The observed and predicted spatial distribution of Milky Way satellite galaxies     

B. Willman  F. Governato †  J. J. Dalcanton ‡  D. Reed  T. Quinn 《Monthly notices of the Royal Astronomical Society》2004,353(2):639-646

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Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography     

Gary L Mills  Alfred K Hanson  James G Quinn  William R Lammela  N.Dennis Chasteen 《Marine Chemistry》1982,11(4):355-377

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.  相似文献   

Isolation of dissolved organic matter and copper-organic complexes from estuarine waters using reverse-phase liquid chromatography     

Gary L. Mills  James G. Quinn 《Marine Chemistry》1981,10(2):93-102

Reverse-phase liquid chromatography was used for the isolation of dissolved organic matter and dissolved copper-organic complexes from the estuarine waters of Narragansett Bay, Rhode Island. The procedure isolates 10–30% of the organic matter and up to 50% of the total dissolved copper from various bay samples. Chromatograms obtained by high-performance liquid chromatography of the isolated organic matter showed qualitative differences between sampling stations progressing from the Providence River in the upper bay to the lower bay.  相似文献   

Chemical comparison of dissolved organic matter isolated from different oceanic environments     

Richard A. Kerr  James G. Quinn 《Marine Chemistry》1980,8(3):217-229

Dissolved organic matter was isolated from coastal and open-ocean surface waters having a wide range of biological productivities, and from seawater of intermediate depths. Approximately 50% of the organic matter was recovered by the use of activated-charcoal chromatography. The organic matter isolated from different types of water masses exhibited varying spectroscopic characteristics, and stable carbon-isotope compositions. The ability of the isolated organic matter to interact with copper ions also varied, but over a relatively narrow range which was not exceeded by more than a factor of two by similarly isolated terrigenous organic matter.  相似文献   

Ice in the Southern Coalsack     

R. G.Smith †  R. D.Blum †  D. E.Quinn  K.Sellgren  D. C. B.Whittet † 《Monthly notices of the Royal Astronomical Society》2002,330(4):837-843

To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H₂O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H₂O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H₂O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H₂O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A _V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.  相似文献   

Hotspots and a clumpy disc: variability of brown dwarfs and stars in the young σ Ori cluster     

A. Scholz  X. Xu  R. Jayawardhana  K. Wood  J. Eislöffel  C. Quinn 《Monthly notices of the Royal Astronomical Society》2009,398(2):873-886

The properties of accretion discs around stars and brown dwarfs in the σ Ori cluster (age 3 Myr) are studied based on near-infrared (IR) time series photometry supported by mid-IR spectral energy distributions (SEDs). We monitor ∼30 young low-mass sources over eight nights in the J and K band using the duPont telescope at Las Campanas. We find three objects showing variability with J -band amplitudes  ≥0.5 mag  ; five additional objects exhibit low-level variations. All three highly variable sources have been previously identified as highly variable; thus, we establish the long-term nature of their flux changes. The light curves contain periodic components with time-scales of  ∼0.5–8 d  , but have additional irregular variations superimposed – the characteristic behaviour for classical T Tauri stars. Based on the colour variability, we conclude that hotspots are the dominant cause of variations in two objects (#19 and #33), including one likely brown dwarf, with spot temperatures in the range of 6000–7000 K. For the third one (#2), a brown dwarf or very low-mass star, inhomogeneities at the inner edge of the disc are the likely origin of variability. Based on mid-IR data from Spitzer , we confirm that the three highly variable sources are surrounded by circum-(sub)-stellar discs. They show typical SEDs for T Tauri-like objects. Using SED models, we infer an enhanced scaleheight in the disc for the object #2, which favours the detection of disc inhomogeneities in light curves and is thus consistent with the information from variability. In the σ Ori cluster, about every fifth accreting low-mass object shows persistent high-level photometric variability. We demonstrate that estimates for fundamental parameters in such objects can be significantly improved by determining the extent and origin of the variations.  相似文献   

The formation of the Oort cloud in open cluster environments     

Nathan A. Kaib  Thomas Quinn 《Icarus》2008,197(1):221-238

We study the influence of an open cluster environment on the formation and current structure of the Oort cloud. To do this, we have run 19 different simulations of the formation of the Oort cloud for 4.5 Gyrs. In each simulation, the Solar System spends its first 100 Myrs in a different open cluster environment before transitioning to its current field environment. We find that, compared to forming in the field environment, the inner Oort cloud is preferentially loaded with comets while the Sun resides in the open cluster and that most of this material remains locked in the interior of the cloud for the next 4.4 Gyrs. In addition, the outer Oort cloud trapping efficiencies we observe in our simulations are lower than previous formation models by about a factor of 2, possibly implying an even more massive early planetesimal disk. Furthermore, some of our simulations reproduce the orbits of observed extended scattered disk objects, which may serve as an observational constraint on the Sun's early environment. Depending on the particular open cluster environment, the properties of the inner Oort cloud and extended scattered disk can vary widely. On the other hand, the outer portions of the Oort cloud in each of our simulations are all similar.  相似文献   

Exploring the sensitivity of coastal inundation modelling to DEM vertical error     

Harry West  Michael Horswell  Nevil Quinn 《International journal of geographical information science》2018,32(6):1172-1193

As sea level is projected to rise throughout the twenty-first century due to climate change, there is a need to ensure that sea level rise (SLR) models accurately and defensibly represent future flood inundation levels to allow for effective coastal zone management. Digital elevation models (DEMs) are integral to SLR modelling, but are subject to error, including in their vertical resolution. Error in DEMs leads to uncertainty in the output of SLR inundation models, which if not considered, may result in poor coastal management decisions. However, DEM error is not usually described in detail by DEM suppliers; commonly only the RMSE is reported. This research explores the impact of stated vertical error in delineating zones of inundation in two locations along the Devon, United Kingdom, coastline (Exe and Otter Estuaries). We explore the consequences of needing to make assumptions about the distribution of error in the absence of detailed error data using a 1 m, publically available composite DEM with a maximum RMSE of 0.15 m, typical of recent LiDAR-derived DEMs. We compare uncertainty using two methods (i) the NOAA inundation uncertainty mapping method which assumes a normal distribution of error and (ii) a hydrologically correct bathtub method where the DEM is uniformly perturbed between the upper and lower bounds of a 95% linear error in 500 Monte Carlo Simulations (HBM+MCS). The NOAA method produced a broader zone of uncertainty (an increase of 134.9% on the HBM+MCS method), which is particularly evident in the flatter topography of the upper estuaries. The HBM+MCS method generates a narrower band of uncertainty for these flatter areas, but very similar extents where shorelines are steeper. The differences in inundation extents produced by the methods relate to a number of underpinning assumptions, and particularly, how the stated RMSE is interpreted and used to represent error in a practical sense. Unlike the NOAA method, the HBM+MCS model is computationally intensive, depending on the areas under consideration and the number of iterations. We therefore used the HBM+ MCS method to derive a regression relationship between elevation and inundation probability for the Exe Estuary. We then apply this to the adjacent Otter Estuary and show that it can defensibly reproduce zones of inundation uncertainty, avoiding the computationally intensive step of the HBM+MCS. The equation-derived zone of uncertainty was 112.1% larger than the HBM+MCS method, compared to the NOAA method which produced an uncertain area 423.9% larger. Each approach has advantages and disadvantages and requires value judgements to be made. Their use underscores the need for transparency in assumptions and communications of outputs. We urge DEM publishers to move beyond provision of a generalised RMSE and provide more detailed estimates of spatial error and complete metadata, including locations of ground control points and associated land cover.  相似文献   

Adaptation and poverty reduction in Mozambique: an opportunity for developing countries to lead§     

Colin F. Quinn  Jennifer F. Howard  Chen Chen  Joyce E. Coffee  Carlos E. Quintela  Britt A. Parker 《Climate Policy》2018,18(2):146-150

Climate change disproportionately impacts the world’s poorest countries. A recent World Bank report highlighted that over 100 million people are at risk of falling into extreme poverty as a result of climate change. There is currently a lack of information about how to simultaneously address climate change and poverty. Climate change challenges provide an opportunity for those impacted most to come up with new and innovative technologies and solutions. This article uses an example from Mozambique where local and international partners are working side-by-side, to show how developing countries can simultaneously address climate change and poverty reduction using an ecosystem-based adaptation approach. Using ecosystem-based adaptation, a technique that uses the natural environment to help societies adapt to climate change, developing countries can lead the way to improve climate adaptation globally. This paradigm shift would help developing countries become leaders in ecosystem-based adaptation and green infrastructure techniques and has implications for climate policy worldwide.

POLICY RELEVANCE

The Paris Agreement resulting from the United Nations Framework Convention on Climate Change (UNFCCC) 21st Conference of Parties (COP 21) in December 2015 was rightly lauded for its global commitment to cut greenhouse gas emissions. However, COP 21 was also historic because of its call for non-party stakeholders to address climate change, inclusion of a global goal of ‘enhancing adaptive capacity, strengthening resilience and reducing vulnerability’, and the United States’ commitment of $800 million to adaptation funding. The combination of recognizing the need for new stakeholders to commit to climate change adaptation, the large impact climate change will have on the developing world, and providing access to funds for climate change adaptation creates a unique opportunity for developing countries to pave the way in adaptation policies in practices. Currently, developing countries are creating National Adaptation Plans (NAPs) for the UNFCCC. Through including a strong component of ecosystem-based adaptation in NAPs, developing countries can shape their countries’ policies, improve local institutions and governments, and facilitate a new generation of innovative leaders. Lessons learned in places like Mozambique can help lead the way in other regions facing similar climatic risks.  相似文献   

Optimal Processing of Marine High-Resolution Seismic Reflection (Chirp) Data     

Quinn  R.  Bull  J.M.  Dix  J.K. 《Marine Geophysical Researches》1998,20(1):13-20

Chirp frequency-modulated (FM) systems offer deterministic, repeatable source-signatures for high-resolution, normal incidence marine seismic reflection data acquisition. An optimal processing sequence for uncorrelated Chirp data is presented to demonstrate the applicability of some conventional seismic reflection algorithms to high-resolution data sets, and to emphasise the importance of a known source-signature. An improvement of greater than 60dB in the signal- to-noise ratio is realised from correlating the FM reflection data with the transmitted pulse. Interpretability of ringy deconvolved data is enhanced by the calculation of instantaneous amplitudes. The signal-to-noise ratio and lateral reflector continuity are both improved by the application of predictive filters whose effectiveness are aided by the repeatability of the Chirp source.  相似文献