Characterization of the 1.2 μm M1 pyroxene band: Extracting cooling history from near‐IR spectra of pyroxenes and pyroxene‐dominated rocks     

Rachel L. KLIMA  Carlé M. PIETERS  M. Darby DYAR 《Meteoritics & planetary science》2008,43(10):1591-1604

Abstract— The 1.2 μm band in near‐infrared spectra of pyroxenes results from Fe²⁺in the M1 crystallographic site. The distribution of Fe and Mg between the M1 and M2 sites is in part a function of the cooling rate and thermal history of a pyroxene. Combining near‐infrared and Mössbauer spectra for a series of compositionally controlled synthetic Mg, Fe, Ca pyroxenes, we quantify the strength of the 1.2 μm band as a function of Fe²⁺in the M1 site. Near‐infrared spectra are deconvolved into component absorptions that can be assigned to the M1 and M2 sites using the modified Gaussian model. The relative strength of the 1.2 μm band is shown to be directly related to the amount of Fe²⁺in the M1 site measured by Mössbauer spectroscopy. The strength of the 1.2 μm band relative to the combined strengths of the 1.2 and 2 μm bands, or the M1 intensity ratio, is calculated for 51 howardite, eucrite, and diogenite (HED) meteorites. Diogenites and cumulate eucrites exhibit the lowest M1 intensity ratios, consistent with their formation as slowly cooled cumulates. Basaltic eucrites exhibit a large range of M1 intensity ratios, all of which are consistently higher than the diogenites and cumulate eucrites. This example illustrates how the M1 intensity ratio can be a used as a tool for characterizing the cooling history of remotely detected pyroxene‐dominated rocks.  相似文献   

Whole Earth Telescope observations of the hot helium atmosphere pulsating white dwarf EC 20058−5234     

D. J. Sullivan †  T. S. Metcalfe  D. O'Donoghue  D. E. Winget  D. Kilkenny  F. van Wyk  A. Kanaan  S. O. Kepler  A. Nitta  S. D. Kawaler  M. H. Montgomery  R. E. Nather  M. S. O'Brien  A. Bischoff-Kim  M. Wood  X. J. Jiang  E. M. Leibowitz  P. Ibbetson  S. Zola  J. Krzesinski  G. Pajdosz  G. Vauclair  N. Dolez  M. Chevreton 《Monthly notices of the Royal Astronomical Society》2008,387(1):137-152

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Using Sealed Wells to Measure Water Levels Beneath Streams and Floodplains          下载免费PDF全文

Saskia L. Noorduijn  Peter G. Cook  Cameron Wood  Nick White 《Ground water》2015,53(6):872-876

The design of wells beneath streams and floodplains has often employed with tall standpipes to prevent incursion of surface water into the well during flood events. Here, an approach has been presented to minimise the infrastructure demands in these environments by sealing the well top (e.g., prevent water entering the well) and monitor the total pressure in the water column using an absolute (non‐vented) pressure transducer. The sealed well design was tested using a laboratory experiment where the total pressure responses were monitored in both an unsealed and sealed well, while the water level was varied. It is observed that, whether the well is sealed or not, the total pressure at a given depth in the aquifer will be equal to that within the well. This indicates that the sealed well design is a viable alternative to tall standpipes and also facilitates installation of wells beneath streams and floodplains.  相似文献   

World's Largest In Situ Thermal Desorption Project: Challenges and Solutions          下载免费PDF全文

G. Heron  K. Parker  S. Fournier  P. Wood  G. Angyal  J. Levesque  R. Villecca 《Ground Water Monitoring & Remediation》2015,35(3):89-100

This paper presents the largest In Situ Thermal Desorption (ISTD) project completed to date. The redevelopment of a former aerospace manufacturing facility adjacent to a commercial airport was the main driver, requiring relatively rapid reduction of several chlorinated volatile organic compounds (CVOC) in a 3.2‐acre source zone. The source zone was divided into four quadrants with differing treatment depths, heated simultaneously using a total of 907 thermal conduction heater wells. Five different depths were selected across the area, according to the depth of contaminant impact. Prior to implementation, a risk and optimization study led to placement of a vertical sheet‐pile wall around the treatment zone to minimize groundwater flow, and a pilot test of a novel direct‐drive method for installation of the heater casings. Because of a shallow water table, a layer of clean fill was placed over the treatment zone, and partial dewatering was necessary prior to heating. A network of vertical multiphase extraction wells and horizontal vapor extraction wells was used to establish hydraulic and pneumatic control and to capture the contaminants. The site was split into four decision units, each with a rigorous soil sampling program which included collecting a total of 270 confirmatory soil samples from locations with the highest pretreatment CVOC concentrations requiring reduction to below 1 mg/kg for each contaminant. Temperature monitoring and mass removal trends were used to trigger the sampling events. Eventually, a small area near the center of the site required the installation of four additional heaters before the soil goals were reached after 238 days of heating. The total energy usage for heating and treating the source area was 23 million kWh—slightly lower than the estimated 26.5 million kWh. Actual energy losses and the energy removal associated with the extracted steam were lower than anticipated. An estimated 13,400 kg (29,800 lbs) of CVOC mass was removed, and all soil goals were met. This paper presents the challenges associated with a project of this scale and describes the solutions to successfully complete the ISTD remedy.  相似文献   

Bio‐Struvite: A New Route to Recover Phosphorus from Wastewater          下载免费PDF全文

Ana Soares  Mamatha Veesam  Francisco Simoes  Elizabeth Wood  Simon A. Parsons  Tom Stephenson 《洁净——土壤、空气、水》2014,42(7):994-997

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Detection of alteration at the Millennium uranium deposit in the Athabasca Basin: a comparison of data from two airborne electromagnetic systems with ground resistivity data     

Richard S. Smith  Garnet R. Wood  Brian Powell 《Geophysical Prospecting》2010,58(6):1147-1158

The Millennium uranium deposit is located within the Athabasca Basin of northern Saskatchewan. The basement rocks, comprised primarily of paleo‐Proterozoic gneisses, are electrically resistive. However, the deposit is associated with highly conductive graphitic metasediments that are intercalated with the gneisses. An unconformity separates the basement rocks from the overlying, horizontally stratified, Proterozoic sandstones of the Athabasca Group (which are also highly resistive). The strike extents of the graphitic metasedimenary packages are extensive and therefore electromagnetic (EM) survey techniques are successful at identifying these zones but do not identify the specific locations where they are enriched in uranium. Through drilling it has been noted that hydrothermal processes associated with mineralization has altered the rocks in the vicinity of the deposits, which should in theory result in a resistivity low. A significant resistivity low has been mapped coincident with the Millennium deposit using ground resistivity survey techniques. However, a comparison of the airborne EM and ground resistivity results reveals that the two data sets have imaged different features. The resistive‐limit (on‐time) windows of the MEGATEM data show conductive features corresponding to lakes located to the west and south of the deposit. The late‐time windows show a feature to the east of the deposit, interpreted as being associated with the east‐dipping graphitic basement conductors (similar to that observed in historical ground EM data collected in this area). The early‐time TEMPEST windows (delay times less than 0.2 ms) show a broad resistivity low located at approximately the same location as where the alteration has been identified through drilling. Modelling the data is not easy but a response that decays prior to 0.3 ms is consistent with 500 Ωm material in the sandstone, a resistivity value close to the lower limit with respect to the hydrothermally altered Athabasca group sediments in this area. The MEGATEM system does not see a conductive zone over the alteration as clearly but the high signal‐to‐noise ratio in the late‐time MEGATEM data means that the conductive material at a greater depth is more coherently imaged.  相似文献   

On Creating Global Gridded Terrestrial Water Budget Estimates from Satellite Remote Sensing     

Yu Zhang  Ming Pan  Eric F. Wood 《Surveys in Geophysics》2016,37(2):249-268

The increasing availability and reliability of satellite remote sensing products [e.g., precipitation (P), evapotranspiration (ET), and the total water storage change (TWSC)] make it feasible to estimate the global terrestrial water budget at fine spatial resolution. In this study, we start from a reference water budget dataset that combines all available data sources, including satellite remote sensing, land surface model (LSM) and reanalysis, and investigate the roles of different non-satellite remote sensing products in closing the terrestrial water budget through a sensitivity analysis by removing/replacing one or more categories of products during the budget estimation. We also study the differences made by various satellite products for the same budget variable. We find that the gradual removal of non-satellite data sources will generally worsen the closure errors in the budget estimates, and remote sensing retrievals of P, ET, and TWSC together with runoff (R) from LSM give the worst closure errors. The gauge-corrected satellite precipitation helps to improve the budget closure (4.2–9 % non-closure errors of annual mean precipitation) against using the non-gauge-corrected precipitation (7.6–10.4 % non-closure errors). At last, a data assimilation technique, the constrained Kalman filter, is applied to enforce the water balance, and it is found that the satellite remote sensing products, though with worst closure, yield comparable budget estimates in the constrained system to the reference data. Overall, this study provides a first comparison between the water budget closure using the satellite remote sensing products and a full combination of remote sensing, LSM, and reanalysis products on a quasi-global basis. This study showcases the capability and potential of the satellite remote sensing in closing the terrestrial water budget at fine spatial resolution if properly constrained.  相似文献   

Characterization and initial field test of an 8–14 μm thermal infrared hyperspectral imager for measuring SO2 in volcanic plumes     

Andrea Gabrieli  Robert Wright  Paul G. Lucey  John N. Porter  Harold Garbeil  Eric Pilger  Mark Wood 《Bulletin of Volcanology》2016,78(10):73

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Assessment of oxygen plasma ashing as a pre-treatment for radiocarbon dating     

Michael I. Bird  Peter D.J. Charville-Mort  Philippa L. Ascough  Rachel Wood  Tom Higham  David Apperley 《Quaternary Geochronology》2010,5(4):435-442

This study investigates the potential of low-temperature oxygen plasma ashing as a technique for decontaminating charcoal and wood samples prior to radiocarbon dating. Plasma ashing is demonstrated to be rapid, controllable and surface-specific. Different organic materials clearly ash at different rates, however, the ability of plasma ashing to selectively ash different organic components is limited in heterogeneous sample matrices. This is because oxidation is confined to the immediate sample surface. Comparison of radiocarbon dates obtained from identical aliquots of contaminated ancient charcoal pre-treated by acid–base–acid (ABA), acid–base-oxidation-stepped combustion (ABOx-SC) and plasma ashing suggests that the technique performs as well as the ABA pre-treatment but does not remove as much contamination as the ABOx-SC technique. Plasma ashing may be particularly useful in cases where sample size is limiting.  相似文献   

Comparison of theory and experiments for dispersion in homogeneous porous media     

Mark L. Porter  Francisco J. Valdés-Parada  Brian D. Wood 《Advances in water resources》2010

Modeling dispersion in homogeneous porous media with the convection–dispersion equation commonly requires computing effective transport coefficients. In this work, we investigate longitudinal and transverse dispersion coefficients arising from the method of volume averaging, for a variety of periodic, homogeneous porous media over a range of particle Péclet (Pe_p) numbers. Our objective is to validate the upscaled transverse dispersion coefficients and concentration profiles by comparison to experimental data reported in the literature, and to compare the upscaling approach to the more common approach of inverse modeling, which relies on fitting the dispersion coefficients to measured data. This work is unique in that the exact microscale geometry is available; thus, no simplifying assumptions regarding the geometry are required to predict the effective dispersion coefficients directly from theory. Transport of both an inert tracer and non-chemotactic bacteria is investigated for an experimental system that was designed to promote transverse dispersion. We highlight the occurrence of transverse dispersion coefficients that (1) depart from power-law behavior at relatively low Pe_p values and (2) are greater than their longitudinal counterparts for a specific range of Pe_p values. The upscaling theory provides values for the transverse dispersion coefficient that are within the 98% confidence interval of the values obtained from inverse modeling. The mean absolute error between experimental and upscaled concentration profiles was very similar to that between the experiments and inverse modeling. In all cases the mean absolute error did not exceed 12%. Overall, this work suggests that volume averaging can potentially be used as an alternative to inverse modeling for dispersion in homogeneous porous media.  相似文献