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While the presence of steroid estrogens in the environment has become a major environmental and health concern, their occurrence in coastal sediments remains poorly characterized. In this study, we measured the levels of three natural (estrone, 17β-estradiol, estriol) and one synthetic (17α-ethinylestradiol) estrogens in 54 coastal sediment samples collected from nine locations off central-southern Chile. Steroid estrogens were found in every sample. Remarkably high levels of 17α-ethinylestradiol were detected, reaching up to 48.14 ng/g dry weight. As a result, the global estrogenic loads were estimated to be high at all sites. Interestingly, they were found to correlate with the size of human populations served by sewage plants. Our study indicates that 17α-ethinylestradiol may accumulate in coastal sediments. The possible impact of this highly potent synthetic estrogen on the biota of the marine ecosystem off central-south Chile and on human health remains an open question.  相似文献   
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Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.  相似文献   
24.
Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ13C values decreased between 0 and 4 m, whereas δ15N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.  相似文献   
25.
The polygenetic Albano maar is the most recent centre of the Colli Albani volcano, located just few kilometres to the south-east of Roma. Presently the maar hosts a 167.5 m deep crater lake, the deepest in Europe. The maar is to be considered quiescent, as phreatic activity is documented throughout the Holocene. This paper illustrates the close relationships between the activity of the maar and the history of settlement in the Roman region as recorded in the geology, archaeology, history and legends of the area. Severe fluctuations of the groundwater table and catastrophic overflows of the Lake Albano from the maar rim had occurred prior to and after the early prehistoric settlements dated in the maar area at the Eneolithic times (ca. III millennium B.C.). Repeated lahars occurred along the northwestern slope of the maar filling in the paleodrainage network and forming a vast plain. Paleohydraulic analyses on fluvial and lahar deposits originated from the Holocene phreatic activity of the Albano maar indicate sediment–water flows in excess of hundreds of cubic metres per second. Absolute age determinations of the paleosoil underlying one of the most recent deposits of the lahar succession at 5800 ± 100 yr B.P. (14C CAL) are in perfect agreement with the age of the overlying Eneolithic age settlements. The last catastrophic overflow is described in the Roman literature as a consequence of the anger of Poseidon against the Romans in 398 B.C. for their war against the Etruscans. In 394 B.C. the Romans decided to prevent the repetition of such events by the excavation through the maar crater wall of a 1.5 km long drain tunnel, which is still operational, keeping the lake 70 m below the lowest point of the maar rim. This tunnel drain may be regarded as the first prevention device for volcanic hazard in history and shows an unprecedented development of the engineering technology under the pressure of hazard perception. The surprising and still largely unknown results of this study are very important to redefine the hazard of the Roman region.  相似文献   
26.
The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.  相似文献   
27.
We examine a model for the expected contributions to the soft X-ray background (SXRB) due to bremsstrahlung and re-combination radiation of gas, enriched with heavy elements, located in groups of galaxies taken from Tully'sCatalog of Nearby Groups of Galaxies. It is shown that the contribution to the SXRB of groups of galaxies can explain up to 20% of the observed flux depending on the chemical composition and ratio of emitting mass to assumed virial mass.  相似文献   
28.
The sea star Asterina stellifera has declined during the last decade and is currently abundant only in the southern limit of its former range. We surveyed this population over 5 years to model individual growth and explore the relationship of changes in local abundance with variation in environmental factors and the reproductive status of individuals. Our results show that A. stellifera is a species with slow growth and a relatively long lifespan. Contrary to expectations for temperate species, growth rates were fairly constant through the year and therefore models including seasonal oscillations were inappropriate. The abundance of this species increased significantly from early spring to early summer, likely due to augmented activity and small‐scale aggregation during the reproductive season that affected our estimates of abundance. No significant recruitment occurred during the 5 years studied. The lack of recruitment during long periods and the slow individual growth rates make A. stellifera particularly vulnerable to local extinction. This study was performed prior to the arrival in the study area of the invasive kelp Undaria pinnatifida and side‐gilled sea slug Pleurobranchaea maculata, species that threaten the community structure where A. stellifera lives. Therefore, the information reported here will be essential to assessing the impacts of these exotic species on this sea star population.  相似文献   
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This study presents an innovative technique of executing soil nails called sectorized post grouting (SPG). The most utilized technique of soil nail grouting is gravity grouting, with the literature reporting advances in pressurized grouting. Although obtaining higher pullout resistance of soil nails, pressurized grouting, mostly done in single-stage grouting, does not compensate for exudation and its use in higher nail lengths is difficult. Thus, a technique has been developed that compensates for exudation, with easier application in lengthier nails. The technique was qualitatively assessed to evaluate its surface roughness and later applied in seven real soil nailing works, where it could be quantitatively assessed. The results show that sectorized post-grouted nails obtained greater pullout resistances than gravity grouted and single-stage grouted nails. Although similar improvement was found in tube-à-manchette (TAM) grouted nails, this method presents lower economic efficiency than sectorized post grouting. The pullout resistance results obtained in this study can be utilized in future soil nailing works executed utilizing SPG.

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