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91.
92.
Entanglement with plastic debris is a major cause of mortality in marine taxa, but the population-level consequences are unknown. Some seabirds collect marine debris for nesting material, which may lead to entanglement. Here we investigate the use of plastics as nesting material by northern gannets Morus bassanus and assess the associated levels of mortality. On average gannet nests contained 469.91 g (range 0-1293 g) of plastic, equating to an estimated colony total of 18.46 tonnes (range 4.47-42.34 tonnes). The majority of nesting material was synthetic rope, which appears to be used preferentially. On average 62.85 ± 26.84 (range minima 33-109) birds were entangled each year, totalling 525 individuals over eight years, the majority of which were nestlings. Although mortality rates are high, they are unlikely to have population-level effects. The use of synthetic fibres as nesting material is a common strategy among seabirds, but the impacts of entanglement warrants further investigation.  相似文献   
93.
Submarine mud volcanism is an important pathway for transfer of deep-sourced fluids enriched in hydrocarbons and other elements into the ocean. Numerous mud volcanoes (MVs) have been discovered along oceanic plate margins, and integrated elemental fluxes are potentially significant for oceanic chemical budgets. Here, we present the first detailed study of the spatial variation in fluid and chemical fluxes at the Carlos Ribeiro MV in the Gulf of Cadiz. To this end, we combine analyses of the chemical composition of pore fluids with a 1-D transport-reaction model to quantify fluid fluxes, and fluxes of boron, lithium and methane, across the sediment-seawater interface. The pore fluids are significantly depleted in chloride, but enriched in lithium, boron and hydrocarbons, relative to seawater. Pore water profiles of sulphate, hydrogen sulphide and total alkalinity indicate that anaerobic oxidation of methane occurs at 34-180 cm depth below seafloor. Clay mineral dehydration, and in particular the transformation of smectite to illite, produces pore fluids that are depleted in chloride and potassium. Profiles of boron, lithium and potassium are closely related, which suggests that lithium and boron are released from the sediments during this transformation. Pore fluids are expelled into the water column by advection; fluid flow velocities are 4 cm yr−1 at the apex of the MV but they rapidly decrease to 0.4 cm yr−1 at the periphery. The associated fluxes of boron, lithium and methane vary between 7-301, 0.5-6 and 0-806 mmol m−2 yr−1, respectively. We demonstrate that fluxes of Li and B due to mud volcanism may be important on a global scale, however, release of methane into the overlying water column is suppressed by microbial methanotrophy.  相似文献   
94.
In soils, mycorrhiza (microscopic fungal hypha) living in symbiosis with plant roots are the biological interface by which plants obtain, from rocks and organic matter, the nutrients necessary for their growth and maintenance. Despite their central role in soils, the mechanism and kinetics of mineral alteration by mycorrhiza are poorly constrained quantitatively. Here, we report in situ quantification of weathering rates from a mineral substrate, (0 0 1) basal plane of biotite, by a surface-bound hypha of Paxillus involutus, grown in association with the root system of a Scots pine, Pinus sylvestris. Four thin-sections were extracted by focused ion beam (FIB) milling along a single hypha grown over the biotite surface. Depth-profile of Si, O, K, Mg, Fe and Al concentrations were performed at the hypha-biotite interface by scanning transmission electron microscopy-energy dispersive X-ray spectroscopy (STEM-EDX). Large removals of K (50-65%), Mg (55-75%), Fe (80-85%) and Al (75-85%) were observed in the topmost 40 nm of biotite underneath the hypha while Si and O are preserved throughout the depth-profile. A quantitative model of alteration at the hypha-scale was developed based on solid-state diffusion fluxes of elements into the hypha and the break-down/mineralogical re-arrangement of biotite. A strong acidification was also observed with hypha bound to the biotite surface reaching pH < 4.6. When consistently compared with the abiotic biotite dissolution, we conclude that the surface-bound mycorrhiza accelerate the biotite alteration kinetics between pH 3.5 and 5.8 to ∼0.04 μmol biotite m−2 h−1. Our current work reaffirms that fungal mineral alteration is a process that combines our previously documented bio-mechanical forcing with the μm-scale acidification mediated by surface-bound hypha and a subsequent chemical element removal due to the fungal action. As such, our study presents a first kinetic framework for mycorrhizal alteration at the hypha-scale under close-to-natural experimental conditions.  相似文献   
95.
The magmatic systems that give rise to voluminous crystal-poor rhyolite magma bodies can be considered to operate on two contrasting timescales: Those governed by longer-term processes by which a magma acquires its chemical and isotopic characteristics (e.g., fractional crystallisation and assimilation), and those operating at shorter timescales during the physical accumulation of the melt-dominant magma body that finally erupts. We explore the compositional and textural relationships between amphibole and orthopyroxene crystals from the 25.4 ka, 530 km3 (magma) Oruanui eruption products (Taupo volcano, New Zealand) to investigate how processes related to the physical assembly of the pre-eruptive magma body are represented in the crystal record. Over 90 % of orthopyroxenes from the volumetrically dominant high-SiO2 (>74 wt%) rhyolite pumices record textural evidence for a significant disequilibrium event (partial dissolution ± resorption of cores and interiors) prior to the growth of 40–500 μm thick rim zones. This dissolution/regrowth history of orthopyroxene is recorded in the chemistry of co-crystallising amphiboles as a prominent inflection in the concentrations of Mn and Zn, two elements notably enriched in orthopyroxene relative to amphibole. Textural and chemical features, linked with in situ thermobarometric estimates, indicate that a major decompression event preceded the formation of the melt-dominant body. The decompression event is inferred to represent the extraction of large volumes of melt plus crystals from the Oruanui crystal mush/source zone at pressures of 140–300 MPa (~6–12 km depth). Orthopyroxene underwent partial dissolution during ascent before reestablishing in the melt-dominant magma body at pressures of 90–140 MPa (~3.5–6 km). We model Fe–Mg diffusion across the core-rim boundaries along the crystallographic a or b-axes to constrain the timing of this decompression event, which marked establishment of the melt-dominant magma body. Maximum modelled ages indicate that this event did not begin until ~1,600 years before eruption, consistent with constraints from zircon model-age spectra. Once extraction began, it underwent runaway acceleration with a peak extraction age of ~230 years, followed by an apparent period of stasis of ~60 years prior to eruption. The rapidity of the extraction and accumulation processes implies the involvement of a dynamic driving force which, in the rifted continental arc setting of the Taupo Volcanic Zone, seems likely to be represented by magma-assisted extensional tectonic processes.  相似文献   
96.
This study revisits the kinematics and tectonics of Central America subduction, synthesizing observations of marine bathymetry, high-resolution land topography, current plate motions, and the recent seismotectonic and magmatic history in this region. The inferred tectonic history implies that the Guatemala–El Salvador and Nicaraguan segments of this volcanic arc have been a region of significant arc tectonic extension; extension arising from the interplay between subduction roll-back of the Cocos Plate and the ~ 10–15mm/yr slower westward drift of the Caribbean plate relative to the North American Plate. The ages of belts of magmatic rocks paralleling both sides of the current Nicaraguan arc are consistent with long-term arc-normal extension in Nicaragua at the rate of ~ 5–10mm/yr, in agreement with rates predicted by plate kinematics. Significant arc-normal extension can ‘hide’ a very large intrusive arc-magma flux; we suggest that Nicaragua is, in fact, the most magmatically robust section of the Central American arc, and that the volume of intrusive volcanism here has been previously greatly underestimated. Yet, this flux is hidden by the persistent extension and sediment infill of the rifting basin in which the current arc sits. Observed geochemical differences between the Nicaraguan arc and its neighbors which suggest that Nicaragua has a higher rate of arc-magmatism are consistent with this interpretation. Smaller-amplitude, but similar systematic geochemical correlations between arc-chemistry and arc-extension in Guatemala show the same pattern as the even larger variations between the Nicaragua arc and its neighbors.  相似文献   
97.
The paleomagnetic data sets from the British Tertiary Igneous Province (BTIP) have recently been criticized as being unreliable and discordant with data from elsewhere in the North Atlantic Igneous Province (NAIP) [Riisager et al. Earth Planet. Sci. Lett. 201 (2002) 261–276; Riisager et al. Earth Planet. Sci. Lett. 214 (2003) 409–425]. We offer new paleomagnetic data for the extensive lava flow sequence on the Isle of Mull, Scotland, and can confirm the paleomagnetic pole positions emanating from important earlier studies. Our new north paleomagnetic pole position for Eurasia at 59 ± 0.2 Ma has latitude 73.3°N, longitude 166.2°E (dp/dm = 5.2/7.0).A re-evaluation and an inter-comparison of the paleomagnetic database emanating from the NAIP were carried out to test for sub-province consistency. We find a general agreement between the Eurasian part of NAIP (BTIP and Faeroes) and East Greenland data. However a compilation of West Greenland data displays a large and unexplained dispersion. We speculate on if this is related to different sense of block rotation of the Tertiary West Greenland constituents. Combining all data from the NAIP constituents, give a pole position at 75.0°N, 169.9°E (N = 25, K = 84.3, A95 = 3.2) in Eurasian reference frame.  相似文献   
98.
There is growing interest in rates of nitrate uptake and denitrification in restored streams to better understand the effects of restoration on nitrogen processing. This study quantified nitrate uptake in two restored and two unrestored streams in Baltimore, Maryland, USA using nitrate additions, denitrification enzyme assays, and a 15N isotope tracer addition in one of the urban restored streams, Minebank Run. Restoration included either incorporation of stormwater ponds below a storm drain and catch basins to attenuate flow or hydrologic “reconnection” of a stream channel to its floodplain. Stream restoration was conducted for restoring aging sanitary and bridge infrastructure and introducing some stormwater management in watersheds developed prior to current regulations. Denitrification potential in sediments was variable across streams, whereas nitrate uptake length appeared to be significantly correlated to surface water velocity, which was low in the restored streams during summer baseflow conditions. Uptake length of NO3 –N in Minebank Run estimated by 15N tracer addition was 556 m. Whole stream denitrification rates in Minebank Run were 153 mg NO3 –N m−2 day−1, and approximately 40% of the daily load of nitrate was estimated to be removed via denitrification over a distance of 220.5 m in a stream reach designed to be hydrologically “connected” to its floodplain. Increased hydrologic residence time in Minebank Run during baseflow likely influenced rates of whole stream denitrification, suggesting that hydrologic residence time may be a key factor influencing N uptake and denitrification. Restoration approaches that increase hydrologic “connectivity” with hyporheic sediments and increase hydrologic residence time may be useful for stimulating denitrification. More work is necessary, however, to examine changes in denitrification rates in restored streams across different seasons, variable N loads, and in response to the “flashy” hydrologic flow conditions during storms common in urban streams.  相似文献   
99.
Data reported in 40Ar/39Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all 40Ar/39Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).  相似文献   
100.
Tropical Africa is often seen to have problem economies that are very much alike and suffer from the same development problems. This view is questioned in exploratory analyses of levels of wealth, spatial productivity, the structure of the economy and aspects of the openness of economies and the way they have changed between 1965 and 1995. The analyses reveal differences between economies in both degree and kind. Change to economies was not unidirectional so that they became more disparate and differentiated. The exploratory analyses were extended using factor analysis as a diagnostic tool on a 19-variable by 25 country data set for 1985, 1990 and 1995. This confirmed the findings of the exploratory analyses and revealed changes in the structure of the factors reflecting development in the period. The results are discussed in the context of the literature in a search for explanation and policy formulation.  相似文献   
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