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131.
Abstract– Shock recovery experiments were performed with an explosive set‐up in which three types of microorganisms embedded in various types of host rocks were exposed to strong shock waves with pressure pulse lengths of lower than 0.5 μs: spores of the bacterium Bacillus subtilis, Xanthoria elegans lichens, and cells of the cyanobacterium Chroococcidiopsis sp. 029. In these experiments, three fundamental parameters were systematically varied (1) shock pressures ranging from 5 to 50 GPa, (2) preshock ambient temperature of 293, 233 and 193 K, and (3) the type of host rock, including nonporous igneous rocks (gabbro and dunite as analogs for the Martian shergottites and chassignites, respectively), porous sandstone, rock salt (halite), and a clay‐rich mineral mixture as porous analogs for dry and water‐saturated Martian regolith. The results show that the three parameters have a strong influence on the survival rates of the microorganisms. The most favorable conditions for the impact ejection from Mars for microorganisms would be (1) low porosity host rocks, (2) pressures <10–20 GPa, and (3) low ambient temperature of target rocks during impact. All tested microorganisms were capable of surviving to a certain extent impact ejection in different geological materials under distinct conditions.  相似文献   
132.
133.
We studied the local coordination and structure of Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water (buffered to pH 7 by 8 mM bicarbonate) using synchrotron-based X-ray absorption spectroscopy (XAS) at the K-edges of Fe, P, Ca, and As. Dissolved phosphate, silicate, and Ca at different ratios relative to each other and to Fe affect the forming Fe(III)-phases in a complex manner. The high affinity of phosphate for Fe(III) results in the predominant precipitation of Fe(III)-phosphate as long as dissolved phosphate is present, with Fe(III) polymerization limited to small oligomers. In Ca-containing solution, Ca uptake by Fe(III)-Ca-phosphate involves the linkage and coagulation of negatively charged Fe(III)-phosphate oligomers via Ca-O-P bonds. In the absence of phosphate, dissolved silicate at Si/Fe ratios above ∼0.5 results in the formation of hydrous ferric oxide (HFO) with mainly edge-sharing Fe-Fe linkage. At lower Si/Fe ratios of ∼0.5-0.1, mainly 2-line ferrihydrite (2L-Fh) with both edge- and corner-sharing Fe-Fe linkage forms. Only in the absence of phosphate at low Si/Fe ratio, lepidocrocite (Lp) forms. In solutions containing sufficient Fe(II), aeration results in the sequential precipitation of Fe(III)-(Ca-)phosphate, HFO or 2L-Fh (depending on solution Si/Fe), and finally Lp. The amount and oxidation state of As co-precipitated with Fe(III) are controlled by the co-oxidation of As(III) with Fe(II), which increases with initial Fe/As ratio, and the competitive uptake of phosphate, As(V) and less strongly sorbing silicate and As(III). This study demonstrates that the diversity and sequence of short-range-ordered Fe(III)-precipitates forming by Fe(II) oxidation in near-neutral natural waters depend on water chemistry. Because differences in the colloidal stability and biogeochemical reactivity of these phases will affect the fate of associated major and trace elements, the different Fe(III)-precipitates and their specific biogeochemical properties must be taken into account when addressing nutrient and contaminant dynamics at redox boundaries in natural and engineered systems.  相似文献   
134.
In oxic environments contaminated with arsenate (As(V)), small polyhydroxycarboxylates such as citrate may impact the structure of precipitating ferrihydrite (Fh) and thus the surface speciation of As(V). In this study, ‘2-line’ Fh was precipitated from ferric nitrate solutions that were neutralized to pH 6.5 in the presence of increasing citrate concentrations and in the absence or presence of As(V). The initial citrate/Fe and As/Fe ratios were 0-50 mol% and 5 mol%, respectively. The reaction products, enriched with up to 0.32 mol citrate per mole Fe, were characterized by X-ray diffraction, transmission electron microscopy, and Fe and As K-edge X-ray absorption spectroscopy. Citrate decreased the particle size of Fh by impairing the polymerization of Fe(O,OH)6 octahedra via edge and corner linkages. In the presence of citrate and As(V), coordination numbers of Fe decreased by up to 28% relative to pure Fh. Citrate significantly reduced the static disorder of Fe-O bonds, implying a decreased octahedral distortion in Fh. Mean bond distances in Fh were not affected by citrate and remained constant within error at 1.98 Å for Fe-O, 3.03 Å for Fe-Fe1, and 3.45 Å for Fe-Fe2. Likewise, citrate had no effect on the As-Fe (3.31 Å) bond distance in As(V) coprecipitated with Fh. The As K-edge EXAFS data comply with the formation of (i) only monodentate binuclear (2C) As(V) surface complexes and (ii) combinations of 2C, monodentate mononuclear (1V), and outersphere As(V) surface complexes. Our results suggest that increasing citrate concentrations led to a decreasing 1V/2C ratio and/or that citrate increasingly impaired the formation of outersphere As(V) complexes. Moreover, citrate stabilized colloidal suspensions of Fh (pH 4.3-6.6, I ∼0.45 M) and reduced Fh formation at the expense of soluble Fe(III)-citrate complexes. At initial citrate/Fe ratios ?25 mol%, between 8% and 41% of total Fe was bound in Fe(III)-citrate complexes after Fh formation. Polynuclear Fe(III)-citrate species were found to bind As(V) via surface complexes indistinguishable by EXAFS from those of As(V) adsorbed to or coprecipitated with Fh. Our study implies that low molecular weight polyhydroxycarboxylates may enhance the mobility of As(V) in aqueous systems of high ionic strength (e.g., neutralizing acid mine drainage) by colloidal stabilization of suspended Fh particles and the formation of ternary As(V) complexes.  相似文献   
135.
We describe an implementation of compressible inviscid fluid solvers with block-structured adaptive mesh refinement on Graphics Processing Units using NVIDIA’s CUDA. We show that a class of high resolution shock capturing schemes can be mapped naturally on this architecture. Using the method of lines approach with the second order total variation diminishing Runge–Kutta time integration scheme, piecewise linear reconstruction, and a Harten–Lax–van Leer Riemann solver, we achieve an overall speedup of approximately 10 times faster execution on one graphics card as compared to a single core on the host computer. We attain this speedup in uniform grid runs as well as in problems with deep AMR hierarchies. Our framework can readily be applied to more general systems of conservation laws and extended to higher order shock capturing schemes. This is shown directly by an implementation of a magneto-hydrodynamic solver and comparing its performance to the pure hydrodynamic case. Finally, we also combined our CUDA parallel scheme with MPI to make the code run on GPU clusters. Close to ideal speedup is observed on up to four GPUs.  相似文献   
136.
While crystallography conventionally presumes that a single crystal carries a unique crystallographic orientation, modern experimental techniques reveal that a single crystal may exhibit an orientation distribution. However, this distribution is largely concentrated; it is extremely concentrated when compared with orientation distributions of polycrystalline specimen. A case study of a deformation experiment with a single hematite crystal is presented, where the experimental deformation induced twining, which in turn changed a largely concentrated unimodal “parent” orientation distribution into a multimodal orientation distribution with a major mode resembling the parent mode and three minor modes corresponding to the progressive twining. The free and open source software MTEX for texture analysis was used to compute and visualize orientations density functions from both integral orientation measurements, i.e. neutron diffraction pole intensity data, and individual orientation measurements, i.e. electron back scatter diffraction data. Thus it is exemplified that MTEX is capable of analysing orientation data from largely concentrated orientation distributions.  相似文献   
137.
Ralf Greve  Rupali A. Mahajan 《Icarus》2005,174(2):475-485
The evolution and dynamics of the north-polar cap (residual-ice-cap/layered-deposits complex) of Mars is simulated with a thermomechanical ice-sheet model. We consider a scenario with ice-free initial conditions at 5 Ma before present due to the large obliquities which prevailed prior to this time. The north-polar cap is then built up to its present shape, driven by a parameterized climate forcing (surface temperature, surface mass balance) based on the obliquity and eccentricity history. The effects of different ice rheologies and different dust contents are investigated. It is found that the build-up scenarios require an accumulation rate of approximately 0.15-0.2 mm a−1 at present. The topography evolution is essentially independent of the ice dynamics due to the slow ice flow. Owing to the uncertainties associated with the ice rheology and the dust content, flow velocities can only be predicted within a range of two orders of magnitude. Likely present values are of the order of 0.1-1 mm a−1, and a strong variation over the climatic cycles is found. For all cases, computed basal temperatures are far below pressure melting.  相似文献   
138.
Line-of-sight velocity distributions of low-luminosity elliptical galaxies   总被引:1,自引:0,他引:1  
The shape of the line-of-sight velocity distribution (LOSVD) is measured for a sample of 14 elliptical galaxies, predominantly low-luminosity ellipticals. The sample is dominated by galaxies in the Virgo cluster but also contains ellipticals in nearby groups and low-density environments. The parametrization of the LOSVD given by Gerhard and van der Marel & Franx is adopted, which measures the asymmetrical and symmetrical deviations of the LOSVD from a Gaussian by the amplitudes h 3 and h 4 of the Gauss–Hermite series. Rotation, velocity dispersion, h 3 and h 4 are determined as a function of radius for both major and minor axes. Non-Gaussian LOSVDs are found for all galaxies along the major axes. Deviations from a Gaussian LOSVD along the minor axis are of much lower amplitude if present at all. Central decreases in velocity dispersion are found for three galaxies. Two galaxies have kinematically decoupled cores: NGC 4458 and the well-known case of NGC 3608.  相似文献   
139.
We present kinematics and stellar population properties of 17 dwarf early-type galaxies in the luminosity range -14 ≥ M B ≥ -19. Our sample fills the gap between the intensively studied giant elliptical and Local Group dwarf spheroidal galaxies. The dwarf ellipticals of the present sample have constant velocity dispersion profiles within their effective radii and do not show significant rotation, hence are clearly anisotropic. The dwarf lenticulars, instead, rotate faster and are, at least partially, supported by rotation. From optical Lick absorption indices, we derive metallicities and element abundances. Combining our sample with literature data of the Local Group dwarf spheroidals and giant ellipticals, we find a surprisingly tight linear correlation between metallicity and luminosity over a wide range: -8 ≥ M B ≥ -22. The α/Fe ratios of our dwarf ellipticals are significantly lower than the ones of giant elliptical galaxies, which is in agreement with spectroscopy of individual stars in Local Group dwarf spheroidals. Our results suggest the existence of a clear kinematic and stellar population dichotomy between dwarf and giant elliptical galaxies. This result is important for theories of galaxy formation, because it implies that present-day dwarf ellipticals are not the fossiled building blocks of giant ellipticals. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
140.
Analytical Lagrangian equations capable of predicting concentration profiles from known source distributions offer the opportunity to calculate source/sink distributions through inverted forms of these equations. Inverse analytical Lagrangian equations provide a practical means of estimating source profiles using concentration and turbulence measurements. Uncertainty concerning estimates of the essentially immeasurable Lagrangian length scale ( ${\mathcal{L}}$ ), a key input, impedes the operational practicality of this method. The present study evaluates ${\mathcal{L}}$ within a corn canopy by using field measurements to constrain an analytical Lagrangian equation. Measurements of net CO2 flux, soil-to-atmosphere CO2 flux, and in-canopy profiles of CO2 concentration provided the information required to solve for ${\mathcal{L}}$ in a global optimization algorithm for 30-min time intervals. For days when the canopy was a strong CO2 sink, the optimization frequently located ${\mathcal{L}}$ profiles that follow a convex shape. A constrained optimization then fit the profile shape to a smooth sigmoidal equation. Inputting the optimized ${\mathcal{L}}$ profiles in the forward and inverse Lagrangian equations leads to strong correlations between measured and calculated concentrations and fluxes. Coefficients of the sigmoidal equation were specific to each 30-min period and did not scale with any measured variable. Plausible looking ${\mathcal{L}}$ profiles were associated with negative bulk Richardson number values. Once the canopy senesced, a simple eddy diffusivity profile sufficed to relate concentrations and sources in the analytical Lagrangian equations.  相似文献   
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