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21.
The classic Lagrange's expansion of the solutionE(e, M) of Kepler's equation in powers of eccentricity is extended to highly eccentric orbits, 0.6627 ... <e<1. The solutionE(e, M) is developed in powers of (e–e*), wheree* is a fixed value of the eccentricity. The coefficients of the expansion are given in terms of the derivatives of the Bessel functionsJ n (ne). The expansion is convergent for values of the eccentricity such that |e–e*|<(e*), where the radius of convergence (e*) is a positive real number, which is calculated numerically.  相似文献   
22.
A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher Corg flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.  相似文献   
23.
The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.  相似文献   
24.
The Yaoundé belt (Cameroon) and the Sergipano belt (NE Brazil) belonged to a major and continuous Neoproterozoic orogen at the northern margin of the ancient Congo-São Francisco craton. The Yaoundé belt comprises schists, quartzites, gneisses and migmatitic gneisses grouped into three domains; the low-grade Mbalmayo Group in south and the medium- to high-grade Yaoundé and Bafia Group in north. The Sergipano belt is divided into six domains, the three southernmost of which are mostly made up of clastic and chemical metasedimentary rocks whereas the others are more diverse with a migmatite–gneiss complex, and two metavolcanicplutonic complexes. In general, the two belts show structural vergence and decrease of metamorphic grade towards the craton; three main deformation phases are recognized in the Sergipano belt in contrast with two described in the Yaoundé belt. The minimum age of Pan-African-Brasiliano collision in the Sergipano belt is constrained at 628 ± 12 Ma on syn-collision granites, whereas in the Yaoundé belt collision took place between 620 and 610 Ma, i.e. the age of granulite facies metamorphism. Sm–Nd isotope geochemistry and U–Pb age dating indicate that most clastic metasedimentary rocks in both belts were derived from sources to the north and, to a lesser degree, from the cratons to the south.  相似文献   
25.
Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m3. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.  相似文献   
26.
Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be3Al2Si6O18) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe2+ doublet (ΔE Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe3+E Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe2+ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   
27.
Summary ?Retrievals of atmospheric aerosol optical thickness are highly dependent on the choice of the class describing the aerosol properties leading to significant errors while using classes available in the literature. High spectral resolution measurements from GOME (Global Ozone Monitoring Experiment) between the ultraviolet and the near infrared can be used for an accurate characterization of the aerosol optical properties. The radiometer MVIRI (METEOSAT Visible and Infrared Imager) on board the geostationary satellite METEOSAT, while being equipped only with broadband VIS channel, ensures an adequate half-hourly monitoring of the atmospheric conditions over a large portion of the Earth. The present algorithm is based on a combination of data from both sensors for the retrieval of the aerosol optical thickness at the reference wavelength of 0.55 μm (AOT). A case of a desert dust outbreak from the African continent over the Atlantic Ocean is examined. AOT values obtained using a priori fixed classes taken from the literature are compared with those retrieved with this algorithm using the GOME-derived classes. Systematic differences of the order of a few tenths on average are found which remain significant also after considering the measurement errors. This represents a novelty introduced by the synergetic use of both sensors. Received March 13, 2002  相似文献   
28.
铅在高岭石表面的解吸动力学   总被引:3,自引:0,他引:3  
经过酸性条件下(pH=3.1)Pb(Ⅱ)高岭石表面解吸动力学的研究,发现解吸反应与吸附反应动力学相似,也是一个二阶段的过程,即初始的快速解吸之后伴随着一个缓慢的释放过程。在快速解吸阶段,7min内解吸量即已达到41%。吸附铅没有完全解吸,有近38%残留在高岭石表面,即解吸和吸附过程不是完全可逆的。解吸过程可以用扩展Elovich方程、Elovich方程、双常数方程和一级扩散方程较好地似合。  相似文献   
29.
30.
The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H3PO4 mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   
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