Sichuan Basin, China     

FAN Cunhui  HE Shun  ZHANG Yu  QIN Qirong  ZHONG Cheng 《《地质学报》英文版》2018,92(6):2351-2366

Shale gas has currently attracted much attention during oil and gas exploration and development. Fractures in shale have an important influence on the enrichment and preservation of shale gas. This work studied the developmental period and formation mechanism of tectonic fractures in the Longmaxi Formation shale in the Dingshan area of ??southeastern Sichuan Basin based on extensive observations of outcrops and cores, rock acoustic emission (Kaiser) experiments, homogenization temperature of fracture fill inclusions, apatite fission track, thermal burial history. The research shows that the fracture types of the Longmaxi Formation include tectonic fractures, diagenetic fractures and horizontal slip fractures. The main types are tectonic high-angle shear and horizontal slip fractures, with small openings, large spacing, low densities, and high degrees of filling. Six dominant directions of the fractures after correction by plane included NWW, nearly SN, NNW, NEE, nearly EW and NW. The analysis of field fracture stage and fracture system of the borehole suggests that the fractures in the Longmaxi Formation could be paired with two sets of plane X-shaped conjugate shear fractures, i.e., profile X-shaped conjugate shear fractures and extension fractures. The combination of qualitative geological analysis and quantitative experimental testing techniques indicates that the tectonic fractures in the Longmaxi Formation have undergone three periods of tectonic movement, namely mid-late Yanshanian movement (82–71.1 Ma), late Yanshanian and middle Himalaya movements (71.1–22.3 Ma), and the late Himalayan movement (22.3–0 Ma). The middle-late period of the Yanshanian movement and end of the Yanshanian movement-middle period of the Himalayan movement were the main fracture-forming periods. The fractures were mostly filled with minerals, such as calcite and siliceous. The homogenization temperature of fracture fill inclusions was high, and the paleo-stress value was large; the tectonic movement from the late to present period was mainly a slight transformation and superposition of existing fractures and tectonic systems. Based on the principle of tectonic analysis and theory of geomechanics, we clarified the mechanism of the fractures in the Longmaxi Formation, and established the genetic model of the Longmaxi Formation. The research on the qualitative and quantitative techniques of the fracture-phase study could be effectively used to analyze the causes of the marine shale gas fractures in the Sichuan Basin. The research findings and results provide important references and technical support for further exploration and development of marine shale gas in South China.  相似文献   

白银厂酸性火山岩地球化学特征及成因分析          下载免费PDF全文

覃伟  陈守余  赵江南  董凯  田光礼 《地质找矿论丛》2018,33(3):425-433

甘肃白银厂矿田是我国著名的火山成因块状硫化物矿床产地,赋矿岩石主要为酸性火山岩(石英角斑岩和石英角斑凝灰岩)。文章通过对白银厂矿区酸性火山岩的岩相学和岩石地球化学特征研究,结果表明:1)岩石发生了低绿片岩相的变质作用,镜下可见明显的绢云母化、绿泥石化等蚀变作用,造成了岩石K、Ca、Na、Rb等活泼元素的迁移;2)岩石具有高硅、低钛、弱铝、贫镁,亏损高场强元素Nb、Ta,以及明显的Sr、P、Ti、Eu的负异常和Th、U、Pb正异常特征,表明本区酸性火山岩可能为下地壳基性岩重熔的产物,源区存在斜长石、磷灰石以及钛铁矿等矿物的残留,并且岩浆在演化过程中经历过围岩的混染与弱的分离结晶作用;3)结合北祁连的区域构造演化、岩浆活动以及本区火山岩的年代学资料,认为该酸性火山岩可能处于由岛弧向弧后盆地过渡的环境中。  相似文献   

准噶尔腹部火山岩风化壳储层特征及其影响因素          下载免费PDF全文

李治  秦启荣  李朋波  顿雅航  付晓燕 《地质找矿论丛》2018,33(4):589-596

文章通过大量岩芯、铸体薄片观察和测井资料分析,对准噶尔腹部石西石炭系火山岩风化壳储层进行了详细地研究。研究结果表明,该火山岩风化壳储层的储集空间主要有基质溶孔、气孔或杏仁体溶孔、角砾间溶孔、微裂缝和裂缝等,其中与裂缝连通的各类溶孔占主导地位;在岩石分布上以集块岩、条带状熔岩、角砾熔岩和致密凝灰岩为主,玄武岩、安山岩和流纹岩则相对较少;储层物性主要表现为高孔低渗,只有裂缝具有较高的渗透率,且裂缝以高角度缝和直立缝为主。研究还发现,岩性岩相、裂缝和风化淋滤作用是影响该风化壳储层的主要因素。区内油层主要聚中在构造高部位、靠近断裂带和有利岩相区域;油层分布在离石炭系风化壳顶面25~150 m的范围内。  相似文献   

碳市场与电力市场机制影响下发电机组成本分析与竞争力研究     

孙友源  郭振  张继广  秦亚琦 《气候变化研究进展》2021,17(4):476-483

碳市场和电力市场将共同发挥市场对资源优化配置的决定性作用,对共同市场主体发电企业带来经营和发展挑战。在考虑碳成本的基础上,采用发电机组经济性影响模型,定量分析了碳市场不同发展阶段对发电机组发电成本的影响,定量评价不同能源结构投资收益经济性,以及对集中竞价市场出清顺序的影响。结果表明,随着有偿配额比例和碳价增加,碳成本占发电成本比例逐步攀升,燃煤机组碳成本占发电成本比例最高将达29%,燃气机组此比例达6%;在设定碳市场高比例配额有偿分配和高碳价情况下,煤电和气电单位发电收益逐步降低甚至出现亏损,远低于可再生能源,推动投资逐步向清洁高效火电机组和可再生能源倾斜;碳成本将成为竞价市场需考虑的重要因素,并影响发电机组出清顺序,进一步巩固高效率、低排放机组在集中竞价市场中的竞争力。  相似文献   

小波去噪的广西加权平均温度插值研究     

陈发德  刘立龙  黄良珂  黎峻宇  秦旭元 《测绘科学》2018,(4):24-29

针对广西地区探空站稀少,难以获得精确的T_m问题,GGOS atmosphere提供了利用ECMWF的相关资料计算而得到的时间分辨率为6h(UTC 00:00:00,06:00:00,12:00:00,18:00:00)、空间分辨率为2.5°×2°的全球T_m格网数据可以在没有气象数据的情况下获得较高时空分辨率的T_m,该文利用GGOS atmosphere T_m格网数据对广西地区4个探空站插值T_m,并用无线电探空数据计算的T_m检验其精度;对误差进行分析后,选取最优小波基与尺度对其残差去噪,利用去噪后得到的曲线建立T_m的改正模型。实验结果表明,插值T_m经基于小波去噪的模型改正后,其RMSE为1.29K;Bevis模型的RMSE为10.71K;GPT2_1W模型的RMSE为3.56K;改正模型精度优于传统模型,可以达到地基GPS反演GNSS-PWV的精度要求。  相似文献