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71.
Degradation of coastal ecosystems in the Great Barrier Reef (GBR) lagoon, Australia, has been linked with increased land-based runoff of suspended solids, nutrients and pesticides since European settlement. This study estimated the increase in river loads for all 35 GBR basins, using the best available estimates of pre-European and current loads derived from catchment modelling and monitoring. The mean-annual load to the GBR lagoon for (i) total suspended solids has increased by 5.5 times to 17,000ktonnes/year, (ii) total nitrogen by 5.7 times to 80,000tonnes/year, (iii) total phosphorus by 8.9 times to 16,000tonnes/year, and (iv) PSII herbicides is 30,000kg/year. The increases in river loads differ across the 10 pollutants and 35 basins examined, reflecting differences in surface runoff, urbanisation, deforestation, agricultural practices, mining and retention by reservoirs. These estimates will facilitate target setting for water quality and desired ecosystem states, and enable prioritisation of critical sources for management.  相似文献   
72.
This study examined the temporal variability in herbicide delivery to the Great Barrier Reef (GBR) lagoon (Australia) from one of the GBR catchment's major sugarcane growing regions. Annual loads of measured herbicides were consistently in the order of 200+kg. Atrazine, it's degradate desethylatrazine, and diuron contributed approximately 90% of annual herbicide load, with early 'first-flush' events accounting for the majority of herbicide loads leaving the catchment. Assessment of herbicide water-sediment partitioning in flood runoff highlighted the majority of herbicides were transported in predominantly dissolved form, although a considerable fraction of diuron was transported in particulate-bound form (ca. 33%). Diuron was also the herbicide demonstrating the highest concentrations and frequency of detection in sediments collected from catchment waterways and adjacent estuarine-marine environments, an outcome aligning with previous research. Herbicide physico-chemical properties appear to play a crucial role in partitioning between water column and sediment habitat types in GBR receiving ecosystems.  相似文献   
73.
The toxic effects of the water accommodated fraction (WAF) of a natural gas condensate on the larvae of five brooding coral species of the Family Pocilloporidae were examined in short term (96 h) bioassays. Lethality was observed in some larvae of Seriatopora hystrix and Seriatopora guttatus upon exposure to high concentrations of the condensate WAF, while those of Stylophora pistillata, Pocillopora damicornis and Pocillopora verrucosa did not experience mortality. Furthermore, increasing concentrations of WAF produced either delayed or impeded metamorphosis for all species except P. damicornis. Growth of juveniles, exposed to different WAF treatments for 96 h during their larval/early juvenile stages, was measured after 30 d. Marked decrease in subsequent growth rate (polyp count) was observed for S. hystrix, S. guttatus and S. pistillata with increasing WAF concentration. The results showed differential susceptibility of larvae of closely related coral species to oil stress, with the following sensitivity ranking: S. guttatus>S. hystrix>S. pistillata>P. verrucosa>P. damicornis. Oil exposure during the planktonic, larval stage of susceptible corals can adversely affect survivorship, recruitment and/or subsequent colony growth, thereby having profound consequences for the abundance of these corals in space and time.  相似文献   
74.
The oiling rate (oiled birds/total birds) has become the international standard to analyze beached bird survey data. However, this index may not reliably track long-term changes in marine oil pollution in regions where other activities that kill seabirds vulnerable to oil, such as hunting and gill-netting, are also changing. We compare the oiling rate from beached bird surveys conducted in southeastern Newfoundland between 1984 and 2006 to an alternative approach, namely trends derived from a model examining the linear density of oiled birds (birds/km). In winter, there was no change in the oiling rate since 1984, while in summer oiling rates significantly increased. In contrast, the number of oiled birds/km showed a significant decline in both winter and summer. The discrepancy in these trends was attributed to steep declines in the number of unoiled birds found in both seasons. In winter, the decline in unoiled birds/km was related to a reduction in the legal murre hunt and less onshore winds, while in summer a reduced cod fishery resulting in fewer murres drowning in nets and warming summers may have lead to the decline. The significant declines in oiled birds/km over the past three decades are hopefully an indication of less oil being present in the marine environment. Although oiled bird densities since 2000 have remained relatively low for the region (winter: 0.58 birds/km, summer: 0.27 birds/km), they still exceed densities reported elsewhere in the world.  相似文献   
75.
Artificial neural networks (ANNs) were developed to accurately predict highly time-variable specific conductance values in an unconfined coastal aquifer. Conductance values in the fresh water lens aquifer change in response to vertical displacements of the brackish zone and fresh water-salt water interface, which are caused by variable pumping and climate conditions. Unlike physical-based models, which require hydrologic parameter inputs, such as horizontal and vertical hydraulic conductivities, porosity, and fluid densities, ANNs can "learn" system behavior from easily measurable variables. In this study, the ANN input predictor variables were initial conductance, total precipitation, mean daily temperature, and total pumping extraction. The ANNs were used to predict salinity (specific conductance) at a single monitoring well located near a high-capacity municipal-supply well over time periods ranging from 30 d to several years. Model accuracy was compared against both measured/interpolated values and predictions were made with linear regression, and in general, excellent prediction accuracy was achieved. For example, although the average percent change of conductance over 90-d periods was 39%, the absolute mean prediction error achieved with the ANN was only 1.1%. The ANNs were also used to conduct a sensitivity analysis that quantified the importance of each of the four predictor variables on final conductance values, providing valuable insights into the dynamics of the system. The results demonstrate that the ANN technology can serve as a powerful and accurate prediction and management tool, minimizing degradation of ground water quality to the extent possible by identifying appropriate pumping policies under variable and/or changing climate conditions.  相似文献   
76.
77.
Mechanical recovery of oil by oil sorbents is one of the most important countermeasures in marine oil-spill response. Polypropylene is the ideal material for marine oil-spill recovery due to its low density, low water uptake and excellent physical and chemical resistance. Different forms of polypropylene nonwoven sorbents were evaluated in this study in terms of initial oil-sorption capacities and oil-retention properties. The investigation revealed that the fibre diameter, sorbent porosity and oil property are the most important factors in the oil-sorption performance of polypropylene nonwoven sorbents.  相似文献   
78.
79.
The large water-pumping and particle-capturing gills of the filter-feeding blue mussel Mytilus edulis are oversized for respiratory purposes. Consequently, the oxygen uptake rate of the mussel has been suggested to be rather insensitive to decreasing oxygen concentrations in the ambient water, since the diff usion rate of oxygen from water flowing through the mussel determines oxygen uptake. We tested this hypothesis by measuring the oxygen uptake in mussels exposed to various oxygen concentrations. These concentrations were established via N2-bubbling of the water in a respiration chamber with mussels fed algal cells to stimulate fully opening of the valves. It was found that mussels exposed to oxygen concentrations decreasing from 9 to 2 mg O_2/L resulted in a slow but significant reduction in the respiration rate, while the filtration rate remained high and constant. Thus, a decrease of oxygen concentration by 78% only resulted in a 25% decrease in respiration rate. However, at oxygen concentrations below 2 mg O_2/L M. edulis responded by gradually closing its valves, resulting in a rapid decrease of filtration rate, concurrent with a rapid reduction of respiration rate. These observations indicated that M.edulis is no longer able to maintain its normal aerobic metabolism at oxygen concentration below 2 mg O 2/L, and there seems to be an energy-saving mechanism in bivalve molluscs to strongly reduce their activity when exposed to low oxygen conditions.  相似文献   
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