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31.
Results of a single group participating in an international experiment are analyzed. The experiment served to verify computational predictions of the ground-motion variations due to near-surface geological effects at a site established for that purpose by the California Department of Conservation. Based on an acceleration record at a rock location, and geotechnical model of medium, records at the other locations of a nearby sedimentary deposit were predicted. A 2-D finite-difference sensitivity analysis suggested that the lateral wave-propagation effects are negligibly small, and locally 1-D computations are sufficient for the present site. Those computations are compared with observations not available to the authors during the blind prediction. Peak accelerations, peak velocities and RMS accelerations were predicted with errors less than 159%, 114% and 62%, respectively. Maxima of the response spectra were fitted within a factor of 2. The predicted and observed Husid's plots (i.e., the normalized cumulative plots of the acceleration squared) have the correlation coefficients 0.98. The detected misfits do not show any simple relation to the instrument location, component, frequency, or time. 相似文献
32.
The geochemistry of Hercynian tin-bearing granitoid massifs of the Krune hory Mts. (Erzgebirge), Slavkovský les Forest (Kaiserwald) and Smriny (eastern Fichtelgebirge) is compared by statistical processing of 270 analyses including a wide spectrum of major and trace elements. Seven different types of granites are distinguished. Out of these, five types represent the successive differentiation of the largest massif of NW Bohemia: the Karlovy Vary (Karlsbad) massif. This comprises strongly differentiated peraluminous granites evolving towards extreme Li-Rb-Cs-F-and Sn-enrichment in the youngest members, which are albite-topaz-zinwaldite lithium granites. The sixth and seventh types are different from the former by their location in the eastern Krune hory and tectonic setting, and they display geochemical features of anorogenic granites: they are metaluminous albite-zinwaldite granites with marked enrichment of Nb, Y, and HREE in addition to Li, Rb, Cs, F and Sn, indicating contamination by sub-crustal material. Sn-W mineralizations, including flat peri-contact greisen bodies, steep greisen veins and tourmalinized phyllites, are all intimately associated with the most strongly differentiated granites — the Li-granite and the Cinovec-granite respectively. 相似文献
33.
B. Andersen V. Domingo A. Jiménez A. Jones S. Korzennik P. L. Pallé F. Pérez Hernández C. Régulo T. Roca Cortés L. L. Tomás 《Solar physics》1988,116(2):391-399
Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively. 相似文献
34.
On the coronograph spectrophotographic records taken on 31.372 UT, August 1979, some faint emission features were found which can be ascribed to Siii and Niii. These emissions were obviously a transient phenomena which were detected only 10 hr after the supposed fall of Comet 1979 XI in the Sun's photosphere. It cannot be excluded that the appearance of Si and Ni lines was triggered by the evaporation of dust particles with a high abundance of heavier elements in the solar corona. This assumption is also supported by intensity distribution of the Fex coronal line around the Sun's limb. The maximum coincide with the position angle of the projected path of the comet. 相似文献
35.
C. Moreno R. Sáez F. González G. Almodóvar M. Toscano G. Playford A. Alansari S. Rziki A. Bajddi 《Mineralium Deposita》2008,43(8):891-911
The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south
of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The
hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern
orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized
as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal
gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation
of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition
and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical
data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary
below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization
of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age
of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints. 相似文献
36.
L. Moreno J. J. Durán M. A. Casermeiro J. R. Quintana Ma A. Fernández 《Environmental Geology》2008,54(3):465-477
Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored
to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the
best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate
is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is
almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil
and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass
discharged was relatively large (COD 14,656 g/m2, NO3 85 g/m2, NO2 4 g/m2, NH4 2,425 g/m2, PO4 1,143 g/m2, K 1,531 g/m2, B 63 g/m2). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO4 94.4%, K 59.17%, N
total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was
eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts
of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of
the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water,
and are proposed as the best indicators. 相似文献
37.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
38.
M. M. Jordán S. Pina F. García-Orenes M. B. Almendro-Candel E. García-Sánchez 《Environmental Geology》2008,55(2):453-462
The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These
materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic
amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients
with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using
columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality,
came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone
materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water
contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order
to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications.
Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium,
phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values
obtained were very elevated. 相似文献
39.
Joanne Muller Malin Kylander Antonio Martinez-Cortizas Dominik Weiss Kevin Blake Raquel Garcia-Sanchez 《Geochimica et cosmochimica acta》2008,72(2):449-463
The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands. 相似文献
40.
Magnesium isotope systematics of the lithologically varied Moselle river basin, France 总被引:2,自引:0,他引:2
Agnès Brenot Christophe Cloquet Nathalie Vigier Jean Carignan Christian France-Lanord 《Geochimica et cosmochimica acta》2008,72(20):5070-5089
Magnesium and strontium isotope signatures were determined during different seasons for the main rivers of the Moselle basin, northeastern France. This small basin is remarkable for its well-constrained and varied lithology on a small distance scale, and this is reflected in river water Sr isotope compositions. Upstream, where the Moselle River drains silicate rocks of the Vosges mountains, waters are characterized by relatively high 87Sr/86Sr ratios (0.7128-0.7174). In contrast, downstream of the city of Epinal where the Moselle River flows through carbonates and evaporites of the Lorraine plateau, 87Sr/86Sr ratios are lower, down to 0.70824.Magnesium in river waters draining silicates is systematically depleted in heavy isotopes (δ26Mg values range from −1.2 to −0.7‰) relative to the value presently estimated for the continental crust and a local diorite (−0.5‰). In comparison, δ26Mg values measured in soil samples are higher (∼0.0‰). This suggests that Mg isotope fractionation occurs during mineral leaching and/or formation of secondary clay minerals. On the Lorraine plateau, tributaries draining marls, carbonates and evaporites are characterized by low Ca/Mg (1.5-3.2) and low Ca/Sr (80-400) when compared to local carbonate rocks (Ca/Mg = 29-59; Ca/Sr = 370-2200), similar to other rivers draining carbonates. The most likely cause of the Mg and Sr excesses in these rivers is early thermodynamic saturation of groundwater with calcite relative to magnesite and strontianite as groundwater chemistry progressively evolves in the aquifer. δ26Mg of the dissolved phases of tributaries draining mainly carbonates and evaporites are relatively low and constant throughout the year (from −1.4‰ to −1.6‰ and from −1.2‰ to −1.4‰, respectively), within the range defined for the underlying rocks. Downstream of Epinal, the compositions of the Moselle River samples in a δ26Mg vs. 87Sr/86Sr diagram can be explained by mixing curves between silicate, carbonate and evaporite waters, with a significant contribution from the Vosgian silicate lithologies (>70%). Temporal co-variation between δ26Mg and 87Sr/86Sr for the Moselle River throughout year is also observed, and is consistent with a higher contribution from the Vosges mountains in winter, in terms of runoff and dissolved element flux. Overall, this study shows that Mg isotopes measured in waters, rocks and soils, coupled with other tracers such as Sr isotopes, could be used to better constrain riverine Mg sources, particularly if analytical uncertainties in Mg isotope measurements can be improved in order to perform more precise quantifications. 相似文献