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121.
Marine plastic pollution is ubiquitous throughout the world’s oceans, and has been found in high concentrations in oceanic gyres of both the northern and southern hemispheres. The number of studies demonstrating plastic debris at seabird colonies and plastic ingestion by adult seabirds has increased over the past few decades. Despite the recent discovery of a large aggregation of plastic debris in the South Pacific subtropical gyre, the incidence of plastics at seabird colonies in New Zealand is unknown. Between 2011 and 2012 we surveyed six offshore islands on the northeast coast of New Zealand’s North Island for burrow-nesting seabird colonies and the presence of plastic fragments. We found non-research related plastic fragments (0.031 pieces/m2) on one island only, Ohinau, within dense flesh-footed shearwater (Puffinus carneipes) colonies. On Ohinau, we found a linear relationship between burrow density and plastic density, with 3.5 times more breeding burrows in areas with plastic fragments found. From these data we conclude that plastic ingestion is a potentially a serious issue for flesh-footed shearwaters in New Zealand. Although these results do not rule out plastic ingestion by other species, they suggest the need for further research on the relationship between New Zealand’s pelagic seabirds and marine plastic pollution.  相似文献   
122.
Using a refined quantitative polymerase chain reaction assay, we compared surface and bottom water concentrations of Vibrio vulnificus with total Vibrio spp. concentrations, fecal indicator bacteria (Escherichia coli and Enterococcus sp.), and environmental parameters (salinity, temperature, chlorophyll a, and turbidity) over 4 years at a mesohaline site in the Neuse River Estuary in North Carolina. V. vulnificus was not detected when water temperature was below 20 °C and 93 % of positive samples were from salinities 10–20 psu. V. vulnificus was detected in 50 % of summer samples with peak concentrations in summer bottom waters. Significant positive correlations for V. vulnificus and temperature, salinity, and bacterial group abundance were found. Significant negative correlations with chlorophyll a were also observed. Interannual comparisons indicated a significant decrease in mean V. vulnificus since 2005, corresponding with increasing salinity due to severe drought conditions in 2007 and 2008. Total Vibrio spp. abundance also decreased in 2007 but returned to the previously observed abundance by 2008. Although a significant positive relationship between total Vibrio spp. and V. vulnificus was documented, interannual comparisons indicate that total Vibrio spp. densities may not be indicative of V. vulnificus in all environmental conditions and that long-term drought conditions may alter community composition.  相似文献   
123.
Polar metabolites resulting from petroleum biodegradation are measured in groundwater samples as TPHd unless a silica gel cleanup (SGC) is used on the sample extract to isolate hydrocarbons. Even though the metabolites can be the vast majority of the dissolved organics present in groundwater, SGC has been inconsistently applied because of regulatory concern about the nature and toxicity of the metabolites. A two‐step approach was used to identify polar compounds that were measured as TPHd in groundwater extracts at five sites with biodegrading fuel sources. First, gas chromatography with mass spectrometry (GC‐MS) was used to identify and quantify 57 individual target polar metabolites. Only one of these compounds—dodecanoic acid, which has low potential human toxicity—was detected. Second, nontargeted analysis was used to identify as many polar metabolites as possible using both GC‐MS and GC×GC‐MS. The nontargeted analysis revealed that the mixture of polar metabolites identified in groundwater source areas at these five sites is composed of approximately equal average percentages of organic acids, alcohols and ketones, with few phenols and aldehydes. The mixture identified in downgradient areas at these five sites is dominated by acids, with fewer alcohols, far fewer ketones, and very few aldehydes and phenols. A ranking system consistent with systems used by USEPA and the United Nations was developed for evaluating the potential chronic oral toxicity to humans of the different classes of identified polar metabolites. The vast majority of the identified polar metabolites have a “Low” toxicity profile, and the mixture of identified polar metabolites present in groundwater extracts at these five sites is unlikely to present a significant risk to human health.  相似文献   
124.
The economy of Western Australia has long been characterized by a heavy dependence on extractive industries. The past decade, however, has seen the mining industry expand very rapidly, with significant implications for the small towns that support the sector. In this article, we consider the socio-economic performance of these towns through an assessment of unemployment, welfare dependence and incomes. In contrast to many other studies of resource boomtowns that typically focus on a single locality or time period, in this study we focus explicitly on spatial and temporal variability. We examine the ways in which place-specific characteristics—the commodity produced, local economic diversity and basic demographic features of a town—interact and have contributed to change in socio-economic well-being of mining communities across Western Australia over a 10-year period.  相似文献   
125.
In this paper, we present the results of the first automated continuous multi-year high temporal frequency study of CO2 dynamics in a coastal coral reef ecosystem. The data cover 2.5?years of nearly continuous operation of the CRIMP-CO2 buoy spanning particularly wet and dry seasons in southern Kaneohe Bay, a semi-enclosed tropical coral reef ecosystem in Hawaii. We interpret our observational results in the context of how rapidly changing physical and biogeochemical conditions affect the pCO2 of surface waters and the magnitude and direction of air–sea exchange of CO2. Local climatic forcing strongly affects the biogeochemistry, water column properties, and gas exchange between the ocean and atmosphere in Kaneohe Bay. Rainfall driven by trade winds and other localized storms generates pulses of nutrient-rich water, which exert a strong control on primary productivity and impact carbon cycling in the water column of the bay. The “La Ni?a” winter of 2005–2006 was one of the wettest winters in Hawaii in 30?years and contrasted sharply with preceding and subsequent drier winter seasons. In addition, short-term variability in physical forcing adds complexity and helps drive the response of the CO2–carbonic acid system of the bay. Freshwater pulses to Kaneohe Bay provide nutrient subsidies to bay waters, relieving the normal nitrogen limitation of this system and driving phytoplankton productivity. Seawater pCO2 responds to the blooms as well as to physical forcing mechanisms, leading to a relatively wide range of pCO2 in seawater from about 250 to 650?μatm, depending on conditions. Large drawdowns in pCO2 following storms occasionally cause bay waters to switch from being a source of CO2 to the atmosphere to being a sink. Yet, during our study period, the southern sector of Kaneohe Bay remained a net source of CO2 to the atmosphere on an annualized basis. The integrated net annual flux of CO2 from the bay to the atmosphere varied between years by a factor of more than two and was lower during the wet “La Ni?a” year, than during the following year. Over the study period, the net annualized flux was 1.80?mol?C?m?2?year?1. Our CO2 flux estimates are consistent with prior synoptic work in Kaneohe Bay and with estimates in other tropical coral reef ecosystems studied to date. The high degree of climatological, physical, and biogeochemical variability observed in this study suggests that automated high-frequency observations are needed to capture the short-, intermediate-, and long-term variability of CO2 and other properties of these highly dynamic coastal coral reef ecosystems.  相似文献   
126.
High-Mg basaltic andesites and andesites occur in the central trans-Mexican volcanic belt, and their primitive geochemical characteristics suggest equilibration with mantle peridotite. These lavas may represent slab melts that reequilibrated with overlying peridotite or hydrous partial melts of a peridotite source. Here, we experimentally map the liquidus mineralogy for a high-Mg basaltic andesite (9.6 wt% MgO, 54.4 wt% SiO2, Mg# = 75.3) as a function of temperature and H2O content over a range of mantle wedge pressures. Our results permit equilibration of this composition with a harzburgite residue at relatively high water contents (>7 wt%) and low temperatures (1,080–1,150°C) at 11–14 kbar. However, in contrast to the high Ni contents characteristic of olivine phenocrysts in many such samples from central Mexico, those of olivine phenocrysts in our sample are more typical of mantle melts that have fractionated a small amount of olivine. To account for this and the possibility that the refractory mantle source may have had olivine more Fo-rich than Fo90, we numerically evaluated alternative equilibration conditions, using our starting bulk composition adjusted to be in equilibrium with Fo92 olivine. This shifts equilibration conditions to higher temperatures (1,180–1,250°C) at mantle wedge pressures (11–15 kbar) for H2O contents (>3 wt%) comparable to those analyzed in olivine-hosted melt inclusions from this region. Comparison with geodynamic models shows that final equilibration occurred shallower than the peak temperature of the mantle wedge, suggesting that basaltic melts from the hottest part of the wedge reequilibrated with shallower mantle as they approached the Moho.  相似文献   
127.
ICZM (Integrated Coastal Zone Management) is a decision-making process for sustainable use, development and protection of coastal marine areas and their resources, in continuous realization. Norway is currently dependent upon the commitment and motivations of the municipalities to fulfill its ICZM initiatives. These communities are lacking epistemic communities that can help prevent the simmering conflicts surrounding aquaculture expansion, as demonstrated by media data from 1984–2010. With the forthcoming harvest of the zooplankton redfeed in Norwegian and surrounding waters, the Aquaculture industry could be in a situation of expanded feed resources, which would ensure its expansion if localities are made available. This would also be in line with the Norwegian government's commitment to the expansion of this industry. A government-endorsed growth of the Aquaculture industry will add fuel to these simmering conflicts concerning the use of the eco-system of collective goods and services available along national coastline in Norway for Aquaculture purposes. The suggestions from the recently released report from the Select Committee appointed by the Ministry of Fisheries and Coastal Affairs in Norway on Effective and Sustainable Area Use in the Aquaculture Industry cab be an aid to supporting the growth of epistemic communities and a subsequent successful national ICZM implementation, thereby paving the way for a conflict-less coastal area management.  相似文献   
128.
Two key issues distinguish probabilistic seismic risk analysis of a lifeline or portfolio of structures from that of a single structure. Regional analysis must consider the correlation among lifeline components or structures in the portfolio, and the larger scope makes it much more computationally demanding. In this paper, we systematically identify and compare alternative methods for regional hazard analysis that can be used as the first part of a computationally efficient regional probabilistic seismic risk analysis that properly considers spatial correlation. Specifically, each method results in a set of probabilistic ground motion maps with associated hazard‐consistent annual occurrence probabilities that together represent the regional hazard. The methods are compared according to how replicable and computationally tractable they are and the extent to which the resulting maps are physically realistic, consistent with the regional hazard and regional spatial correlation, and few in number. On the basis of a conceptual comparison and an empirical comparison for Los Angeles, we recommend a combination of simulation and optimization approaches: (i) Monte Carlo simulation with importance sampling of the earthquake magnitudes to generate a set of probabilistic earthquake scenarios (defined by source and magnitude); (ii) the optimization‐based probabilistic scenario method, a mixed‐integer linear program, to reduce the size of that set; (iii) Monte Carlo simulation to generate a set of probabilistic ground motion maps, varying the number of maps sampled from each earthquake scenario so as to minimize the sampling variance; and (iv) the optimization‐based probabilistic scenario again to reduce the set of probabilistic ground motion maps. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
129.
A Tiburon ROV dive within the East Blanco Depression (EBD) increased the mapped extent of a known hydrothermal field by an order of magnitude. In addition, a unique opal-CT (cristobalite-tridymite)-hematite mound was discovered, and mineralized sediments and rock were collected and analyzed. Silica-hematite mounds have not previously been found on the deep ocean floor. The light-weight rock of the porous mound consists predominantly of opal-CT and hematite filaments, rods, and strands, and averages 77.8% SiO2 and 11.8% Fe2O3. The hematite and opal-CT precipitated from a low-temperature (≥ 115° C), strongly oxidized, silica- and iron-rich, sulfur-poor hydrothermal fluid; a bacterial mat provided the framework for precipitation.

Samples collected from a volcaniclastic rock outcrop consist primarily of quartz with lesser plagioclase, smectite, pyroxene, and sulfides; SiO2 content averages 72.5%. Formation of these quartz-rich samples is best explained by cooling in an up-flow zone of silica-rich hydrothermal fluids within a low permeability system. Opal-A, opal-CT, and quartz mineralization found in different places within the EBD hydrothermal field likely reflects decreasing silica saturation and increasing temperature of the mineralizing fluid with increasing silica crystallinity.

Six push cores recovered gravel, coarse sand, and mud mineralized variously by Fe or Mn oxides, silica, and sulfides. Total rare-earth element concentrations are low for both the rock and push core samples. Ce and Eu anomalies reflect high and low temperature hydrothermal components and detrital phases.

A remarkable variety of types of mineralization occur within the EBD field, yet a consistent suite of elements is enriched (relative to basalt and unmineralized cores) in all samples analyzed: Ag, Au, S, Mo, Hg, As, Sb, Sr, and U; most samples are also enriched in Cu, Pb, Cd, and Zn. On the basis of these element enrichments, the EBD hydrothermal field might best be described as a base- and precious-metal-bearing, silica-Fe-oxide-barite deposit. Such deposits are commonly spatially and temporally associated with volcanogenic massive sulfide (VMS) ores. A plot of data for pathfinder elements shows a large hot spot at the northwestern margin of the field, which may mark a region where moderate to high temperature sulfide deposits are forming at depth; further exploration of the hydrothermal field to the northwest is warranted.  相似文献   
130.
Groundwater seepage can lead to the erosion and failure of streambanks and hillslopes. Two groundwater instability mechanisms include (i) tension failure due to the seepage force exceeding the soil shear strength or (ii) undercutting by seepage erosion and eventual mass failure. Previous research on these mechanisms has been limited to non‐cohesive and low cohesion soils. This study utilized a constant‐head, seepage soil box packed with more cohesive (6% and 15% clay) sandy loam soils at prescribed bulk densities (1.30 to 1.70 Mg m?3) and with a bank angle of 90° to investigate the controls on failure mechanisms due to seepage forces. A dimensionless seepage mechanism (SM) number was derived and evaluated based on the ratio of resistive cohesion forces to the driving forces leading to instability including seepage gradients with an assumed steady‐state seepage angle. Tension failures and undercutting were both observed dependent primarily on the saturated hydraulic conductivity, effective cohesion, and seepage gradient. Also, shapes of seepage undercuts for these more cohesive soils were wider and less deep compared to undercuts in sand and loamy sand soils. Direct shear tests were used to quantify the geotechnical properties of the soils packed at the various bulk densities. The SM number reasonably predicted the seepage failure mechanism (tension failure versus undercutting) based on the geotechnical properties and assumed steady‐state seepage gradients of the physical‐scale laboratory experiments, with some uncertainty due to measurement of geotechnical parameters, assumed seepage gradient direction, and the expected width of the failure block. It is hypothesized that the SM number can be used to evaluate seepage failure mechanisms when a streambank or hillslope experiences steady‐state seepage forces. When prevalent, seepage gradient forces should be considered when analyzing bank stability, and therefore should be incorporated into commonly used stability models. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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