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991.
R. N. Colvile T. W. Choularton J. N. Cape B. J. Bandy K. N. Bower R. A. Burgess T. J. Davies G. J. Dollard M. W. Gallagher K. J. Hargreaves B. M. R. Jones S. A. Penkett R. L. Storeton-West 《Journal of Atmospheric Chemistry》1996,24(3):211-239
Four case studies are described, from a three-site field experiment in October/November 1991 using the Great Dun Fell flow-through reactor hill cap cloud in rural Northern England. Measurements of total odd-nitrogen nitrogen oxides (NO
y
) made on either side of the hill, before and after the air flowed through the cloud, showed that 10 to 50% of the NO
y
, called NO
z
, was neither NO nor NO2. This NO
z
failed to exhibit a diurnal variation and was often higher after passage through cloud than before. No evidence of conversion of NO
z
to NO3
- in cloud was found. A simple box model of gas-phase chemistry in air before it reached the cloud, including scavenging of NO3 and N2O5 by aerosol of surface area proportional to the NO2 mixing ratio, shows that NO3 and N2O5 may build up in the boundary layer by night only if stable stratification insulates the air from emissions of NO. This may explain the lack of evidence for N2O5 forming NO3
- in cloud under well-mixed conditions in 1991, in contrast with observations under stably stratified conditions during previous experiments when evidence of N2O5 was found. Inside the cloud, some variations in the calculated total atmospheric loading of HNO2 and the cloud liquid water content were related to each other. Also, indications of conversion of NO
x
to NO
z
were found. To explain these observations, scavenging of NO
x
and HNO2 by cloud droplets and/or aqueous-phase oxidation of NO2
- by nitrate radicals are considered. When cloud acidity was being produced by aqueous-phase oxidation of NO
x
or SO2, NO3
- which had entered the cloud as aerosol particles was liberated as HNO3 vapour. When no aqueous-phase production of acidity was occurring, the reverse, conversion of scavenged HNO3 to particulate NO3
-, was observed. 相似文献
992.
Oliver Wild Oliver V. Rattigan Roderic L. Jones John A. Pyle R. Anthony Cox 《Journal of Atmospheric Chemistry》1996,25(2):167-199
The Cambridge 2-D Eulerian model has been used to study the potential atmospheric distributions and lifetimes of a number of CFC replacement compounds and their degradation products. The study has focused on HFC 134a and HCFCs 123, 141b and 142b and the major products formed by their atmospheric degradation. The loss of these compounds and their products by hydroxyl radical attack, photolysis and in-cloud hydrolysis have been investigated. The study has shown that HCFCs 141b and 142b have sufficiently long lifetimes to enter the stratosphere in significant quantities, where degradation leads to an increase in the total stratospheric chlorine concentration. The study has also highlighted areas where further experimental work would be valuable, in particular characterisation of the product channels for the degradation reactions and determination of the removal rates of the products in the aqueous phase. 相似文献
993.
Richard W. Katz 《Climatic change》1996,32(3):237-255
994.
995.
996.
997.
Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies 总被引:2,自引:0,他引:2
Ellen E. Moyer David W. Ostendorf Robin J. Richards Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153
Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site. 相似文献
998.
Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse 总被引:2,自引:0,他引:2
K. Michelle Lipe David A. Sabatini Mark A. Hasegawa Jeffrey H. Harwell 《Ground Water Monitoring & Remediation》1996,16(1):85-92
Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation. 相似文献
999.
Gisela Björse Richard H. W. Bradshaw Daniel B. Michelson 《Journal of Paleolimnology》1996,16(1):67-78
A method was developed to construct maps of former forest types based on regional pollen data in southern Sweden. The considered species were Alnus, Betula, Carpinus, Corylus, Fagus, Fraxinus, Juniperus, Picea, Pinus, Populus, Quercus, Salix, Tilia and Ulmus. A network of 37 regional pollen sites with high data quality from lakes and peat deposits were selected from Sweden south of 60 ° N. Pollen percentage values were calculated and converted into estimates of tree composition. For controlling the reliability of the reconstruction, the estimates from the core-tops were compared with present day forest inventory data, and local pollen diagrams were compared with the regional pollen diagrams. An inverse distance weighted interpolation algorithm was used to generate maps for each tree species distribution at 2000 BP, 1500 BP, 1000 BP, 500 BP and 0 BP. A supervised classification routine was implemented to generate nine different forest types common to the five studied time intervals. The maps show that the amounts and patterns of distribution of the species and the forest types have varied in a significant but systematic manner through time. The changes are due to human activities, migrational patterns and changes in climate. These maps will be of value as a basis for future landscape planning, forestry and conservation of biodiversity.This is the 20th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers. 相似文献
1000.