Trapping and adsorption of CO₂ in amorphous ice: A FTIR study     

Óscar Gálvez  Belén Maté  Víctor J. Herrero  Rafael Escribano 《Icarus》2008,197(2):599-605

The interaction of carbon dioxide and amorphous water ice at 95 K is studied using transmission infrared spectroscopy. Samples are prepared in two ways: co-deposition of the gases admitted simultaneously or sequential deposition, in which amorphous water ice (ASW) is grown first and CO₂ vapor is added subsequently. In either case, a fraction of the CO₂ molecules is found to interact with water in a way that gives rise to shifts and splittings in the infrared bands with respect to those of a pure CO₂ solid. In co-deposition experiments, a larger amount of carbon dioxide is trapped within the amorphous water than in sequential deposition samples, where a substantial proportion of molecules appears to be trapped in macropores of the ASW. The specific surface area of sequential samples is evaluated and compared to previous literature results. When the sequential samples are heated to 140 K, beyond the onset temperature at which water ice undergoes a phase transition, the CO₂ molecules at the pores relocate inside the bulk in a structure similar to that found in co-deposited samples, as deduced by changes in the shape of the CO₂ infrared bands.  相似文献   

Euro-Cordex Regional Projection Models: What Kind of Agreement for Europe?     

Martins  Ana  Rafael  Sandra  Monteiro  Alexandra  Scotto  Manuel  Gouveia  Sónia 《Mathematical Geosciences》2019,51(8):1021-1035

Mathematical Geosciences - EURO-CORDEX is an international initiative which provides regional climate projections based on multiple dynamical and empirical–statistical downscaling models. The...  相似文献   

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success     

Jordana Borini Freire  Rafael M. Sousa  Karla Taufner  Maria TW Carneiro  Henrique R Filgueiras  Dominik Lenz  Paulo Dias Ferreira  Denise C Endringer 《Marine Ecology》2021,42(1):e12633

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.  相似文献   

Multiple Random Walk Simulation: A Fast Method to Map Grade Uncertainty with Large Datasets     

Rafael Moniz Caixeta  Diniz Tamantini Ribeiro  João Felipe Coimbra Leite Costa  Péricles Lopes Machado 《Natural Resources Research》2017,26(2):213-221

Multiple Random Walk Simulation consists of a methodology adapted to run fast simulations if close-spaced data are abundant (e.g., short-term mining models). Combining kriging with the simulation of random walks attempts to approximate traditional simulation algorithm results but at a computationally faster way when there is a large amount of conditioning samples. This paper presents this new algorithm illustrating the situations where the method can be used properly. A synthetic study case is presented in order to illustrate the Multiple Random Walk Simulation and to analyze the speed and goodness of its results against the ones from using Turning Bands Simulation and Sequential Gaussian Simulation.  相似文献   

Correction to: Water masses in the Caribbean Sea and sub‑annual variability in the Guajira upwelling region     

Torres  Rafael Ricardo  Latandret  Sadid  Salon  Jhon  Dagua  Claudia 《Ocean Dynamics》2023,73(9):593-593

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Assessment of soil factors controlling ephemeral gully erosion on agricultural fields   总被引：1，自引：0，他引：1       下载免费PDF全文

Paul Ollobarren Del Barrio  Miguel A. Campo‐Bescós  Rafael Giménez  Javier Casalí 《地球表面变化过程与地形》2018,43(9):1993-2008

The soil factor is crucial in controlling and properly modeling the initiation and development of ephemeral gullies (EGs). Usually, EG initiation has been related to various soil properties (i.e. sealing, critical shear stress, moisture, texture, etc.); meanwhile, the total growth of each EG (erosion rate) has been linked with proper soil erodibility. But, despite the studies to determine the influence of soil erodibility on (ephemeral) gully erosion, a universal approach is still lacking. This is due to the complex relationship and interactions between soil properties and the erosive process. A feasible soil characterization of EG erosion prediction on a large scale should be based on simple, quick and inexpensive tests to perform. The objective of this study was to identify and assess the soil properties – easily and quickly to determine – which best reflect soil erodibility on EG erosion. Forty‐nine different physical–chemical soil properties that may participate in establishing soil erodibility were determined on agricultural soils affected by the formation of EGs in Spain and Italy. Experiments were conducted in the laboratory and in the field (in the vicinity of the erosion paths). Because of its importance in controlling EG erosion, five variables related to antecedent moisture prior to the event that generated the gullies and two properties related to landscape topography were obtained for each situation. The most relevant variables were detected using multivariate analysis. The results defined 13 key variables: water content before the initiation of EGs, organic matter content, cation exchange capacity, relative sealing index, two granulometric and organic matter indices, seal permeability, aggregates stability (three index), crust penetration resistance, shear strength and an erodibility index obtained from the Jet Test erosion apparatus. The latter is proposed as a useful technique to evaluate and predict soil loss caused by EG erosion. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

Long‐term sediment yield from a small catchment in southern Brazil affected by land use and soil management changes          下载免费PDF全文

Jean P.G. Minella  Gustavo H. Merten  Claúdia A.P. Barros  Rafael Ramon  Alexandre Schlesner  Robin T. Clarke  Michele Moro  Leandro Dalbianco 《水文研究》2018,32(2):200-211

Sediments produced from eroding cultivated land can cause on‐site and off‐site effects that cause considerable economic and social impacts. Despite the importance of soil conservation practices (SCP) for the control of soil erosion and improvements in soil hydrological functions, limited information is available regarding the effects of SCP on sediment yield (SY) at the catchment scale. This study aimed to investigate the long‐term relationships between SY and land use, soil management, and rainfall in a small catchment. To determine the effects of anthropogenic and climatic factors on SY, rainfall, streamflow, and suspended sediment concentration were monitored at 10‐min intervals for 14 years (2002–2016), and the land use and soil management changes were surveyed annually. Using a statistical procedure to separate the SY effects of climate, land use, and soil management, we observed pronounced temporal effects of land use and soil management changes on SY. During the first 2 years (2002–2004), the land was predominantly cultivated with tobacco under a traditional tillage system (no cover crops and ploughed soil) using animal traction. In that period, the SY reached approximately 400 t·km^?2·year^?1. From 2005 to 2009, a soil conservation programme introduced conservation tillage and winter cover crops in the catchment area, which lowered the SY to 50 t·km^?2·year^?1. In the final period (2010–2016), the SCP were partially abandoned by farmers, and reforested areas increased, resulting in an SY of 150 t·km^?2·year^?1. This study also discusses the factors associated with the failure to continue using SCP, including structural support and farmer attitudes.  相似文献   

Tsunami hydrodynamic force on a building using a SPH real-scale numerical simulation     

Klapp  Jaime  Areu-Rangel  Omar S.  Cruchaga  Marcela  Aránguiz  Rafael  Bonasia  Rosanna  Godoy  Mauricio J.  Silva-Casarín  Rodolfo 《Natural Hazards》2020,100(1):89-109

Natural Hazards - One of the most important aspects in tsunami studies is the behaviour of the wave when it approaches the coast. Information on physical parameters that characterize waves is often...  相似文献   

Structure-from-motion photogrammetry analysis of historical aerial photography: Determining beach volumetric change over decadal scales     

Rafael C. Carvalho  David M. Kennedy  Yakufu Niyazi  Chloe Leach  Teresa M. Konlechner  Daniel Ierodiaconou 《地球表面变化过程与地形》2020,45(11):2540-2555

Historical aerial photographs are an invaluable tool in shoreline mapping and change detection in coastal landscapes. We evaluate the extent to which structure-from-motion (SfM) photogrammetric methods can be applied to quantify volumetric changes along sandy beaches, using archival imagery. We demonstrate the application of SfM-derived digital surface models (DSMs) at East Beach and Lady Bay in southwest Victoria, Australia, using photographic datasets taken in 1969, 1977 and 1986, and compare them to LiDAR-derived DSMs acquired at both sites in 2007. The SfM approaches resulted in two entire and two partial suitable DSMs out of six datasets. Good-quality DSMs were spatially continuous with a good spread of ground control points (GCPs) near the beach at Lady Bay, whereas unsuitable DSMs were mostly restricted by poor distribution and number of GCPs in spatially segmented areas of East Beach, due to limited overlapping of images, possible poor quality of GCPs and also the propagation of errors in the derived point clouds. A volume of approximately 223 000 ± 72 000 m³ was deposited at Lady Bay between 1969 and 2007, despite minimal erosion observed near the breakwater. The partially suitable dataset of East Beach indicated that beach erosion of at least 39 m³ m⁻¹ occurred immediately to the east of the seawall after 1977. We also discuss the drawbacks and strengths of SfM approaches as a benchmark of historical erosion assessments along sandy beaches. © 2020 John Wiley & Sons, Ltd.  相似文献   

Beerkan multi-runs for characterizing water infiltration and spatial variability of soil hydraulic properties across scales   总被引：1，自引：1，他引：0  

Laurent Lassabatere  Simone Di Prima  Rafael Angulo-Jaramillo  Saskia Keesstra  David Salesa 《水文科学杂志》2019,64(2):165-178

A method is presented for characterizing the spatial variability of water infiltration and soil hydraulic properties at the transect and field scales. The method involves monitoring a set of 10 Beerkan runs distributed over a 1-m length of soil, and running BEST (Beerkan estimation of soil transfer parameters) methods to derive hydraulic parameters. The Beerkan multi-runs (BMR) method provides a significant amount of data at the transect scale, allowing the determination of correlations between water infiltration variables and hydraulic parameters, and the detection of specific runs affected by preferential flow or water repellence. The realization of several BMRs at several transects on the same site allows comparison of the variation between locations (spatial variability at the field scale) and at the transect scale (spatial variability at the metre scale), using analysis of variance. From the results, we determined the spatial variability of water infiltration and hydraulic parameters as well as its characteristic scale (transect versus field).  相似文献