Host rock compositional controls on zircon trace element signatures in metabasites from the Austroalpine basement   总被引：11，自引：0，他引：11  

Bernhard Schulz  Reiner Klemd 《Geochimica et cosmochimica acta》2006,70(3):697-710

Zircon populations of Neoproterozoic and early Paleozoic age occur in metabasites of a high-pressure amphibolite-facies unit of the Austroalpine basement south of the Tauern Window. The host rocks for these zircons are eclogitic amphibolites of N-MORB-type character, hornblende gneisses with volcanic-arc basalt signature, and alkaline within-plate-basalt amphibolites. Bulk rock magmatic trace element patterns were preserved during amphibolite-facies high-pressure and subsequent high-temperature events, as well as a greenschist-facies overprint. Positive Ce and negative Eu anomalies and enrichment of HREE in normalized zircon REE patterns, as analysed by LA-ICP-MS, are typical for an igneous origin of these zircon suites. Zircon Y is well correlated to HREE, Ce, Th, U, Nb, and Ta and allows discrimination of compositional fields for each host rock type. Low Th/U ratios are correlated to low Y and HREE abundances in zircon from low bulk Th/U host rocks. This is likely a primary igneous characteristic that cannot be attributed to metamorphic recrystallization. Variations of zircon/host rock element ratios confirm that ionic radii and charges control abundances of many trace elements in zircon. The trace element ratios—presented as mineral/melt distribution coefficients—indicate a selectively inhibited substitution of Zr and Si by HREE and Y in zircon which crystallized from a N-MORB melt. Correlated host rock and zircon trace element concentrations indicate that the metabasite zircons are not xenocrysts but crystallized from mafic melts, represented by the actual host rocks.  相似文献   

俯冲洋岛玄武岩脱水释放的水流体成分：来自西天山榴辉岩相高压脉的约束     

熊贤明  高俊  Reiner KLEMD  黄德志 《岩石学报》2006,22(1):103-114

俯冲洋壳的脱水作用对于岛弧火山岩的成因具有重要意义。西天山高压低温变质带中切割主岩蓝片岩/榴辉岩的榴辉岩相脉体记录了古生代俯冲带中的脱水过程。脉体具有典型高压矿物组合：石榴石(＞8%)+绿辉石(15%)+石英(＞55%)+蓝闪石(5%)+冻蓝闪石(10%)±黝帘石±方解石。高压脉及其主岩的岩相学与矿物化学研究表明流体是在俯冲过程中蓝片岩向榴辉岩进变质条件下释放。脉的主量元素成分显示流体富Si。主岩的稀土元素和微量元素表明其原岩为洋岛玄武岩(OIB)。脉和主岩具有相似的微量元素配分模式,并且相对N-MORB都显示富Li、Be、Cs、Rb、Ba、Pb、La的特点。通过模拟计算,在高压脉、与脉平衡的流体以及模拟的原生流体中都富集流体活动性元素(Li、Be、Pb)和LILE(Cs、Rb、Ba),贫HFSE(Nb)和REE(Nd、Sm)。证实了在古生代南天山洋俯冲时洋岛玄武岩脱水释放出富Li、Be、LILE、La和Pb,贫HFSE和HREE的流体。  相似文献   

Different carbon reservoirs of auriferous fluids in African Archean and Proterozoic gold deposits? Constraints from stable carbon isotopic compositions of quartz-hosted CO2-rich fluid inclusions     

Volker Lüders  Reiner Klemd  Thomas Oberthür  Birgit Plessen 《Mineralium Deposita》2015,50(4):449-454

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俯冲带流体——来自（超）高压变质岩石的证据     

高俊  李继磊  马智佩  Reiner KLEMD 《地质学报》2024,98(3):758-782

俯冲带是地球上岩浆活动、高压—超高压变质作用、中深源地震、壳幔物质交换、元素循环和铜金大规模成矿的集中发生场所。富水流体不仅调控了这些地质作用,而且也深刻影响了全球C、S等挥发分的循环。当蚀变大洋岩石圈及上覆沉积物进入俯冲带中深部（15~300 km）,伴随由葡萄石- 绿纤石相至超高压榴辉岩相的递进变质作用,含水矿物在不同深度的分解造成流体释放为一连续过程。除极端高地温梯度环境之外,大多数俯冲带洋壳释放的流体为富水流体。但,俯冲带不同深度所产生的流体特征有明显差异。出露于全球造山带的高压—超高压变质地体保存了分凝体、脉体、水压致裂角砾岩等流体作用的有力证据,绿辉石、石榴子石、绿帘石等矿物中原生流体包裹体为流体的直接记录。在俯冲带中等深度（＜65 km）,流体是溶质含量很低的含卤化物水溶液,可含CO2-3、SO2-4、HS-等组分,其所含Si、Al、Ca、Mg、Fe、Na主量元素溶质相当于海水中固化物量的2~3倍,并具大离子亲石元素（LILE）、轻元素（B、Li）富集和高场强元素（HFSE）亏损的特点。当深度≥65 km时,流体转化为类似于超临界性质的溶液,含CH4、C2H6、H2S等挥发分,其所含主量元素溶质显著增加,微量元素除LILE等外,还负载相当量的HFSE和过渡族成矿元素。俯冲带65~100 km深度,为富水流体向超临界流体转变的区间。这种流体具有“亚超临界”性质,发生了氧化还原性质和元素溶解能力的渐变,并伴随硬柱石和角闪石的最终耗尽。高压变质岩石及相关脉体的O、Sr、Nd和金属同位素示踪研究表明俯冲带流体的源区多样,有蚀变基性洋壳、地幔橄榄岩和沉积物,并保存了海底热液蚀变作用的印迹。流体以脉冲方式沿网络状裂隙呈隧道式运移和传输,规模可达千米级,时间尺度在数月至数百年。目前通过高压—超高压变质岩的研究对俯冲带流体已经有了深入的了解,但展望未来,该领域依然有诸多争议和科学问题值得探索。  相似文献   

Seasonal and interannual variations in satellite derived sea surface temperature of the Baltic Sea in the 1990s     

Herbert Siegel  Monika Gerth  Reiner Tiesel  Gisela Tschersich 《Ocean Dynamics》1999,51(4):407-422

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Multipoint Observations of Solar Type III Radio Bursts from STEREO and Wind     

M. J. Reiner  K. Goetz  J. Fainberg  M. L. Kaiser  M. Maksimovic  B. Cecconi  S. Hoang  S. D. Bale  J.-L. Bougeret 《Solar physics》2009,259(1-2):255-276

The twin STEREO and the Wind spacecraft make remote multipoint measurements of interplanetary radio sources of solar origin from widely separated vantage points. One year after launch, the angular separation between the STEREO spacecraft reached 45°, which was ideal for locating solar type III radio sources in the heliosphere by three-spacecraft triangulation measurements from STEREO and Wind. These triangulated source locations enable intrinsic properties of the radio source, such as its beaming characteristics, to be deduced. We present the first three-point measurements of the beaming characteristics for two solar type III radio bursts that were simultaneously observed by the three spacecraft in December of 2007 and in January of 2008. These analyses suggest that individual type III bursts exhibit a wide beaming pattern that is approximately beamed along the direction tangent to the Parker spiral magnetic field line at the source location.  相似文献   

Solar Origin of the Radio Attributes of a Complex Type III Burst Observed on 11 April 2001     

M. J. Reiner  K.-L. Klein  M. Karlický  K. Jiřička  A. Klassen  M. L. Kaiser  J.-L. Bougeret 《Solar physics》2008,249(2):337-354

We report here on the solar origin of distinctive radiation characteristics observed for a decametric type III solar radio burst that was associated with a major solar flare and CME on 11 April 2001. The associated decimeter (Ond?ejov) and meter (Potsdam) wavelength emissions, as well as the GOES soft X-ray lightcurve, suggest that there were two successive events of energy release and electron acceleration associated with this solar eruption. The Nançay radioheliograph images and additional evidence of plasmoid propagation suggest that the second event of electron acceleration resulted from coronal reconfigurations, likely caused by the erupting CME. These observational analyses provide new insights into the physical origin of the distinguishing characteristics of complex type III-like radio emissions that are typically observed at decameter wavelengths during major solar eruptive events.  相似文献   

GOCE gravitational gradiometry   总被引：16，自引：6，他引：10  

Reiner Rummel  Weiyong Yi  Claudia Stummer 《Journal of Geodesy》2011,85(11):777-790

GOCE is the first gravitational gradiometry satellite mission. Gravitational gradiometry is the measurement of the second derivatives of the gravitational potential. The nine derivatives form a 3 × 3 matrix, which in geodesy is referred to as Marussi tensor. From the basic properties of the gravitational field, it follows that the matrix is symmetric and trace free. The latter property corresponds to Laplace equation, which gives the theoretical foundation of its representation in terms of spherical harmonic or Fourier series. At the same time, it provides the most powerful quality check of the actual measured gradients. GOCE gradiometry is based on the principle of differential accelerometry. As the satellite carries out a rotational motion in space, the accelerometer differences contain angular effects that must be removed. The GOCE gradiometer provides the components V _xx , V _yy , V _zz and V _xz with high precision, while the components V _xy and V _yz are of low precision, all expressed in the gradiometer reference frame. The best performance is achieved inside the measurement band from 5 × 10^–3 to 0.1 Hz. At lower frequencies, the noise increases with 1/f and is superimposed by cyclic distortions, which are modulated from the orbit and attitude motion into the gradient measurements. Global maps with the individual components show typical patterns related to topographic and tectonic features. The maps are separated into those for ascending and those for descending tracks as the components are expressed in the instrument frame. All results are derived from the measurements of the period from November to December 2009. While the components V _xx and V _yy reach a noise level of about \({10\;\rm{\frac{mE}{\sqrt{Hz}}}}\), that of V _zz and V _xz is about \({20\; \rm{\frac{mE}{\sqrt{Hz}}}}\). The cause of the latter’s higher noise is not yet understood. This is also the reason why the deviation from the Laplace condition is at the \({20 \;\rm{\frac{mE}{\sqrt{Hz}}}}\) level instead of the originally planned \({11\;\rm{\frac{mE}{\sqrt{Hz}}}}\). Each additional measurement cycle will improve the accuracy and to a smaller extent also the resolution of the spherical harmonic coefficients derived from the measured gradients.  相似文献   

Nb–Ta fractionation by partial melting at the titanite–rutile transition     

Timm John  Reiner Klemd  Stephan Klemme  Jörg A. Pfänder  J. Elis Hoffmann  Jun Gao 《Contributions to Mineralogy and Petrology》2011,161(1):35-45

During the evolution of the Earth, distinct geochemical reservoirs with different Nb/Ta ratios have developed. Archean granitoids of the tonalite–trondhjemite–granodiorite (TTG) suite, which represent the Earth’s early continental crust, show larger Nb/Ta variations than any other Earth reservoir. This implies that significant Nb–Ta fractionation must have occurred during early crust formation, while the underlying mechanism behind is still unclear. Here, we present a new model on how Nb may be fractionated from Ta during partial melting of subducted oceanic crust. Our data show that Nb/Ta ratios in melts derived from rutile- and titanite-bearing eclogite are largely controlled by the modal relative abundances of rutile and titanite in the source. High modal ratios of titanite over rutile generate melts with very high Nb/Ta (>60), whereas low modal titanite/rutile produces melts with much lower Nb/Ta (≤30). Very low Nb/Ta (<16) occur when all Ti-phases are consumed at very high degrees of melting. As the modal ratio of titanite to rutile is a function of pressure, the Nb/Ta of melts is a function of melting depth. Our new model helps to explain the extreme variation of Nb/Ta observed in many TTGs and thus how Nb and Ta were fractionated during the early evolution of the Earth. Furthermore, the model also indicates that simple one-stage melting models for mafic crust are not sufficient to explain the formation of TTGs.  相似文献   

Weathering of Fruchtschiefer building stones: mineral dissolution or rock disaggregation?     

Cornelius Fischer  Stephan Kaufhold  Wanja Wedekind  Reiner Dohrmann  Volker Karius  Siegfried Siegesmund 《Environmental Earth Sciences》2011,63(7-8):1665-1676

Building stones manufactured from contact metamorphic slates (Fruchtschiefer slate) from Theuma (Sachsen, Germany) were investigated for mineralogical alterations as well as for changes in porosity and surface roughness due to weathering. After weathering periods of several years to decades, the originally dark gray-colored slates show pale spots of several centimeters in size at the surface of building stones. The dark-colored and light-colored sections of the slate show no differences in mineralogy. Surface weathering did not result in newly precipitated minerals. It was also found that the observed differences in color are not caused by variations in sedimentary organic carbon concentration or in sulfide/sulfate concentrations. Obtained results instead indicate that dark surface sections may show a thin cover of recent organic matter (OM), e.g., living OM, soot, dirt, etc. Microscopic investigations suggested that this cover was exfoliated at light-colored surface sections. The observed disaggregation of the upper 2 mm of the building block material results in an increase in porosity. Porosity of black (unweathered) slate is <2 vol.%. Due to weathering, the slate’s pores with diameters >1 μm show a significant increase in frequency compared to the original pore size distribution. Porosity of weathered rock volumes increased to approx. 8 vol.%. Discolored surface sections show a higher surface roughness (root-mean-square roughness, Rq ~ 1 μm) compared to dark-colored slate surfaces (Rq ~ 200 nm), both data are for cleavage planes. Preferentially, the discolored surface sections are located close to the edges of cut stones. This and the alteration in porosity, pore size, and surface roughness indicate that color changes of the slate are largely influenced by rock disaggregation proceeding from the edges into the center rather than by mineral dissolution/precipitation processes.  相似文献