Is the Arctic Surface Layer a Source and Sink of NOx in Winter/Spring?     

B. Ridley  J. Walega  D. Montzka  F. Grahek  E. Atlas  F. Flocke  V. Stroud  J. Deary  A. Gallant  H. Boudries  J. Bottenheim  K. Anlauf  D. Worthy  A. L. Sumner  B. Splawn  P. Shepson 《Journal of Atmospheric Chemistry》2000,36(1):1-22

Measurements of NO_x (NO +NO₂) and the sum of reactive nitrogenconstituents, NO_y, were made near the surface atAlert (82.5°N), Canada during March and April1998. In early March when solar insolation was absentor very low, NO_x mixing ratios were frequentlynear zero. After polar sunrise when the sun was abovethe horizon for much or all of the day a diurnalvariation in NO_x and NO_y was observed withamplitudes as large as 30–40 pptv. The source ofactive nitrogen is attributed to release from the snowsurface by a process that is apparently sensitized bysunlight. If the source from the snowpack is a largescale feature of the Arctic then the diurnal trendsalso require a competing process for removal to thesurface. From the diurnal change in the NO/NO₂ratio, mid-April mixing ratios for the sum of peroxyand halogen oxide radicals of 10 pptv werederived for periods when ozone mixing ratios were inthe normal range of 30–50 ppbv. Mid-day ozoneproduction and loss rates with the active nitrogensource were estimated to be 1–2 ppbv/day and in nearbalance. NO_y mixing ratios which averaged only295±66 pptv do not support a large accumulation inthe high Arctic surface layer in the winter and springof 1998. The small abundance of NO_y relative tothe elevated mixing ratios of other long-livedanthropogenic constituents requires that reactivenitrogen be removed to the surface during transport toor during residence within the high Arctic.  相似文献   

Photochemistry in the Arctic Free Troposphere: Ozone Budget and Its Dependence on Nitrogen Oxides and the Production Rate of Free Radicals     

Craig Stroud  Sasha Madronich  Elliot Atlas  Christopher Cantrell  Alan Fried  Brian Wert  Brian Ridley  Fred Eisele  Lee Mauldin  Richard Shetter  Barry Lefer  Frank Flocke  Andy Weinheimer  Mike Coffey  Brian Heikes  Robert Talbot  Donald Blake 《Journal of Atmospheric Chemistry》2004,47(2):107-138

Local ozone production and loss rates for the arctic free troposphere (58–85° N, 1–6 km, February–May) during the TroposphericOzone Production about the Spring Equinox (TOPSE) campaign were calculated using a constrained photochemical box model. Estimates were made to assess the importance of local photochemical ozone production relative to transport in accounting for the springtime maximum in arctic free tropospheric ozone. Ozone production and loss rates from our diel steady-state box model constrained by median observations were first compared to two point box models, one run to instantaneous steady-state and the other run to diel steady-state. A consistent picture of local ozone photochemistry was derived by all three box models suggesting that differences between the approaches were not critical. Our model-derived ozone production rates increased by a factor of 28 in the 1–3 km layer and a factor of 7 in the 3–6 kmlayer between February and May. The arctic ozone budget required net import of ozone into the arctic free troposphere throughout the campaign; however, the transport term exceeded the photochemical production only in the lower free troposphere (1–3 km) between February and March. Gross ozone production rates were calculated to increase linearly with NO_x mixing ratiosup to 300 pptv in February and for NO_x mixing ratios up to 500 pptv in May. These NO_x limits are an order of magnitude higher thanmedian NO_x levels observed, illustrating the strong dependence ofgross ozone production rates on NO_x mixing ratios for the majority of theobservations. The threshold NO_x mixing ratio needed for netpositive ozone production was also calculated to increase from NO_x 10pptv in February to 25 pptv in May, suggesting that the NO_x levels needed to sustain net ozone production are lower in winter than spring. This lower NO_x threshold explains how wintertime photochemical ozone production can impact the build-up of ozone over winter and early spring. There is also an altitude dependence as the threshold NO_x neededto produce net ozone shifts to higher values at lower altitudes. This partly explains the calculation of net ozone destruction for the 1–3 km layerand net ozone production for the 3–6 km layer throughout the campaign.  相似文献   

Memorial for Howard James Axon (1924–1992)     

Alex Bevan  Norman Ridley  Derek Sears 《Meteoritics & planetary science》1992,27(5):611-612

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The three screen doors: can marine "protected" areas be effective?     

Jameson SC  Tupper MH  Ridley JM 《Marine pollution bulletin》2002,44(11):1177-1183

The great majority of marine protected areas (MPAs) fail to meet their management objectives. So MPAs can be effective conservation tools, we recommend two paradigm shifts, the first related to how they are located and the second related to how they are managed. MPAs are unlikely to be effective if they are located in areas that are subject to numerous, and often uncontrollable, external stressors from atmospheric, terrestrial, and oceanic sources, all of which can degrade the environment and compromise protection. MPA effectiveness is also limited by low institutional and community capacity for management and inappropriate size with respect to ecological needs. In particular, the check list approach to management does not ensure that key threats are dealt with, or that management expenditures provide a quantifiable return. We recommend a business planning approach to MPA management, in which managers focus on the viability of the management system, i.e., the ability of the MPA to provide ecological goods and services to its target users over the long term.  相似文献   

Modeling the surface complexation of calcium at the rutile-water interface to 250°C     

Moira K. Ridley  Michael L. Machesky  Donald A. Palmer 《Geochimica et cosmochimica acta》2004,68(2):239-251

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On the Role of Lightning NOx in the Formation of Tropospheric Ozone Plumes: A Global Model Perspective     

Didier Hauglustaine  Louisa Emmons  Mike Newchurch  Guy Brasseur  Toshinori Takao  Kouji Matsubara  James Johnson  Brian Ridley  Jeff Stith  James Dye 《Journal of Atmospheric Chemistry》2001,38(3):277-294

A series of ozone transects measured each year from 1987 to 1990 over thewestern Pacific and eastern Indian oceans between mid-November andmid-Decembershows a prominent ozone maximum reaching 50–80 ppbv between 5 and 10 kmin the 20° S–40° S latitude band. This maximum contrasts with ozonemixing ratios lower than20 ppbv measured at the same altitudes in equatorial regions. Analyses witha globalchemical transport model suggest that these elevated ozone values are part ofa large-scale tropospheric ozone plume extending from Africa to the western Pacific acrosstheIndian ocean. These plumes occur several months after the peak in biomassburninginfluence and during a period of high lightning activity in the SouthernHemispheretropical belt. The composition and geographical extent of these plumes aresimilar to theozone layers previously encountered during the biomass burning season in thisregion.Our model results suggest that production of nitrogen oxides from lightningstrokes sustains the NO_x (= NO+NO₂) levels and the ozonephotochemical productionrequired in the upper troposphere to form these persistent elevated ozonelayers emanating from biomass burning regions.  相似文献   

Meso-scale surface wind changes associated with the passage of cold fronts along the eastern side of the Southern Alps,New Zealand     

Dr. A. P. Sturman  R. K. Smith  M. A. Page  R. N. Ridley  J. T. Steiner 《Meteorology and Atmospheric Physics》1990,42(2):133-143

Summary The movement of cold fronts along the eastern side of the Southern Alps has been studied in detail during the Southerly Change Experiment (SOUCHEX). An enhanced network of surface wind monitoring stations was established in the Canterbury region of the South Island to allow detailed study of meso-scale wind fields during the passage of fronts. Fivesoutherly changes occurred during the experiment, one of which failed to produce a clear wind change over much of the area. The often erratic movement of these fronts along the eastern side of the mountains is illustrated by isochrone maps of the onset of the wind change. Other general characteristics of these events include their shallowness (1000–1500 m deep) and in most cases their abrupt onset. Detailed analysis of anemograph data collected during SOUCHEX indicates great variability in the surface wind field associated with passage of the fronts. Maps of the meso-scale wind field plotted for the first southerly change of the 14 January 1988 illustrate the complexity of the wind changes experienced over the eastern South Island in particular. The arrival of the cold fronts at individual sites provided features of air mass interaction which appear to relate to time of day, and regional and local site factors. Variations, in wind, temperature and relative humidity provide clear examples of both single and double air mass changes. However, nocturnal changes seem to be less distinct due to lower ambient temperatures and increased boundary layer stability.With 9 Figures  相似文献   

The variability of chemical analyses as a function of sample heterogeneity,and the implications to the analyses of rock standards     

Kevin J.D. Ridley  Andrew Turek 《Geochimica et cosmochimica acta》1976,40(11):1375-1379

The errors in the chemical analyses of a granodiorite rock powder for 6 constituents (K ₂O, Na₂O, CaO,∑Fe₂O₃, MgO, and MnO) have been determined by replicate analyses of the whole rock and of a series of different sieved fractions. Sample inhomogeneity is indicated. This is confirmed by analyses of the fused rock powder. Fusion to a glass is therefore recommended for the preparation of geochemical rock standards.  相似文献   

The crystallisation trends of spinels in tertiary basalts from Rhum and Muck and their petrogenetic significance     

W. Ian Ridley 《Contributions to Mineralogy and Petrology》1977,64(3):243-255

Spinels are commonly observed in alkali olivine basalts and olivine basalts that form the Plateau Magma Series of the British Tertiary Province. The spinels are either partly or wholly enclosed within olivine or may have adhered to olivine surfaces, and have undergone cation exchange and reaction with the cooling basaltic melt. Detailed microprobe traverses indicate complex exchanges involving Fe-Mg, Cr-Al, Fe³⁺-R³⁺ and Fe²⁺ Ti-R³⁺ substitutions. Some of these changes are due to a reaction with liquid that produced plagioclase and resulted in Al depletion in the spinel. A complex series of solid solutions between hercynite-magnesioferrite-chromite and Al-Cr-titomomagnetite, is indicated in a combination that precludes the disappearance of spinel by a simple peritetic reaction with the melt. The initial spinels are compositionally distinct from the chromites found in the Rhum layered series and underline the great compositional variability of liquidus spinels that can crystallise from basaltic liquid. Some of this variability may relate to the changing solubility of Cr, which behaves as a trace element, in basaltic liquids in response to slight changes in the structure of the melt.LDGO Contribution no. 2575  相似文献   

The field relations of the Las Cañadas Volcanoes,Tenerife, Canary islands     

W. I. Ridley 《Bulletin of Volcanology》1971,35(2):318-334

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