The structure and transformation of the nanomineral schwertmannite: a synthetic analog representative of field samples     

Rebecca A. French  Niven Monsegue  Mitsuhiro Murayama  Michael F. Hochella Jr. 《Physics and Chemistry of Minerals》2014,41(4):237-246

The phase transformation of schwertmannite, an iron oxyhydroxide sulfate nanomineral synthesized at room temperature and at 75 °C using H₂O₂ to drive the precipitation of schwertmannite from ferrous sulfate (Regenspurg et al. in Geochim Cosmochim Acta 68:1185–1197, 2004), was studied using high-resolution transmission electron microscopy. The results of this study suggest that schwertmannite synthesized using this method should not be described as a single phase with a repeating unit cell, but as a polyphasic nanomineral with crystalline areas spanning less than a few nanometers in diameter, within a characteristic ‘pin-cushion’-like amorphous matrix. The difference in synthesis temperature affected the density of the needles on the schwertmannite surface. The needles on the higher-temperature schwertmannite displayed a dendritic morphology, whereas the needles on the room-temperature schwertmannite were more closely packed. Visible lattice fringes in the schwertmannite samples are consistent with the powder X-ray diffraction (XRD) pattern taken on the bulk schwertmannite and also matched d-spacings for goethite, indicating a close structural relationship between schwertmannite and goethite. The incomplete transformation from schwertmannite to goethite over 24 h at 75 °C was tracked using XRD and TEM. TEM images suggest that the sample collected after 24 h consists of aggregates of goethite nanocrystals. Comparing the synthetic schwertmannite in this study to a study on schwertmannite produced at 85 °C, which used ferric sulfate, reveals that synthesis conditions can result in significant differences in needle crystal structure. The bulk powder XRD patterns for the schwertmannite produced using these two samples were indistinguishable from one another. Future studies using synthetic schwertmannite should account for these differences when determining schwertmannite’s structure, reactivity, and capacity to take up elements like arsenic. The schwertmannite synthesized by the Regenspurg et al. method produces a mineral that is consistent with the structure and morphology of natural schwertmannite observed in our previous study using XRD and TEM, making this an ideal synthetic method for laboratory-based mineralogical and geochemical studies that intend to be environmentally relevant.  相似文献   

Interactions between Northern-Shifting Tropical Species and Native Species in the Northern Gulf of Mexico     

Rebecca L. Gericke  Kenneth L. Heck Jr.  F. Joel Fodrie 《Estuaries and Coasts》2014,37(4):952-961

Niche models applied in the context of future climate change predict that as regional temperatures increase, the distribution of tropical species will shift poleward. While range expansions have been documented for a number of species, there is limited information on the ecological impacts of shifts on native species. Recently, abundances of tropically-associated gray snapper (Lutjanus griseus) and lane snapper (Lutjanus synagris) have increased in seagrass nurseries in the northern Gulf of Mexico (GOM), concurrent with regional increases in sea surface temperature. We investigated effects of increased abundances of these species on abundance and growth of pinfish (Lagodon rhomboides), the dominant native species. Because juvenile pinfish and snappers share common prey, predators, and habitat, the high degree of niche overlap suggests an equally high potential for competition. We used a multiple before–after control impact design to determine whether increased snapper abundances significantly affected abundance or growth of pinfish. Trawl surveys at six locations in the northern GOM in summer and fall 2010 were used to calculate pinfish and snapper abundances. We identified three locations with high snapper abundances and three locations with no snapper and compared pinfish abundance and otolith-determined growth rates in these locations before and after snapper recruitment. Paired t tests and two-way analysis of variance revealed no significant differences in pinfish abundance or growth in the presence of snappers compared to locations and seasons without snappers. We conclude that range expansions of tropically associated snappers have had no significant effect on abundance or growth of native pinfish in northern GOM seagrass habitats.  相似文献   

A review of the magnitude and response times for sediment yield reductions following the rehabilitation of gullied landscapes     

Rebecca Bartley  Jean Poesen  Scott Wilkinson  Matthias Vanmaercke 《地球表面变化过程与地形》2020,45(13):3250-3279

Gully erosion is a major driver of elevated sediment yields across many areas of the globe, and considerable rehabilitation has occurred to reduce the amount of sediment eroded from gullies. However, compared to other forms of erosion, there has been little systematic review of the effectiveness of gully rehabilitation on reducing sediment yields. This study reviewed the global literature to provide an understanding of the potential sediment yield reductions that can occur following the rehabilitation of gullied landscapes. We focused on studies reporting a measured response on how gully and catchment sediment yield has changed since treatment. A total of 37 studies were found that met this criterion. The studies were partitioned into three broad categories, including those focused on: (i) treating the catchment above the gully; (ii) installing treatments in the actual gully channel; and (iii) a combination of approaches which include treating both the catchment and the gully channel. All the studies demonstrated a reduction in sediment yield following gully rehabilitation, with reported values ranging between 12 and 94%. The timeframes associated with the reductions in sediment yield varied considerably (2–80 years). Applying a variety of rehabilitation measures, which generally includes treating both the hillslope above the gully, and trapping sediment within the gully, appears to result in shorter (median) timescales for sediment yield reduction. Overall, this review indicates that gully rehabilitation strategies combining both engineering and vegetation measures are often the most successful. Engineering measures such as check dams are important for stabilizing sites in the early phases to support the revegetation of gullies and adjacent hillslopes. However, vegetation is the key to the long-term success of gully rehabilitation. This is because many engineering structures eventually fail, or they have a limited life span as an active sediment trap. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Simulated perturbation in the sea-to-air flux of dimethylsulfi de and the impact on polar climate     

Bo QU  Albert JGABRIC  Rebecca JACKSON 《海洋湖沼学报（英文）》2021,(1):110-121

Marine biogenic emission of dimethylsulfi de(DMS)has been well recognized as the main natural source of reduced sulfur to the remote marine atmosphere and has the potential to aff ect climate,especially in the polar regions.We used a global climate model(GCM)to investigate the impact on atmospheric chemistry from a change to the contemporary DMS fl ux to that which has been projected for the late 21 st century.The perturbed simulation corresponded to conditions that pertained to a tripling of equivalent CO 2,which was estimated to occur by year 2090 based on current worst-case greenhouse gas emission scenarios.The changes in zonal mean DMS fl ux were applied to 50°S–70°S Antarctic(ANT)and 65°N–80°N Arctic(ARC)regions.The results indicate that there are clearly diff erent impacts after perturbation in the southern and northern polar regions.Most quantities related to the sulfur cycle show a higher increase in ANT.However,most sulfur compounds have higher peaks in ARC.The perturbation in DMS fl ux leads to an increase of atmospheric DMS of about 45%in ANT and 33.6%in ARC.The sulfur dioxide(SO 2)vertical integral increases around 43%in ANT and 7.5%in ARC.Sulfate(SO 4)vertical integral increases by 17%in ANT and increases around 6%in ARC.Sulfur emissions increases by 21%in ANT and increases by 9.7%in ARC.However,oxidation of DMS by OH increases by 38.2%in ARC and by 15.17%in ANT.Aerosol optical depth(AOD)increases by 4%in the ARC and by 17.5%in the ANT,and increases by 22.8%in austral summer.The importance of the perturbation of the biogenic source to future aerosol burden in polar regions leads to a cooling in surface temperature of 1 K in the ANT and 0.8 K in the ARC.Generally,polar regions in the Antarctic Ocean will have a higher off setting eff ect on warming after DMS fl ux perturbation.  相似文献   

Accretion of the NW Himalayan foreland pre-dates Late Cenozoic climate change     

Ellen A. Lamont  Francis J. Sousa  Andrew J. Meigs  Ramakrishna Jayangondaperumal  Rebecca M. Flowers  Aravind Anilkumar  Danielle Woodring  Edward R. Sobel 《地学学报》2023,35(1):41-48

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