Choosing methods for estimating dissolved and particulate riverine fluxes from monthly sampling     

Sébastien Raymond  Florentina Moatar  Michel Meybeck  Vincent Bustillo 《水文科学杂志》2013,58(6):1326-1339

Abstract

In discrete water quality surveys, riverine fluxes are associated with unknown uncertainties (biases and imprecisions). Annual flux errors have been determined from the generation of discrete surveys by Monte Carlo sorting for monthly sampling, from 10 years of daily records (120 records). Eight calculation methods were tested for suspended particulate matter, dissolved solids and dissolved and total nutrients in medium to large basins (10³ to 10⁶ km²) covering a wide range of hydrological conditions and riverine biogeochemistry. The performance of each method was analysed first by type of riverine material, which appeared to be much less pertinent than the flux variability matrix. The latter combines the river flow duration in two percent of time (W_2%) and the truncated exponent (b_50sup) defining the relationship of concentration vs discharge (C–Q) at higher flows (C = aQ^b50sup). As flux variability increases (high W_2% and/or high b_50sup), averaging and rating curve methods become less efficient compared to hydrograph separation methods. Flux biases and imprecisions were plotted in the [W_2%, b_50sup] matrix for discrete monthly surveys.

Editor Z. W. Kundzewicz

Citation Raymond, S., Moatar, F., Meybeck, M., and Bustillo, V., 2013. Choosing methods for estimating dissolved and particulate riverine fluxes from monthly sampling. Hydrological Sciences Journal, 58 (6), 1326–1339.  相似文献   

Olivine or impact melt: Nature of the “Orange” material on Vesta from Dawn     

Lucille Le Corre  Vishnu Reddy  Nico Schmedemann  Kris J. Becker  David P. O’Brien  Naoyuki Yamashita  Patrick N. Peplowski  Thomas H. Prettyman  Jian-Yang Li  Edward A. Cloutis  Brett W. Denevi  Thomas Kneissl  Eric Palmer  Robert W. Gaskell  Andreas Nathues  Michael J. Gaffey  David W. Mittlefehldt  William B. Garry  Holger Sierks  Christopher T. Russell  Carol A. Raymond  Maria C. De Sanctis  Eleonora Ammanito 《Icarus》2013

NASA’s Dawn mission observed a great variety of colored terrains on asteroid (4) Vesta during its survey with the Framing Camera (FC). Here we present a detailed study of the orange material on Vesta, which was first observed in color ratio images obtained by the FC and presents a red spectral slope. The orange material deposits can be classified into three types: (a) diffuse ejecta deposited by recent medium-size impact craters (such as Oppia), (b) lobate patches with well-defined edges (nicknamed “pumpkin patches”), and (c) ejecta rays from fresh-looking impact craters. The location of the orange diffuse ejecta from Oppia corresponds to the olivine spot nicknamed “Leslie feature” first identified by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157) from ground-based spectral observations. The distribution of the orange material in the FC mosaic is concentrated on the equatorial region and almost exclusively outside the Rheasilvia basin. Our in-depth analysis of the composition of this material uses complementary observations from FC, the visible and infrared spectrometer (VIR), and the Gamma Ray and Neutron Detector (GRaND). Several possible options for the composition of the orange material are investigated including, cumulate eucrite layer exposed during impact, metal delivered by impactor, olivine–orthopyroxene mixture and impact melt. Based on our analysis, the orange material on Vesta is unlikely to be metal or olivine (originally proposed by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157)). Analysis of the elemental composition of Oppia ejecta blanket with GRaND suggests that its orange material has ∼25% cumulate eucrite component in a howarditic mixture, whereas two other craters with orange material in their ejecta, Octavia and Arruntia, show no sign of cumulate eucrites. Morphology and topography of the orange material in Oppia and Octavia ejecta and orange patches suggests an impact melt origin. A majority of the orange patches appear to be related to the formation of the Rheasilvia basin. Combining the interpretations from the topography, geomorphology, color and spectral parameters, and elemental abundances, the most probable analog for the orange material on Vesta is impact melt.  相似文献   

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn     

M. Cristina De Sanctis  Eleonora Ammannito  M. Teresa Capria  Fabrizio Capaccioni  Jean‐Philippe Combe  Alessandro Frigeri  Andrea Longobardo  Gianfranco Magni  Simone Marchi  Tom B. McCord  Ernesto Palomba  Federico Tosi  Francesca Zambon  Francesco Carraro  Sergio Fonte  Y. J. Li  Lucy A. McFadden  David W. Mittlefehldt  Carle M. Pieters  Ralf Jaumann  Katrin Stephan  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2013,48(11):2166-2184

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.  相似文献   

Global thermal inertia and surface properties of Mars from the MGS mapping mission   总被引：1，自引：0，他引：1  

Nathaniel E. Putzig  Michael T. Mellon  Raymond E. Arvidson 《Icarus》2005,173(2):325-341

We present a new high-resolution map of thermal inertia derived from observations of planetary brightness temperature by the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) obtained during the entire MGS primary mapping mission. Complete seasonal coverage provides a nearly global view of Mars, including the polar regions, at a spatial resolution of approximately 3 km. Our map of nighttime thermal-bolometer-based thermal inertia covers approximately 60% of the surface between 80° S and 80° N latitudes. We confirm the global pattern of high and low thermal inertia seen in lower resolution mapping efforts and provide greater detail concerning a third surface unit with intermediate values of both thermal inertia and albedo first identified by Mellon et al. 2000, Icarus 148, 437-455. Several smaller regional units with distinct characteristics are observed. Most notably, a unit of low thermal inertia () and low-to-intermediate albedo (0.09-0.22) dominates the region polewards of 65° S. We consider possible causes for these characteristics and conclude that a low-density mantle formed by desiccation of a previously ice-rich near-surface layer is the most likely explanation for the observed thermophysical properties. Global comparison of thermal inertia and elevation shows that high and low thermal inertia values can be found over a broad range of elevation, with only low values (30-) occurring at the highest elevations and the highest values occurring only at lower elevations. However, the lowest values () are found only at lower elevations, implying that the distribution of low thermal inertia material is not solely controlled by atmospheric pressure and the trapping of fines at high elevations. A new estimate of thermal inertia for the Viking and Pathfinder landing sites helps establish an important link between surface characteristics observed in situ and those derived from remote-sensing data.  相似文献   

Benthic diatom communities as indicators of anthropogenic metal contamination at Casey Station,Antarctica     

Laura?Cunningham  Ben?Raymond  Ian?Snape  Martin J.?RiddleEmail author 《Journal of Paleolimnology》2005,33(4):499-513

Prior to environmental legislation in the 1980s, anthropogenic waste in Antarctica was often deposited into landfill sites or into the sea. This resulted in metal contamination in terrestrial and near-shore marine environments. In this study, we assess the feasibility of using both past and present diatom assemblages to reconstruct and monitor past and future metal contamination. Our dataset included the analyses of both surface sediment samples and sediment cores from a contaminated site near Casey Station, Antarctica. Redundancy analyses indicated a strong relationship between metal concentrations and the composition of diatom communities. Within the surface sediment samples, tin and lead individually explained 43% of the variation observed in the diatom data; copper and iron explained 42% of this variation. In the sediment cores, tin and lead individually explained 53% of the variation in diatom community composition. In the same samples copper explained 47% of this variation, with iron explaining 46% of the observed variation. Once one metal had been selected, incorporating further metal data into the analyses added little extra information. Modern analog technique (MAT) analyses showed a strong correlation between actual and predicted values within one dataset (R²: Cu 0.75; Pb 0.86; Sn 0.89; p<0.05 for each). MAT reconstructions of metal concentrations closely followed measured concentrations, with both high and low concentrations recorded. MAT analyses performed favorably when compared to predictive techniques based on multivariate linear regression and multilayer perceptron neural networks. This study demonstrates that the composition of benthic diatom communities is a good indicator of anthropogenic metal contamination, and may be useful in monitoring the success of environmental remediation strategies in Antarctica and elsewhere.  相似文献   

River discharge controls phytoplankton dynamics in the northern San Francisco Bay estuary     

James E. Cloern  Andrea E. Alpine  Brian E. Cole  Raymond L.J. Wong  James F. Arthur  Melvin D. Ball 《Estuarine, Coastal and Shelf Science》1983,16(4):415-429

Phytoplankton dynamics in the upper reach of the northern San Francisco Bay estuary are usually characterized by low biomass dominated by microflagellates or freshwater diatoms in winter, and high biomass dominated by neritic diatoms in summer. During two successive years of very low river discharge (the drought of 1976-77), the summer diatom bloom was absent. This is consistent with the hypothesis that formation of the diatom population maximum is a consequence of the same physical mechanisms that create local maxima of suspended sediments in partially-mixed estuaries: density-selective retention of particles within an estuarine circulation cell. Because the estuary is turbid, calculated phytoplankton growth rates are small in the central deep channel but are relatively large in lateral shallow embayments where light limination is less severe. When river discharge falls within a critical range (100–350 m³ s^?1) that positions the suspended particulate maximum adjacent to the productive shallow bays, the population of neritic diatoms increases. However, during periods of high discharge (winter) or during periods of very low discharge (drought), the suspended particulate maximum is less well-defined and is uncoupled (positioned downstream or upstream) from the shallow bays of the upper estuary, and the population of neritic diatoms declines. Hence, the biomass and community composition of phytoplankton in this estuary are controlled by river discharge.  相似文献   

Flare parameters for the 7 September, 1973 two-ribbon flare     

J. G. Doyle  J. C. Raymond 《Solar physics》1984,90(1):97-110

A study is made of the relative importance of the various energy loss mechanisms for the long-decay event of 7 September, 1973, using spectral scans in the 400 Å–1335 Å range. This spectral range contains many of the important electron density and temperature diagnostic line ratios for the solar transition zone. We refine earlier analyses of the flare energy budget using more detailed emission measure curves and density diagnostics. We examine the constant pressure assumptions used in both coronal loop models and in the interpretation of observations in terms of flare energetics. We find that much of the upper transition region emission originates in cooling loops. Radiative losses are found to dominate.  相似文献   

Geochemical influences on H40/1 bacteriophage inactivation in glaciofluvial sands     

Raymond?FlynnEmail author  Daniel?Hunkeler  Christine?Guerin  Christine?Burn  Pierre?Rossi  Michel?Aragno 《Environmental Geology》2004,45(4):504-517

Geochemical heterogeneities may cause spatial variations in virus inactivation rates resulting from interactions with minerals leading to differences in natural disinfection capacity within an aquifer. Column studies investigating the interaction of the bacteriophage H40/1 with natural sands sampled from the Kappelen test site (Kappelen), Bern, Switzerland indicated that inactivation rates are higher for adsorbed bacteriophages than for those suspended in groundwater. Moreover, breakthrough curves obtained from field-based tracer tests at Kappelen indicated that the adsorbed H40/1 is inactivated in-situ at comparable rates. Statistical analyses of mineralogical data failed to demonstrate significant spatial variations in aquifer composition either across the site or with depth. In contrast hydrochemical analyses of groundwater samples collected at Kappelen demonstrated that iron-reducing groundwater occurs below aerobic waters. Tracer breakthrough curves indicate that H40/1 survival is not affected by variable redox conditions. Investigation results suggest that spatial geochemical variability does not significantly affect H40/1s inactivation rate at Kappelen.  相似文献   

Âges KAr des roches magmatiques du fossé de Garoua (Cameroun) : leur place dans le cadre de la « Ligne du Cameroun »     

Raymond Montigny  Ismaïla Ngounouno  Bernard Druelle 《Comptes Rendus Geoscience》2004,336(16):285

KAr analyses on whole rock and minerals are reported for the Kokoumi anorogenic pluton and alkaline volcanics of the Benue valley, west of Garoua (northern Cameroon), which belong to the northern part of the ‘Cameroon Line’. The two formations yield similar ages of 39 and 37 Ma, respectively. These values likely correspond to the time of emplacement. They are in agreement with the interpretation considering the ‘Cameroon Line’ as a huge lithospheric crack tapping a hot deep asthenospheric zone. To cite this article: R. Montigny et al., C. R. Geoscience 336 (2004).  相似文献   

The effects of seasonal variability and weather on microbial fecal pollution and enteric pathogens in a subtropical estuary     

Erin K. Lipp  Raymond Kurz  Robert Vincent  Cesar Rodriguez-Palacios  Samuel R. Farrah  Joan B. Rose 《Estuaries and Coasts》2001,24(2):266-276

The Charlotte Harbor estuary in southwest Florida was sampled monthly for one year at twelve stations, in the lower reaches of the Myakka and Peace Rivers. The objectives of the study were to address the distribution and seasonal changes in microbial indicators and human pathogen levels in Charlotte Harbor shellfish and recreational waters, and to determine those factors that may be important in the transport and survival of pathogens. Monthly water samples and quarterly sediment samples were analyzed for fecal coliform bacteria, enterococci,Clostridium perfringens, and coliphage. Quarterly samples also were analyzed for the enteric human pathogens,Cryptosporidium spp.,Giardia spp., and enteroviruses. Fecal indicator organisms were generally concentrated in areas of low salinity and high densities of septic systems; however, pollution became widespread during wet weather in, the late fall and winter of 1997–1998, coincident with a strong El Nino event. Between, December 1997 and February 1998, enteroviruses were detected at 75% of the sampling stations; none were detected in other months. Enteric protozoa were detected infrequently and were not related to seasonal influences. Fecal indicators and enteroviruses were each significantly associated with rainfall, streamflow, and temperature. Regression models suggest that temperature and rainfall can predict the occurrence of enteroviruses in 93.7% of the cases. Based on findings in this watershed, factors such as variability in precipitation, streamflow, and temperature show promise in modeling and forecasting periods of poor coastal water quality.  相似文献