Early diagenetic processes during Mn-carbonate formation: evidence from the isotopic composition of authigenic Ca-rhodochrosites of the Baltic Sea   总被引：1，自引：0，他引：1  

Thomas Neumann  Uwe HeiserMarkus A Leosson  Michael Kersten 《Geochimica et cosmochimica acta》2002,66(5):867-879

The formation of authigenic Ca-rich rhodochrosite (ACR) in sapropelic sediments of the Gotland Basin, Baltic Sea, is governed by deepwater renewal processes whereby saline water from the North Atlantic flushes the brackish anoxic Baltic Deeps. The carbon and oxygen isotopic compositions of these Mn-carbonates suggest that ACR formation takes place just below the sediment surface and that dissolved compounds from the deepwater column, such as water and bicarbonate molecules, were incorporated in ACR during authigenesis. Porewaters near the sediment surface display δ¹⁸O values of −5.4‰ (VSMOW) and are generally depleted in ¹⁸O, compared to the oxygen isotopic composition of water in equilibrium with Mn-carbonate solid solutions (ACR δ¹⁸O values are −4.6‰). This suggests that early burial diagenetic processes significantly modify the initial isotopic composition of water during Mn-carbonate formation. The reduction of sulfate having δ¹⁸O values of +8.4‰ accounts for a permanent enrichment of porewater ¹⁸O and observed δ¹⁸O values at depth equal to −4.6‰. However, this process does not explain the observed disequilibrium in the oxygen isotopic composition between water and ACR close to the sediment surface where Mn-carbonate formation takes place. Based on isotopic mass balance calculations, we suggest that MnO₂ with δ¹⁸O values of +8.9‰ released oxygen enriched in ¹⁸O into the anoxic porewaters close below the sediment surface. This process should occur after oxygenation events during deepwater renewal when MnO₂ accumulates at the surface of anoxic sediments. Manganese carbonates formed in these waters display δ¹⁸O values of ∼1.0‰ heavier than values expected solely from the initial deepwater composition. This quantitatively explains the discrepancy between paleosalinities calculated from ACR δ¹⁸O based on Mn-carbonate/water isotopic equilibrium fractionation and direct observations for the same period. Our results emphasize the important role of microbial MnO₂ reduction during rhodochrosite authigenesis and suggest that Mn(II) activity, rather than alkalinity, is the limiting component for sedimentary Mn-carbonate formation.  相似文献   

Observations of urban and suburban environments with global satellite scatterometer data   总被引：1，自引：0，他引：1  

S.V. Nghiem  D. Balk  E. Rodriguez  G. Neumann  A. Sorichetta  C. Small  C.D. Elvidge 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(4):367-380

A global and consistent characterization of land use and land change in urban and suburban environments is crucial for many fundamental social and natural science studies and applications. Presented here is a dense sampling method (DSM) that uses satellite scatterometer data to delineate urban and intraurban areas at a posting scale of about 1 km. DSM results are analyzed together with information on population and housing censuses, with Landsat Enhanced Thematic Mapper Plus (ETM+) imagery, and with Defense Meteorological Satellite Program (DMSP) night-light data. The analyses include Dallas-Fort Worth and Phoenix in the United States, Bogotá in Colombia, Dhaka in Bangladesh, Guangzhou in China, and Quito in Ecuador. Results show that scatterometer signatures correspond to buildings and infrastructures in urban and suburban environments. City extents detected by scatterometer data are significantly smaller than city light extents, but not all urban areas are detectable by the current SeaWinds scatterometer on the QuikSCAT satellite. Core commercial and industrial areas with high buildings and large factories are identified as high-backscatter centers. Data from DSM backscatter and DMSP nighttime lights have a good correlation with population density. However, the correlation relations from the two satellite datasets are different for different cities indicating that they contain complementary information. Together with night-light and census data, DSM and satellite scatterometer data provide new observations to study global urban and suburban environments and their changes. Furthermore, the capability of DSM to identify hydrological channels on the Greenland ice sheet and ecological biomes in central Africa demonstrates that DSM can be used to observe persistent structures in natural environments at a km scale, providing contemporaneous data to study human impacts beyond urban and suburban areas.  相似文献   

Mobilization of Ti-Nb-Ta during subduction: Evidence from rutile-bearing dehydration segregations and veins hosted in eclogite, Tianshan, NW China   总被引：15，自引：0，他引：15  

Jun Gao  Reiner Klemd 《Geochimica et cosmochimica acta》2007,71(20):4974-4996

Field evidence from the western Tianshan subduction complex in northwestern China indicates that the high field strength elements Ti, Nb, and Ta were mobilized and thereby fractionated from Zr and Hf during the dehydration process that transformed blueschist into eclogite. Both a segregation with a depletion halo, thought to represent initial mobilization during dehydration, and a transport vein, indicative of the long distance transport were investigated. In each case, centimeter-sized rutile grains grew as needle-like crystals in the segregation and as prismatic crystals in the vein. Within the host rock of the segregation, the Ti contents of garnet and omphacite, the modal abundances of rutile and titanite and the bulk rock Ti, Nb, and Ta contents decrease towards the segregation. These observations are consistent with transport of Ti, Nb, and Ta from the host rock into the segregation. Textural and geochemical data for the eclogite-facies vein minerals indicate that Ti-Nb-Ta-rich fluids were transported over long-distances (at minimum meter-scale) during fracture-controlled fluid flow. Complex forming ligands (e.g., Na-Si-Al polymers and F⁻) may have enhanced the solubility of Ti, Nb, and Ta in the fluid. Changes in fluid composition (e.g., X_CO2) may both precipitate rutile and fractionate Ti, Nb, and Ta from LILE and REE.  相似文献   

Comparative assessment of CORINE2000 and GLC2000: Spatial analysis of land cover data for Europe   总被引：3，自引：0，他引：3  

K. Neumann  M. Herold  A. Hartley  C. Schmullius   《International Journal of Applied Earth Observation and Geoinformation》2007,9(4):425-437

Given the current lack of interoperability between global and regional land cover products, efforts are underway to link the new European global land cover map (GLOBCOVER) with the existing global land cover 2000 map (GLC2000) and European CORINE mapping initiative. Since both datasets apply different mapping standards, key for a successful implementation is a thorough understanding of the heterogeneities among both datasets. Thus, this paper provides an assessment of compatibilities and differences between the CORINE2000 and GLC2000 datasets. The comparative assessment considers inconsistencies between the thematic legends (using the UN land cover classification system-LCCS), class specific accuracies, and the spatial resolution and heterogeneity of the datasets. The results are summarized with implications for the development of the new GLOBCOVER datasets.  相似文献   

Bastille Day Event: A Radio Perspective     

Reiner  M.J.  Kaiser  M.L.  Karlický  M.  Jiřička  K.  Bougeret  J.-L. 《Solar physics》2001,204(1-2):121-137

We describe the radio signatures that led up to and concluded the solar eruptive event of 14 July 2000 (Bastille Day Event). These radio signatures provide a means of remotely sensing the associated solar activity and transient phenomena. For many days prior to the Bastille Day Event kilometric Type III radio storm emissions were observed that were presumably associated with the active region NOAA 9077. These storm emissions continued until the X5.7 flare at ∼ 10 UT on 14 July 2000 that characterized the Bastille Day Event, then ceased abruptly. The Bastille Day Event itself produced very intense, complex, long-duration Type III-like radio emissions, which appear to have been associated with electrons generated (accelerated) deep in the solar corona. The coronal mass ejection (CME) associated with the Bastille Day Event generated decametric to kilometric Type II radio emissions as the CME propagated through the solar corona and interplanetary medium. The frequency drift of these Type II radio emissions are related to the dynamics of the propagating CME and indicate that the CME experienced significant deceleration as it propagated from the high corona into the interplanetary medium.  相似文献   

Application of Gibbs Energy Minimization to ModelEarly-Diagenetic Solid-Solution Aqueous-Solution EquilibriaInvolving Authigenic Rhodochrosites in Anoxic BalticSea Sediments     

Dmitrii A. Kulik  Michael Kersten  Uwe Heiser  Thomas Neumann 《Aquatic Geochemistry》2000,6(2):147-199

The natural early-diagenetic environment ``anoxicporewater – authigenic mineral phases' has beencharacterized in sediment of the Gotland Deep,Baltic Sea, by a closed-system model. Occurrence ofcarbonate precipitates as thin almost pure whitelaminae was considered as a natural experiment forlong-term equilibration between these phases andporewater. Plots of distribution coefficientsindicate that metastable equilibrium exists betweenporewater and the authigenic Ca-rich rhodochrositephases below 7 cm depth. A thermodynamic model ofporewater geochemistry at in situ P = 25 barand T = 5 °C was developed using the Gibbsenergy minimization (GEM) approach. The values of isobaric-isothermal potentials of Mn, Ca, Fe, Mg,Sr, Ba, C, and O, calculated from the porewatercomposition, were used in a new ``dual thermodynamic'calculation approach to estimate solid activitycoefficients of the end-members in the non-idealsolid solution (Mn, Ca, Mg, Sr, Ba, Fe)CO₃,i.e., at full major and minor multi-componentcomplexity. The regular Margules interactionparameters for the composing binaries estimated bythis model were _Mn-Ca = 1.9 ± 0.5,_Mn-Mg = 0.6,_Ca-Mg = 3.7,_Mn-Fe = 0.2,_Ca-Fe = 2.8,_Mn-Sr = 9.7,_Ca-Sr = 2.15,_Mn-Ba = 4.0,_Ca-Ba = 1.4,validating the theoretical predictions given byLippmann in his pioneering 1980's paper. Thestrictly thermodynamic equilibrium model is not onlyable to match both the measured porewater andcarbonate solid-solution composition, but also topredict that the porewater pH, pe, alkalinity, anddissolved Mn, Fe, and S concentrations arecontrolled by the authigenic mineral bufferingassemblage mackinawite-greigite-rhodochrosite. Ourmodel is only compatible with the idea of ACRformation with typical composition (X_Mnbetween 70–75%) in the topmost sediment layerwhich, however, needs a major source ofMn_aq ^II. This is provided by reduction ofparticulate Mn oxides precipitated in significantamounts in the water column upon major inflow eventsin the Baltic Sea. The model enables also to set upscenarios of changing environmental conditions, e.g.,to predict the non-linear response of the carbonatesolid-solution composition to changes in Mn loading,alkalinity and salinity of the sediment-watersystem. The results suggest that the major andespecially minor element contents (Sr, Mg, Ba) inauthigenic carbonates can be applied as anenvironmental paleoproxy.  相似文献   

A GPS-Based Online Control and Alarm System     

Simone Kälber  Reiner Jäger  Rainer Schwäble 《GPS Solutions》2000,3(3):19-25

A global positioning system (GPS)-based online control and alarm system (GOCA) for monitoring of three-dimensional movements has been developed at the Karlsruhe University of Technology. The GOCA hardware consists of an array of GPS sensors and communication units to be placed in the monitoring area. The hardware-dependent control software communicates with the GPS sensors and provides the GPS baseline data and covariance information to the GOCA deformation analysis software. The GOCA center, which comprises both the control software and the GOCA software, may be linked – for example, over a long distance – to another personal computer (PC) that serves as a remote control station. GOCA is able to provide the full capabilities of classical deformation analysis online (with stations grouped into stable points and moving object points). Both types of points may be occupied either continuously or over short periods at different times. The object points are determined with respect to the stable points. A network adjustment is performed for each interval of data collection, and the coordinate and covariance information may optionally be transformed into a specific reference system (e. g., the building system). Unstable reference points are to be detected by statistical tests. The estimated object point time series are filtered with respect to gross errors using robust estimation techniques. Online filters are used to smooth the time series data of critical displacements and to predict other deformation functions. The time series data, as well as prediction results, are displayed graphically for each object point. An example concerning the online monitoring of a slag heap in a coal-mining area is included. ? 2000 John Wiley & Sons, Inc.  相似文献   

Program News Bright Prospects for a Significant Improvement of the Earth's Gravity Field Knowledge     

Reiner Rummel 《Marine Geodesy》2000,23(3):219-220

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Evaluation of redox-active iron sites in smectites using middle and near infrared spectroscopy   总被引：1，自引：0，他引：1  

Anke Neumann  Thomas B. Hofstetter 《Geochimica et cosmochimica acta》2011,75(9):2336-2355

Redox processes of structural Fe in clay minerals play an important role in biogeochemical cycles and for the dynamics of contaminant transformation in soils and aquifers. Reactions of Fe(II)/Fe(III) in clay minerals depend on a variety of mineralogical and environmental factors, which make the assessment of Fe redox reactivity challenging. Here, we use middle and near infrared (IR) spectroscopy to identify reactive structural Fe(II) arrangements in four smectites that differ in total Fe content, octahedral cationic composition, location of the negative excess charge, and configuration of octahedral hydroxyl groups. Additionally, we investigated the mineral properties responsible for the reversibility of structural alterations during Fe reduction and re-oxidation. For Wyoming montmorillonite (SWy-2), a smectite of low structural Fe content (2.8 wt%), we identified octahedral AlFe(II)-OH as the only reactive Fe(II) species, while high structural Fe content (>12 wt%) was prerequisite for the formation of multiple Fe(II)-entities (dioctahedral AlFe(II)-OH, MgFe(II)-OH, Fe(II)Fe(II)-OH, and trioctahedral Fe(II)Fe(II)Fe(II)-OH) in iron-rich smectites Ölberg montmorillonite, and ferruginous smectite (SWa-1), as well as in synthetic nontronite. Depending on the overall cationic composition and the location of excess charge, different reactive Fe(II) species formed during Fe reduction in iron-rich smectites, including tetrahedral Fe(II) groups in synthetic nontronite. Trioctahedral Fe(II) domains were found in tetrahedrally charged ferruginous smectite and synthetic nontronite in their reduced state while these Fe(II) entities were absent in Ölberg montmorillonite, which exhibits an octahedral layer charge. Fe(III) reduction in iron-rich smectites was accompanied by intense dehydroxylation and structural rearrangements, which were only partially reversible through re-oxidation. Re-oxidation of Wyoming montmorillonite, in contrast, restored the original mineral structure. Fe(II) oxidation experiments with nitroaromatic compounds as reactive probes were used to link our spectroscopic evidence to the apparent reactivity of structural Fe(II) in a generalized kinetic model, which takes into account the presence of Fe(II) entities of distinctly different reactivity as well as the dynamics of Fe(II) rearrangements.  相似文献   

Erratum     

S. Orr  S. P. Neumann 《Stochastic Hydrology and Hydraulics》1994,8(4):318

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