A new simple approach to evaluate pedogenic clay transformation in a Vertic Calcisol     

Claudio Territo  Philippe Vieillard  Dominique Righi  Sabine Petit  Riccardo Scalenghe 《Journal of Geochemical Exploration》2006,88(1-3):345

The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile.  相似文献   

Coseismic rotation changes from the 2004 Sumatra earthquake: the effects of Earth's compressibility versus earthquake induced topography     

Roberto Sabadini  Riccardo E. M. Riva  Giorgio Dalla Via 《Geophysical Journal International》2007,171(1):231-243

Polar motion is modelled for the large 2004 Sumatra earthquake via dislocation theory for an incompressible elastic earth model, where inertia perturbations are due to earthquake-triggered topography of density–contrast interfaces, and for a compressible model, where inertia perturbation due to compression-dilatation of Earth's material is included; density and elastic parameters are based on a multilayered reference Earth. Both models are based on analytical Green's functions, propagated from the centre to the Earth's surface. Preliminary and updated seismological solutions are considered in elucidating the effects of improving earthquake parameters on polar motion. The large Sumatra thrust earthquake was particularly efficient in driving polar motion since it was responsible for large material displacements occurring orthogonally to the strike of the earthquake and to the Earth's surface, as imaged by GRACE gravity anomalies over the earthquake area. The effects of earthquake-induced topography are four times larger than the effects of Earth's compressibility, for l = 2 geopotential components. For varying compressional Earth properties and seismic solution, modelled polar motion ranges from 8.6 to 9.4 cm in amplitude and between 117° and 130° east longitude in direction. The close relationship between polar motion direction, earthquake longitude and thrust nature of the event, are established in terms of basic physical concepts.  相似文献   

Constraints on the Genesis of Potassium-rich Italian Volcanic Rocks from U/Th Disequilibrium     

Avanzinelli  Riccardo; Elliott  Tim; Tommasini  Simone; Conticelli  Sandro 《Journal of Petrology》2008,49(2):195-223

We present new U-series isotope, ⁸⁷Sr/ ⁸⁶Sr, ¹⁴³Nd/ ¹⁴⁴Nd andtrace element data for a set of mafic, K-rich rocks from volcanoesin Central–Southern Italy. These shoshonitic to ultrapotassiclavas display strongly depleted high field strength element(HSFE) abundances with respect to other incompatible trace elementstogether with high but variable ⁸⁷Sr/ ⁸⁶Sr and low but variable¹⁴³Nd/ ¹⁴⁴Nd values. Such characteristics are thought to bedue to addition of subducted crust of variable amount and compositionto their mantle sources prior to magma genesis. Rocks from thenorthernmost region (i.e. Tuscan Magmatic Province and NorthernRoman Magmatic Province) display (²³⁰Th/ ²³⁸U) activity ratiosclose to radioactive equilibrium, suggesting that metasomatismof their sources occurred before 400 ka and recent melting tookplace at shallow depths, in the absence of garnet. A ²³⁸U excessof up to 27% has been measured in rocks from the NeapolitanDistrict. The occurrence of significant U excesses is a featureof arc magmas, but is typically seen in depleted lavas ratherthan in highly enriched rocks such as these (20 ppm Th). Thissignature requires a recent addition of a U-rich component tothe already strongly enriched mantle wedge beneath this regionof Italy. We suggest that a supercritical liquid, from deeplysubducted carbonate-rich sediments of the still-active Ionianslab, is responsible for generating a high-U, low-Th component,which produces the observed disequilibria. A 30% ²³⁰Th excessmeasured in a single unaltered sample from the Lucanian MagmaticProvince, along with a less marked negative HFSE anomaly, suggeststhe contribution of a deeper, garnet-bearing component in thegenesis of these magmas, plausibly related to the upwellingof asthenospheric mantle around the corner of the Ionian slab. KEY WORDS: U/Th disequilibria; potassic and ultrapotassic rocks; subduction: metasomatism; mantle melting; Central and Southern Italy  相似文献   

Evolution of orthogonal sets of coeval extension joints   总被引：1，自引：0，他引：1  

Riccardo Caputo 《地学学报》1995,7(5):479-490

The formation of two orthogonal sets of extension joints either crossing or abutting each other is a typical product of brittle deformation. Such systems of joints, with the two joint sets being geologically coeval, have been called a fracture grid-lock. The two sets are of common genesis and thus a unique remote stress field can be inferred. This interpretation causes some perplexity if the two joint sets are purely extension fractures and formed perpendicular to the least principal stress. In the present paper a conceptual model to explain the origin and the evolution of such systems is proposed. In a volume of rock undergoing a tensional and uniform remote stress state, caused for example by a tectonic regime, two horizontal and negative (i.e. tensional) stress rates are assumed to exist. When the tensile strength of the rock is locally reached, failure occurs perpendicular to the least principal stress. Then, that direction locally experiences a positive stress drop due to the stress release. For this reason, the stress field, retaining the same principal directions, is locally distorted by a swap between the σ₃ and the σ₂ components in a volume of rock surrounding the fracture. As a consequence of the persisting remote stress rates, when elastic failure conditions are newly accumulated, a second fracture forms and propagates perpendicular to the previous one. Repeated failure events, stress-drops and stress swaps eventually generate a fracture grid-lock. The whole process is also described with a simplified analytical model by applying elasticity theory.  相似文献   

Origin and timing of the post-Variscan gabbro–granite complex of Porto (Western Corsica)     

Maria Rosaria Renna  Riccardo Tribuzio  Massimo Tiepolo 《Contributions to Mineralogy and Petrology》2007,154(5):493-517

The post-Variscan complex of Porto consists of metaluminous to slightly peraluminous A-type biotite granites mingled with gabbro-dioritic rocks, and late dykes with basaltic to trachyandesitic composition. U-Pb zircon dating by LA-ICP-MS on two mafic intrusive samples constrains the time of the gabbro–granite crystallisation at 281 ± 3 Ma and 283 ± 2 Ma. Hornblende ⁴⁰Ar-³⁹Ar ages from a late trachyandesite dyke date the dyking event at 280 ± 2 Ma, which is within error the U-Pb zircon ages of the intrusives. Biotite granites show variable major and trace element compositions and similar initial ε_Nd (−0.3 to +0.9). Whole rock chemistry variations and trace element compositions of plagioclase and allanite indicate that the granites are genetically linked, essentially through fractional crystallisation of feldspars and minor allanite. On the basis of whole-rock chemistry e.g. initial ε_Nd +4.9 to +1.7 and trace element clinopyroxene compositions, we have ascertained that the mafic intrusives and basic dykes formed from isotopically depleted mantle source-derived melts with similar trace element signature. These basic melts experienced slightly different evolutionary histories, controlled by fractional crystallisation and crustal contamination, mainly by the acid magma that gave rise to the associated biotite granites, but also by the enclosing older Variscan granitoids. U-Pb zircon data suggest that the Porto complex was affected by hydrothermal fluid circulation at 259 ± 9 Ma.  相似文献   

The Fate of High-Angle Dipping Slabs in the Subduction Factory: an Integrated Trace Element and Radiogenic Isotope (U, Th, Sr, Nd, Pb) Study of Stromboli Volcano, Aeolian Arc, Italy   总被引：2，自引：0，他引：2  

Tommasini  Simone; Heumann  Arnd; Avanzinelli  Riccardo; Francalanci  Lorella 《Journal of Petrology》2007,48(12):2407-2430

The subaerial part of the Stromboli stratovolcano was builtup in the last 100 kyr through six periods of activity; theerupted magmas record the largest compositional variation ofall the Aeolian arc volcanoes (calc-alkaline, shoshonitic, andpotassic alkaline magma series). The trace element characteristicsof the less evolved magmas of each period of activity are coherentlycorrelated with their radiogenic isotope (Sr, Nd, Pb) composition,and are typical of volcanic arc rocks. In terms of U-seriesisotopes, samples from the different magma series have both²³⁸U and ²³⁰Th excesses, and this distinctive feature providesadditional constraints on source enrichment processes withinthe mantle wedge and on the mechanism of partial melting. Overallthe complete set of data demonstrates that the genesis of thedifferent magma series at Stromboli can be accommodated in amantle source that experienced two distinct enrichment processesby different parts of the subducting oceanic crust of the Ionianslab. The first was caused by supercritical liquids originatingfrom the basaltic and sedimentary parts of the subducting slabat >5 GPa and 900°C. The second was induced by aqueousfluids, again originating from the basaltic and sedimentaryparts of the slab, released from a shallower part of the subductedIonian slab (< 5 GPa and 800°C). U–Th disequilibriaconstrain the timing of the first metasomatic event (Stage I:supercritical liquids) at >435 ka, whereas the second event(Stage II: aqueous fluids) occurred at 100 ka. The high-angledip of the Ionian slab (70°) caused the superimpositionof the metasomatizing agents of the two enrichment processesin the same volume of the mantle wedge, explaining the occurrenceof such different magma series in a single volcanic edifice.The U–Th disequilibria provide evidence for dynamic meltingof the metasomatized mantle wedge combined with an ageing effectresulting from the restoration of secular equilibrium afterthe perturbation caused by the U-rich aqueous fluids of StageII. The trace element and radiogenic isotope (U, Th, Sr, Nd,Pb) signature of the mantle source of the magmas at Stromboliis thus dependent upon the amount of supercritical liquids andaqueous fluids released by the two components of the subductedslab, whereas the distinctive ²³⁸U and ²³⁰Th excesses of themagmas result from a combination of mantle ageing and time-dependentdynamic melting. The geochemical and radiogenic isotope signatureof the mantle source beneath Stromboli places important constraintson the isotopic polarity from Southern Latium to the Aeolianarc attributed to the effect of a HIMU mantle component followingeither lateral inflow of foreland mantle material or upwellingof a mantle plume in the centre of the Tyrrhenian basin. Ourgeochemical model demonstrates that the high ²⁰⁶Pb/²⁰⁴Pb ofthe putative ‘HIMU’ mantle component could be equallyformed during metasomatism of the pre-existing mantle wedgeby either the supercritical liquid (Stage I) or aqueous fluid(Stage II) released by the subducted altered basalt of the Ionianplate. KEY WORDS: radiogenic isotopes; U–Th disequilibria; mantle metasomatism; supercritical liquid; aqueous fluid; Stromboli  相似文献   

Tracking dynamics of magma migration in open-conduit systems     

Sébastien Valade  Giorgio Lacanna  Diego Coppola  Marco Laiolo  Marco Pistolesi  Dario Delle Donne  Riccardo Genco  Emanuele Marchetti  Giacomo Ulivieri  Carmine Allocca  Corrado Cigolini  Takeshi Nishimura  Pasquale Poggi  Maurizio Ripepe 《Bulletin of Volcanology》2016,78(11):78

  相似文献   

Improved Constraints on Models of Glacial Isostatic Adjustment: A Review of the Contribution of Ground-Based Geodetic Observations     

Matt A. King  Zuheir Altamimi  Johannes Boehm  Machiel Bos  Rolf Dach  Pedro Elosegui  François Fund  Manuel Hernández-Pajares  David Lavallee  Paulo Jorge Mendes Cerveira  Nigel Penna  Riccardo E. M. Riva  Peter Steigenberger  Tonie van Dam  Luca Vittuari  Simon Williams  Pascal Willis 《Surveys in Geophysics》2010,31(5):465-507

The provision of accurate models of Glacial Isostatic Adjustment (GIA) is presently a priority need in climate studies, largely due to the potential of the Gravity Recovery and Climate Experiment (GRACE) data to be used to determine accurate and continent-wide assessments of ice mass change and hydrology. However, modelled GIA is uncertain due to insufficient constraints on our knowledge of past glacial changes and to large simplifications in the underlying Earth models. Consequently, we show differences between models that exceed several mm/year in terms of surface displacement for the two major ice sheets: Greenland and Antarctica. Geodetic measurements of surface displacement offer the potential for new constraints to be made on GIA models, especially when they are used to improve structural features of the Earth’s interior as to allow for a more realistic reconstruction of the glaciation history. We present the distribution of presently available campaign and continuous geodetic measurements in Greenland and Antarctica and summarise surface velocities published to date, showing substantial disagreement between techniques and GIA models alike. We review the current state-of-the-art in ground-based geodesy (GPS, VLBI, DORIS, SLR) in determining accurate and precise surface velocities. In particular, we focus on known areas of need in GPS observation level models and the terrestrial reference frame in order to advance geodetic observation precision/accuracy toward 0.1 mm/year and therefore further constrain models of GIA and subsequent present-day ice mass change estimates.  相似文献   

Zircon U–Pb geochronology of lower crust and quartzo-feldspathic clastic sediments from the Balagne ophiolite (Corsica)     

Maria Rosaria Renna  Riccardo Tribuzio  Alessio Sanfilippo  Massimo Tiepolo 《Swiss Journal of Geoscience》2017,110(2):479-501

The Balagne ophiolite from central-northern Corsica represents a continent-near paleogeographic domain of the Jurassic Liguria-Piedmont ophiolitic basin. Pillow and massive basalt lavas are primarily associated with Middle–Upper Jurassic pelagic sediments (mostly radiolarites at their base), continental-derived quartzo-feldspathic clastic sediments and ophiolitic breccias containing clasts of gabbros and basalts. The basalt-sedimentary succession is tectonically associated with a slice composed of an intrusive sequence overlain by basalt lavas. A “plagiogranite” from the intrusive sequence was dated by U–Pb zircon geochronology. Although affected by some uncertainty, mainly reflecting common Pb contamination, the U–Pb zircon data suggest a crystallization age of 159 ± 3 Ma (MSWD = 6.3), which is coeval with the formation of oceanic lower crust in the Schistes Lustrés units from Alpine Corsica. The predominance of quartz grains preserving typical volcanic shape, the prevalence of prismatic zircons and the arkose whole-rock composition indicate that the continental-derived quartzo-feldspathic clastic sediments have a low degree of textural maturity. U–Pb zircon geochronology carried out on two distinct levels of quartzo-feldspathic clastic sediments identified the predominance of zircons with within error U–Pb dates at ~280 Ma; minor components at ~457, ~309 and ~262 Ma were also obtained. The U–Pb date distribution is consistent with a source magmatic material mostly developed during the Variscan orogenic collapse.  相似文献   

Isotope geochemistry (Sr–Nd–Pb) and petrogenesis of leucite-bearing volcanic rocks from “Colli Albani” volcano, Roman Magmatic Province, Central Italy: inferences on volcano evolution and magma genesis     

Elena Boari  Riccardo Avanzinelli  Leone Melluso  Guido Giordano  Massimo Mattei  Arnaldo A. De Benedetti  Vincenzo Morra  Sandro Conticelli 《Bulletin of Volcanology》2009,71(9):977-1005

The “Colli Albani” composite volcano is made up of strongly silica-undersaturated leucite-bearing rocks. Magmas were erupted during three main periods, but a complex plumbing system dominated by regional tectonics channelled magmas into different reservoirs. The most alkali-rich magmas, restricted to the caldera-forming period (pre-caldera), are extremely enriched in incompatible trace elements and display more radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71057–0.71067), with slightly less radiogenic Pb with respect to those of the post-caldera period. Post-caldera volcanic activity was concentrated in three different volcanic environments: external to the caldera, along the caldera edge and within the caldera. The post-caldera magmas produced melilite- to leucitite-bearing, plagioclase-free leucitites. In contrast to the pre-caldera lavas, they are characterised by lower incompatible trace element abundances and less radiogenic Sr (⁸⁷Sr/⁸⁶Sr?=?0.71006–0.71039). Magmas evolved through crystal fractionation plus minor crustal assimilation in a large magma chamber during the pre-caldera period. The multiple caldera collapses dissected and partially obliterated the early magma chamber. During the post-caldera stage, magmas were channelled through several pathways and multiple shallow-level magma reservoirs were established. A lithospheric mantle wedge previously depleted in the basaltic component and subsequently enriched by metasomatic slab-derived component is suggested as the mantle source of Colli Albani parental magmas. Two different parental magmas are recognised for the pre- and post-caldera stages. The differences may be related to the interplay between smaller degrees of melting for the pre-caldera magmas and more carbonate-rich recycled subducted lithologies in the post-caldera magmas.  相似文献