Arsenic distribution, speciation and solubility in shallow groundwater of Owens Dry Lake, California     

J.i-hun RyuSuduan Gao  Randy A. Dahlgren  Robert A. Zierenberg 《Geochimica et cosmochimica acta》2002,66(17):2981-2994

Generation of dust particles from the Owens Lake playa creates a severe air pollution hazard in the western United States. Much of the dust produced from the dry lakebed is derived from salts formed by evaporation of saline groundwater that often contains high concentrations of dissolved arsenic (As). The objectives of this research were to study the spatial distribution of dissolved arsenic in the shallow groundwater, and to examine factors affecting arsenic solubility and speciation. Evapoconcentration, redox potential, pH, and mineral solubility were examined as factors regulating arsenic biogeochemistry. Dissolved arsenic concentrations ranged from 0.1 to 96 mg L⁻¹ and showed a general increase from the shoreline to the center of the lakebed. Arsenic concentrations were strongly correlated to electrical conductivity (EC) and δD suggesting that evapoconcentration is an important process regulating total As concentrations. Arsenite [As(III)] was the dominant form of inorganic arsenic at Eh values less than about −170 mV while arsenate [As(V)] was predominant at higher Eh values. Organic arsenic was negligible (<0.21%) in all shallow groundwater samples. Dissolved arsenic concentrations do not appear to be strongly regulated by solid-phase reactions. Solid-phase arsenic concentrations generally ranged between 4.0 and 42.6 mg kg⁻¹ and a maximum concentration range (20 to 40 mg kg⁻¹) was reached as solution concentration increased up to 80 mg L⁻¹, indicating minimal sorption and/or precipitation of arsenic. Chemical equilibrium modeling indicated that orpiment (As₂S₃) was the only solid phase with a positive saturation index (indicating over-saturation), but only at high arsenic and sulfide concentrations. The findings of this research are important for assessing the potential environmental impacts of elevated arsenic concentrations on dust mitigation efforts taking place at Owens Dry Lake.  相似文献   

Concentrations of unsubstituted polycyclic aromatic hydrocarbons in softshell clams from Coos Bay,Oregon, USA     

Michael C Mix  Randy L Schaffer 《Marine pollution bulletin》1983,14(3):94-97

Concentrations of benzo[a]pyrene (BAP) were measured in subpopulations of softshell clams, Mya arenaria, from four intertidal sites in Coos Bay from June 1976 to June 1978. Subsequently, concentrations of 15 unsubstituted polynuclear aromatic hydrocarbons (PNAH) were determined in two subpopulations from September 1978 to August 1979. There were significant differences between BAP concentrations in clams from the four sites. For the two-year period, they were highest in clams inhabiting areas adjacent to the industrialized bayfront and lowest in clams inhabiting more remote areas. There were no significant seasonal variations in BAP concentrations during this period. During the 1978–1979 study, the average total PNAH concentration in clams from the bayfront area was 555.1 μg kg^?1 compared to 76.3 μg kg^?1 for clams from a more remote environment. In general, PNAH concentrations were lowest in the fall-winter and highest during the spring-summer.  相似文献   

Focused infiltration of snowmelt water in partially frozen soil under small depressions   总被引：5，自引：0，他引：5  

Masaki Hayashi  Garth van der Kamp  Randy Schmidt 《Journal of Hydrology》2003,270(3-4):214-229

Ephemeral puddles in small closed depressions can play an important role in the hydrology and ecology of many landscapes, by storing runoff water, recharging soil moisture and shallow groundwater, and by providing food and habitat for many organisms. Infiltration of snowmelt water under small depressions (<1000 m²) has been studied in the St. Denis National Wildlife Area in Saskatchewan, Canada, located within the northern glaciated prairie of North America where numerous depressions of varying sizes exist. The depressions stored most of the snowmelt runoff generated within their respective watersheds. The water level in a typical depression declined at 0.6 mm/h while the underlying frozen soil was thawing. This rate was likely limited by the rate of downward movement of the thawing front, which was functioning as a moving impermeable boundary. The rate of thawing was controlled by the external energy input from the ground surface. Standing water in depressions efficiently trapped incoming radiation and conducted it to the thawing front. The recession rate increased to 1.1 mm/h when the soil under the depression thawed completely. The recession rate at this later stage appears to be limited by the hydraulic conductivity of the subsoil (0.04–4 mm/h), which is much smaller than the topsoil conductivity (10–20 mm/h).  相似文献   

Ground Water-Lake Interaction Modeling Using the LAK3 Package for MODFLOW 2000     

Randy Hunt 《Ground water》2003,41(2):114-118

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Forensic isotope analysis to refine a hydrologic conceptual model     

Bassett RL  Steinwand A  Jorat S  Petersen C  Jackson R 《Ground water》2008,46(3):372-383

Water resources in the arid southwestern United States are frequently the subject of conflict from competing private and public interests. Legal remedies may remove impasses, but the technical analysis of the problem often determines the future success of legal solutions. In Owens Valley, California, the source of water for the Los Angeles Aqueduct (LAA) is flow diverted from the Owens River and its tributaries and ground water from valley aquifers. Future management of ground water delivered to the LAA needs technical support regarding quantity available, interconnection of shallow and confined aquifers, impact on local springs, and rate of recharge. Ground water flow models and ground water composition are tools already in use, but these have large uncertainty for local interpretations. This study conducted targeted sampling of springs and wells to evaluate the hydrologic system to corroborate conceptual and numerical models. The effort included measurement of intrinsic isotopic composition at key locations in the aquifers. The stable isotopic data of boron (delta(11)B), sulfur (delta(34)S), oxygen (delta(18)O), hydrogen (delta D), and tritium ((3)H) supported by basic chemical data provided rules for characterizing the upper and the lower aquifer system, confirmed the interpretation of ground water flow near faults and flow barriers, and detected hydraulic connections between the LAA and the perennial springs at key locations along the unlined reach of the LAA. This study exemplifies the use of forensic isotopic approaches as independent checks on the consistency of interpretations of conceptual models of a ground water system and the numerical hydrologic simulations.  相似文献   

Historical trends in Chesapeake Bay dissolved oxygen based on benthic foraminifera from sediment cores     

Alexander W. Karlsen  Thomas M. Cronin  Scott E. Ishman  Debra A. Willard  Randy Kerhin  Charles W. Holmes  Marci Marot 《Estuaries and Coasts》2000,23(4):488-508

Environmentally sensitive benthic foraminifera (protists) from Chesapeake Bay were used as bioindicators to estimate the timing and degree of changes in dissolved oxygen (DO) over the past five centuries. Living foraminifers from 19 surface samples and fossil assemblages from 11 sediment cores dated by²¹⁰Pb,¹³⁷Cs,¹⁴C, and pollen stratigraphy were analyzed from the tidal portions of the Patuxent, Potomac, and Choptank Rivers and the main channel of the Chesapeake Bay.Ammonia parkinsoniana, a facultative anaerobe tolerant of periodic anoxic conditions, comprises an average of 74% of modern Chesapeake foraminiferal assemblages (DO-0.47 and 1.72 ml l⁻¹) compared to 0% to 15% of assemblages collected in the 1960s. Paleoecological analyses show thatA. parkinsoniana was absent prior to the late 17th century, increased to 10–25% relative frequency between approximately 1670–1720 and 1810–1900, and became the dominant (60–90%) benthic formaniferal species in channel environments beginning in the early 1970s. Since the 1970s, deformed tests ofA. parkinsoniana occur in all cores (10–20% ofAmmonia), suggesting unprecedented stressful benthic conditions. These cores indicate that prior to the late 17th century, there was limited oxygen depletion. During the past 200 years, decadal scale variability in oxygen depletion has occurred, as dysoxic (DO=0.1–1.0 ml l⁻¹), perhaps short-term anoxic (DO<0.1 ml l⁻¹) conditions developed. The most extensive (spatially and temporally) anoxic conditions were reached during the 1970s. Over decadal timescales, DO variability seems to be linked closely to climatological factors influencing river discharge; the unprecedented anoxia since the early 1970s is attributed mainly to high freshwater flow and to an increase in nutrient concentrations from the watershed.  相似文献   

Radar Detection of Near-Earth Asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN     

Lance A.M. Benner  Steven J. Ostro  Jon D. Giorgini  Raymond F. Jurgens  David L. Mitchell  Randy Rose  Keith D. Rosema  Martin A. Slade  Ron Winkler  Donald K. Yeomans  Donald B. Campbell  John F. Chandler  Irwin I. Shapiro 《Icarus》1997,130(2):296-312

We describe Doppler-only radar observations of near-Earth asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN that were obtained at Arecibo and Goldstone between 1984 and 1996. Estimates of the echo spectral bandwidths, radar cross sections, and circular polarization ratios of these objects constrain their pole-on breadths, radar albedos, surface roughnesses, taxonomic classes, rotation periods, and pole directions. Aten's bandwidth is consistent with its radiometrically determined diameter of 0.9 km. Adonis has a rotation periodP≤ 11 h and an effective diameter (the diameter of a sphere with the same projected area as the asteroid) between 0.3 and 0.8 km. The radar properties of Adonis suggest it is not a member of taxonomic classes C or M. The effective diameter of Xanthus is between 0.4 and 2.2 km with a rotation periodP≤ 20 h. Echoes from 1992 QN constrain the asteroid's pole-on breadth to be ≥0.6 km and probably exclude it from the C and M taxonomic classes. The strongest Eger echoes are asymmetric with bandwidths that set lower bounds of 1.5 and 2.3 km on the minimum and maximum breadths of the asteroid's pole-on silhouette. If Eger is modeled as a 1.5 × 2.3 km biaxial ellipsoid, then its effective diameter for an equatorial view is 1.5 km end-on and 1.9 km broadside or pole-on, implying a geometric albedo smaller than published values but still consistent with a classification as an E-type object. The near-unity circular polarization ratios of Adonis, Eger, and 1992 QN are among the highest values measured for any asteroid or comet and suggest extreme near-surface roughness at centimeter to meter scales.  相似文献   

Supernova remnants, planetary nebulae and the distance to NGC 4214     

Michael A. Dopita  Daniela Calzetti  Jesús Maíz Apellániz  William P. Blair  Knox S. Long  Max Mutchler  Bradley C. Whitmore  Howard E. Bond  John MacKenty  Bruce Balick  Marcella Carollo  Michael Disney  Jay A. Frogel  Robert O’Connell  Donald Hall  Jon A. Holtzman  Randy A. Kimble  Patrick McCarthy  Francesco Paresce  Abhijit Saha  Alistair R. Walker  Joe Silk  Marco Sirianni  John Trauger  Rogier Windhorst  Erick Young 《Astrophysics and Space Science》2010,330(1):123-131

We present narrow band, continuum subtracted Hα, [S ii], Hβ, [O iii] and [O ii] data taken with the Wide Field Camera 3 on the Hubble Space Telescope in the nearby dwarf starburst galaxy NGC 4214. From these images, we identify seventeen new planetary nebula candidates, and seven supernova remnant candidates. We use the observed emission line luminosity function of the planetary nebulae to establish a new velocity-independent distance to NGC 4214. We conclude that the PNLF technique gives a reddening independent distance to NGC 4214 of 3.19±0.36 Mpc, and that our current best-estimate of the distance to this galaxy ids 2.98±0.13 Mpc.  相似文献   

Radar observations and a physical model of Asteroid 4660 Nereus, a prime space mission target     

Marina Brozovic  Steven J. Ostro  Jon D. Giorgini  Randy Rose  Alice A. Hine  Daniel J. Scheeres 《Icarus》2009,201(1):153-166

Near-Earth Asteroid 4660 Nereus has been identified as a potential spacecraft target since its 1982 discovery because of the low delta-V required for a spacecraft rendezvous. However, surprisingly little is known about its physical characteristics. Here we report Arecibo (S-band, 2380-MHz, 13-cm) and Goldstone (X-band, 8560-MHz, 3.5-cm) radar observations of Nereus during its 2002 close approach. Analysis of an extensive dataset of delay-Doppler images and continuous wave (CW) spectra yields a model that resembles an ellipsoid with principal axis dimensions X=510±20 m, Y=330±20 m and . The pole direction is approximately located at ecliptic pole longitude and latitude of λ=+25°, β=+80° with the uncertainty radius of 10°. Our modeling yields a refined rotation period of 15.16±0.04 h. Nereus has a circular polarization (SC/OC) ratio of 0.74±0.08, which implies substantial near-surface centimeter-to-decimeter scale roughness. Dynamical analysis of our model suggests that YORP alteration of the rotation period may become evident within a few years. Nereus has two stable synchronous orbits where natural material may remain in orbit, while most asteroids observed to date do not have such stable synchronous orbits. We also find that spacecraft orbits about Nereus are feasible.  相似文献   

Compositional and lithological diversity among brecciated lunar meteorites of intermediate iron concentration     

Randy L. Korotev  Ryan A. Zeigler  Bradley L. Jolliff  Anthony J. Irvin  Theodore E. Bunch 《Meteoritics & planetary science》2009,44(9):1287-1322

Abstract— We present new compositional data for 30 lunar stones representing about 19 meteorites. Most have iron concentrations intermediate to those of the numerous feldspathic lunar meteorites (3–7% FeO) and the basaltic lunar meteorites (17–23% FeO). All but one are polymict breccias. Some, as implied by their intermediate composition, are mainly mixtures of brecciated anorthosite and mare basalt, with low concentrations of incompatible elements such as Sm (1–3 μg/g). These breccias likely originate from points on the Moon where mare basalt has mixed with material of the FHT (Feldspathic Highlands Terrane). Others, however, are not anorthosite‐basalt mixtures. Three (17–75 μ/g Sm) consist mainly of nonmare mafic material from the nearside PKT (Procellarum KREEP Terrane) and a few are ternary mixtures of material from the FHT, PKT, and maria. Some contain mafic, nonmare lithologies like anorthositic norites, norites, gabbronorites, and troctolite. These breccias are largely unlike breccias of the Apollo collection in that they are poor in Sm as well as highly feldspathic anorthosite such as that common at the Apollo 16 site. Several have high Th/Sm compared to Apollo breccias. Dhofar 961, which is olivine gabbronoritic and moderately rich in Sm, has lower Eu/Sm than Apollo samples of similar Sm concentration. This difference indicates that the carrier of rare earth elements is not KREEP, as known from the Apollo missions. On the basis of our present knowledge from remote sensing, among lunar meteorites Dhofar 961 is the one most likely to have originated from South Pole‐Aitken basin on the lunar far side.  相似文献