铅在高岭石表面的解吸动力学   总被引：3，自引：0，他引：3  

魏俊峰  吴大清  彭金莲  刁桂仪 《矿物岩石》2002,22(2):5-8

经过酸性条件下（pH=3.1)Pb(Ⅱ）高岭石表面解吸动力学的研究，发现解吸反应与吸附反应动力学相似，也是一个二阶段的过程，即初始的快速解吸之后伴随着一个缓慢的释放过程。在快速解吸阶段，7min内解吸量即已达到41％。吸附铅没有完全解吸，有近38％残留在高岭石表面，即解吸和吸附过程不是完全可逆的。解吸过程可以用扩展Elovich方程、Elovich方程、双常数方程和一级扩散方程较好地似合。  相似文献   

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif     

Javier Fernández-Suárez  Fernando Corfu  Ricardo Arenas  Alberto Marcos  José R. Martínez Catalán  Florentino García  Jacobo Abati  Francisco J. Fernández 《Contributions to Mineralogy and Petrology》2002,143(2):236-253

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.  相似文献   

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO₄ system     

Ivan L’Heureux  Bjørn Jamtveit 《Geochimica et cosmochimica acta》2002,66(3):417-429

Barite-celestite crystals can be synthesized from aqueous solutions during counter-diffusion in a gel column connecting two reservoirs. It is known that such crystals may exhibit oscillatory zoning, whereby the barium composition in the crystal fluctuates more or less regularly from the core of the crystal to its rim. We present here a simple model of oscillatory zoning in such binary solid solutions A₁A₂ grown from aqueous solutions. The model combines diffusive transport of the relevant ions with an autocatalytic growth process. The latter is formulated as a continuous growth in which the probability of finding a kink site on the growing surface depends on the chemical composition of that surface. Thus, an A₁-rich surface favors the growth of A₁ over A₂, as long as A₁ is present in the vicinity of the surface. Precipitation results in a local depletion of A₁ in the aqueous solution, and the system may switch to a A₂ growth mode, until diffusion replenishes the amount of A₁, and so on. We use a dynamical equation for the molar fraction of component A₁ in the crystal, which results from mass conservation across the rough crystal-solution interface. Linear stability analysis and direct numerical solutions show that the system exhibits oscillatory behavior. Using the barite-celestite system as a framework, the scaling is consistent with the experimental observations. We discuss the variety of zoning patterns and textures numerically obtained as the concentrations of reactants in the reservoirs vary. This model might help in understanding the formation of oscillatory zoning in hydrothermal environments.  相似文献   

山地丘陵地区物探爆破孔钻机及配套机具的研究与开发          下载免费PDF全文

赵大军  孙友宏  侯传彬  薛军 《探矿工程》2002,(4):22-24

为满足我国山地丘陵地区物探爆破孔施工技术的要求，研究适合土层、岩层钻进用的钻机及工具，对钻机的配套设备进行了开发研究。分析了国内山地丘陵地区物探爆破孔施工技术现状，并着重介绍了研制设计内容及生产试验情况。  相似文献   

Multiparametric Traveltime Inversion     

Biloti  Ricardo  Santos  Lúcio T.  Tygel  Martin 《Studia Geophysica et Geodaetica》2002,46(2):177-192

In conventional seismic processing, the classical algorithm of Hubral and Krey is routinely applied to extract an initial macrovelocity model that consists of a stack of homogeneous layers bounded by curved interfaces. Input for the algorithm are identified primary reflections together with normal moveout (NMO) velocities, as derived from a previous velocity analysis conducted on common midpoint (CMP) data. This work presents a modified version of the Hubral and Krey algorithm that is designed to extend the original version in two ways, namely (a) it makes an advantageous use of previously obtained common-reflection-surface (CRS) attributes as its input and (b) it also allows for gradient layer velocities in depth. A new strategy to recover interfaces as optimized cubic splines is also proposed. Some synthetic examples are provided to illustrate and explain the implementation of the method.  相似文献   

P wave amplitudes in a 3-D earth     

Ileana M. Tibuleac  Guust Nolet  Caryl Michaelson  Ivan Koulakov 《Geophysical Journal International》2003,155(1):1-10

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巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件及远景分析   总被引：2，自引：2，他引：2  

李国新  孙泽轩  姚毅锋  黄大友 《铀矿地质》2003,19(3):148-153

本根据野外调查及室内系列编图成果，分析了巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件，认为下白里统巴彦花组是中新生代盆地的找矿目的层位，并存在古河道与潜水层间氧化带两种砂岩型铀矿类型。巴彦毛都、准巴彦塔拉、乌里雅斯太和伊勒门盆地是形成砂岩型铀矿的远景盆地。  相似文献   

关于新疆煤炭工业可持续发展的思考     

黄道成  敬益武 《中国煤田地质》2003,15(6):101-103

阐述了新疆煤炭工业发展中存在的主要问题,分析了新疆煤田地质工作的发展方向及当前工作重点,并对新疆煤炭工业的可持续发展战略提出了政策性建议。  相似文献   

基于GIS技术的矿产资源信息系统   总被引：8，自引：3，他引：8  

蔡洪春  张春明  姜绍飞  陈为公  寇大明 《地质与资源》2003,12(2):111-114

地质资料基本上可以分为空间数据和属性数据两大类.它们是地学数据不可分割的两方面,客观上要求统一进行管理.采用地理信息系统技术,可以彻底解决两种类型数据统一管理问题.结合正在开展的辽宁省矿产资源勘查、开发与利用规划工作,论述了建立基于GIS技术的辽宁矿产资源信息系统实现数据可视化和空间模型分析的思路和实现方法.它为今后矿产资源管理工作实现全面科学化管理提供了现代化手段,也为制定行业发展规划以及进行生产决策提供了支持,进而促进地质找矿和矿产开发的工作部署朝思维可视化及思路多样化的方向发展.  相似文献   

地表剥蚀作用对地应力场反演的影响   总被引：2，自引：4，他引：2  

易达  陈胜宏 《岩土力学》2003,24(2):254-256

岩体自重和剥蚀作用都是形成岩体初始应力场的重要因素。在地应力回归分析中，反演所得岩体重度往往大于实测重度。通过算例说明，地表剥蚀作用因素是导致该结果的主要原因，并分析了由此产生的一些工程应用问题。  相似文献