Analyzing biases of nitrogen contents and δ~(15)N values arising from acidified marine sediments with different CaCO_3 concentrations     

PENG Yajun  LIU Dongyan  WANG Yujue  RICHARD Pierre  KEESING John K. 《海洋学报(英文版)》2018,(8)

In some studies, the researchers pretreated and measured organic carbon, nitrogen and their isotopes(δ~(13)C and δ~(15)N) of marine sediment together, to save costs and resources of analysis. However, the procedure of acidification to remove inorganic carbon for analysing δ~(13)C can affect the values of nitrogen and δ~(15)N, and the biases vary a lot depending on the CaCO_3 contents of sediments. In this study, the biases of total nitrogen(TN)and δ~(15)N values arising from acidified sediments were compared between the CaCO_3-poor(1%–16%) and CaCO_3-rich(20%–40%) samples. TN and δ~(15)N values were altered during acid treatment(without centrifugation) that possibly led to N-containing compounds volatilization. For CaCO_3-poor samples, acidification led to a range of 0%–40% TN losses and 0‰–2‰ shift in δ~(15)N values; and 10%–60% TN losses and 1‰–14‰ shift in δ~(15)N values for CaCO_3-rich samples. The biases from most samples exceeded the precision of the instrument(0.002% for TN and 0.08‰ for δ~(15)N), and high biases could mislead our judgment for the environmental implication of the data. Thus,avoiding co-analysis of organic carbon, nitrogen and their isotopes(δ~(13)C and δ~(15)N) in sediments, even for CaCO_3-poor marine sediments, is necessary.  相似文献   

Intra‐parasequence architecture of an interpreted asymmetrical wave‐dominated delta     

KARL CHARVIN  GARY J. HAMPSON  KERRY L. GALLAGHER  RICHARD LABOURDETTE 《Sedimentology》2010,57(3):760-785

Although modern wave‐dominated shorelines exhibit complex geomorphologies, their ancient counterparts are typically described in terms of shoreface‐shelf parasequences with a simple internal architecture. This discrepancy can lead to poor discrimination between, and incorrect identification of, different types of wave‐dominated shoreline in the stratigraphic record. Documented in this paper are the variability in facies characteristics, high‐resolution stratigraphic architecture and interpreted palaeo‐geomorphology within a single parasequence that is interpreted to record the advance of an ancient asymmetrical wave‐dominated delta. The Standardville (Ab1) parasequence of the Aberdeen Member, Blackhawk Formation is exposed in the Book Cliffs of central Utah, USA. This parasequence, and four others in the Aberdeen Member, record the eastward progradation of north/south‐trending, wave‐dominated shorelines. Within the Standardville (Ab1) parasequence, distal wave‐dominated shoreface‐shelf deposits in the eastern part of the study area are overlain across a downlap surface by southward prograding fluvial‐dominated delta‐front deposits, which have previously been assigned to a separate ‘stranded lowstand parasequence’ formed by a significant, allogenic change in relative sea‐level. High‐resolution stratigraphic analysis of these deposits reveals that they are instead more likely to record a single episode of shoreline progradation characterized by alternating periods of normal regressive and forced regressive shoreline trajectory because of minor cyclical fluctuations in relative sea‐level. Interpreted normal regressive shoreline trajectories within the wave‐dominated shoreface‐shelf deposits are marked by aggradational stacking of bedsets bounded by non‐depositional discontinuity surfaces. Interpreted forced regressive shoreline trajectories in the same deposits are characterized by shallow incision of fluvial distributary channels and strongly progradational stacking of bedsets bounded by erosional discontinuity surfaces that record enhanced wave‐base scour. Fluvial‐dominated delta‐front deposits most probably record the regression of a lobate delta parallel to the regional shoreline into an embayment that was sheltered from wave influence. Wave‐dominated shoreface‐shelf and fluvial‐dominated delta‐front deposits occur within the same parasequence, and their interpretation as the respective updrift and downdrift flanks of a single asymmetrical wave‐dominated delta that periodically shifted its position provides the most straightforward explanation of the distribution and relative orientation of these two deposit types.  相似文献   

Role of glaciohydraulic supercooling in the formation of stratified facies basal ice: Svínafellsjökull and Skaftafellsjökull, southeast Iceland     

SIMON J. COOK  ZOE P. ROBINSON  IAN J. FAIRCHILD  PETER G. KNIGHT  RICHARD I. WALLER  IAN BOOMER 《Boreas: An International Journal of Quaternary Research》2010,39(1):24-38

Cook, S. J., Robinson, Z. P., Fairchild, I. J., Knight, P. G., Waller, R. I. & Boomer, I. 2009: Role of glaciohydraulic supercooling in the formation of stratified facies basal ice: Svínafellsjökull and Skaftafellsjökull, southeast Iceland. Boreas, 10.1111/j.1502‐3885.2009.00112.x. ISSN 0300‐9483. There is need for a quantitative assessment of the importance of glaciohydraulic supercooling for basal ice formation and glacial sediment transfer. We assess the contribution of supercooling to stratified facies basal ice formation at Svínafellsjökull and Skaftafellsjökull, southeast Iceland, both of which experience supercooling. Five stratified basal ice subfacies have previously been identified at Svínafellsjökull, but their precise origins have not been determined. Analysis of stratified basal ice stable isotope compositions (δ¹⁸O and δD), spatial distribution and physical characteristics demonstrates that two subfacies present at both glaciers are consistent with supercooling. These ‘supercool’ subfacies account for 42% of stratified facies exposed at Svínafellsjökull, although estimates at Skaftafellsjökull are precluded by limited basal ice exposure. Owing to their high debris contents, supercooling‐related facies contribute a debris flux of 4.8 to 9.6 m³ m^?1 a^?1 at Svínafellsjökull (83% of the stratified facies debris flux). Other stratified subfacies, formed by non‐supercooling processes, account for 58% of the stratified basal ice at Svínafellsjökull, but only contribute a debris flux of 1.0 to 2.0 m³ m^?1 a^?1 (17% of the stratified facies debris flux). We conclude that supercooling has a significant role in glacial sediment transfer, although in stratified basal ice formation its role is less significant at these locations than has been reported elsewhere.  相似文献   

A natural experiment suggests little direct temperature forcing of the peatland palaeoclimate record          下载免费PDF全文

RICHARD J. PAYNE 《第四纪科学杂志》2014,29(6):509-514

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The perils of taxonomic inconsistency in quantitative palaeoecology: experiments with testate amoeba data     

RICHARD J. PAYNE  MARIUSZ LAMENTOWICZ  EDWARD A. D. MITCHELL 《Boreas: An International Journal of Quaternary Research》2011,40(1):15-27

Payne, R. J., Lamentowicz, M. & Mitchell, E. A. D. 2010: The perils of taxonomic inconsistency in quantitative palaeoecology: experiments with testate amoeba data. Boreas, 10.1111/j.1502‐3885.2010.00174.x. ISSN 0300‐9483. A fundamental requirement of quantitative palaeoecology is consistent taxonomy between a modern training set and palaeoecological data. In this study we assess the possible consequences of violation of this requirement by simulating taxonomic errors in testate amoeba data. Combinations of easily confused taxa were selected, and data manipulated to reflect confusion of these taxa; transfer functions based on unmodified data were then applied to these modified data sets. Initially these experiments were carried out one error at a time using four modern training sets; subsequently, multiple errors were separately simulated both in four modern training sets and in four palaeoecological data sets. Some plausible taxonomic confusions caused major biases in reconstructed values. In the case of two palaeoecological data sets, a single consistent taxonomic error was capable of changing the pattern of environmental reconstruction beyond all recognition, totally removing any real palaeoenvironmental signal. The issue of taxonomic consistency is one that many researchers would rather ignore; our results show that the consequences of this may ultimately be severe.  相似文献   

Chert spheroids of the Monterey Formation,California (USA): early‐diagenetic structures of bedded siliceous deposits     

RICHARD J. BEHL 《Sedimentology》2011,58(2):325-351

Chert spheroids are distinctive, early‐diagenetic features that occur in bedded siliceous deposits spanning the Phanerozoic. These features are distinct in structure and genesis from similar, concentrically banded ‘wood‐grain’ or ‘onion‐skin’ chert nodules from carbonate successions. In the Miocene Monterey Formation of California (USA), chert spheroids are irregular, concentrically banded nodules, which formed by a unique version of brittle differential compaction that results from the contrasting physical properties of chert and diatomite. During shortening, there is brittle fracture of diatomite around, and horizontally away from, the convex surface of strain‐resistant chert nodules. Unlike most older siliceous deposits, the Monterey Formation still preserves all stages of silica diagenesis, thus retaining textural, mineralogical and geochemical features key to unravelling the origin of chert spheroids and other enigmatic chert structures. Chert spheroids found in opal‐A diatomite form individual nodules composed of alternating bands of impure opal‐CT chert and pure opal‐CT or chalcedony. With increased burial diagenesis, surrounding diatomite transforms to bedded porcelanite or chert, and spheroids no longer form discrete nodules, yet still display characteristic concentric bands of pure and impure microcrystalline quartz and chalcedony. Petrographic observations show that the purer silica bands are composed of void‐filling cement that precipitated in curved dilational fractures, and do not reflect geochemical growth‐banding in the manner of Liesegang phenomena invoked to explain concentrically banded chert nodules in limestone. Chertification of bedded siliceous sediment can occur more shallowly (< 100 m) and rapidly (< 1 Myr) than the bulk silica phase transitions forming porcelanite or siliceous shale in the Monterey Formation and other hemipelagic/pelagic siliceous deposits. Early diagenesis is indicated by physical properties, deformational style and oxygen‐isotopic composition of chert spheroids. Early‐formed cherts formed by pore‐filling impregnation of the purest primary diatomaceous beds, along permeable fractures and in calcareous–siliceous strata.  相似文献   

Structure of a silica diagenetic transformation zone: the Gjallar Ridge,offshore Norway     

MARK T. IRELAND  RICHARD J. DAVIES  NEIL R. GOULTY  DANIEL CARRUTHERS 《Sedimentology》2011,58(2):424-441

Three‐dimensional seismic data from the Gjallar Ridge were used together with X‐ray diffraction data, scientific boreholes and wireline logs to analyse the seismic structure of a silica diagenetic transformation zone. The following features were identified: (i) an interval some 150 to 300 m thick that contains anomalously high‐amplitude reflections; (ii) a strong reflection event at the top of this interval which cross‐cuts stratigraphy, interpreted as the transformation boundary between opal‐A‐rich and opal‐CT‐rich sediment; (iii) amplitude variations on stratigraphic reflections within the interval, attributed to variations in the proportions of opal‐A and opal‐CT; and (iv) a second, deeper, cross‐cutting reflection event within the interval, interpreted as the transformation boundary between opal‐CT‐rich and quartz‐rich sediment. The base of the interval containing the anomalously high‐amplitude reflections is interpreted as a stratigraphic reflection demarcating the base of the silica‐rich strata. On a stratigraphic reflection within the interval of high amplitudes, roughly circular regions of anomalously high amplitude with diameters of 0·8 to 2·5 km are separated by lower amplitude regions. This pattern is similar to the cells previously identified at the opal‐A to opal‐CT transformation boundary and probably results from more complete transformation of opal‐A to opal‐CT. All of these observations provide the first recognition from seismic data that silica diagenetic transformations are not always narrow boundaries represented by single cross‐cutting seismic reflection events, as implied previously, but can be heterogeneous and hundreds of metres in thickness, as observed at outcrop.  相似文献   

CLIMATOLOGY OF TORNADOES ASSOCIATED WITH GULF COAST‐LANDFALLING HURRICANES     

TODD W. MOORE  RICHARD W. DIXON 《Geographical review》2011,101(3):371-395

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Managing the transition to climate stabilization     

RICHARD G. RICHELS  THOMAS F. RUTHERFORD  GEOFFREY J. BLANFORD  LEON CLARKE 《Climate Policy》2013,13(5):409-428

It is becoming increasingly clear that economically efficient climate policies are unlikely to be implemented in the near term. Therefore an analysis is warranted that considers the implications of certain suboptimal transition policies. This analysis constructs a transition scenario based on realistic assumptions about the current trends in policy-making. The transition is examined in the context of varying assumptions about the stringency of the target and the availability of low- or no-carbon energy technologies in the future. In addition to evaluating the effects of suboptimal policies, the transitional analysis offers new insights about the intrinsic uncertainty regarding both the appropriate stabilization target and technology.  相似文献   

Climate change feedback on the future oceanic CO₂ uptake     

RICHARD J. MATEBR  ANTHONY C. HIRST 《Tellus. Series B, Chemical and physical meteorology》1999,51(3):722-733

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