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31.
Nearly all studies of site response under seismic excitation employ idealized site models in which uniform layers of homogeneous soils are separated by perfect interfaces. The impedance mismatch at each interface gives rise to wave reflections which strongly affect the calculated free surface response. In reality, these perfect interfaces may often not exist. Instead, a zone in which materials from both above and below are mingled may form a blurred interface between layers. This article examines the effects of such weathered zones. The zone is modelled by a linearly varying shear modulus so that no abrupt impedance change occurs. Significant differences in response of weathered and unweathered profiles are found.  相似文献   
32.
A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO4, and NO3. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H4SiO4, HCO3, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.  相似文献   
33.
The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (13C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. 13C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CHxO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (fa), O/C and relative proportions of various carbon types estimated by 13C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献   
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35.
ABSTRACT

This study experiments with reservoir representation schemes to improve the ability to model active water management in the National Water Model (NWM). For this purpose, we developed an integrated water management model, NWM-ResSim, by coupling the NWM with HEC-ResSim, and two reservoir representation schemes are tested: simulation of reservoir operations and retrieval of scheduled operations. The experiments focus on a pilot reservoir domain in the Russian River basin – Lake Mendocino, California – and its contributing watershed. The evaluation results suggest that the NWM-ResSim improves the simulation performance of reservoir outflow from this managed reservoir over the NWM default level pool routing scheme. The degree of this improvement depends on the suitability of the operation guidance; the reservoir operations simulation scheme could have acceptable errors for the purposes of water resources management, but not for flood operations. Results of the retrieval scheme of scheduled operations demonstrated better performance for sub-daily flood operations.  相似文献   
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Advancing vulnerability science depends in part on identifying common themes from multiple, independent vulnerability assessments. Such insights are difficult to produce when the assessments use dissimilar, often qualitative, measures. The Vulnerability Scoping Diagram is presented to facilitate the comparison of assessments with dissimilar measures. The diagram is illustrated with recent research on drought vulnerabilities, showing that common insights into vulnerability may emerge if independent research teams use a common structure for organizing information about exposure, sensitivity and adaptive capacity—even if the underlying measures differ between assessments. Broadly adopting this technique, which is grounded in the “Eight Steps” methodological protocol [Schröter, D., Polsky, C., Patt, A., 2005. Assessing vulnerabilities to the effects of global change: an eight step approach. Mitigation and Adaptation Strategies for Global Change 10(4), 573–595], will enable a vulnerability meta-analysis, the lessons from which may permit places to identify helpful adaptation or mitigation options without first having to conduct their own vulnerability assessments.  相似文献   
38.
The Myggbukta caldera complex and a swarm of basic dykes constitute the latest Tertiary magmatism in the Hold with Hope region, East Greenland. The Sr and Nd isotope ratios of these rocks show coherent variations which extend to high 87Sr/86Sr and low 143Nd/144Nd values and require a contribution from continental lithosphere. Broad correlations with major element differentiation indices suggest that the continental component was incorporated during magmatic differentiation thereby favouring a crustal contamination process. Trace element concentrations are strongly correlated with isotopic compositions but display ranges for many incompatible elements which extend beyond likely crustal contaminant compositions. This is readily modelled by AFC processes in which the dominant cause of trace element enrichment is the concentration effect of fractional crystallisation rather than the composition of the contaminant. The simplest such models still require unrealistically high degrees of fractional crystallisation to explain the ten-fold enrichment of some trace elements. This can be overcome if the primary magmas entering the crust already had highly variable trace element compositions. Such variability is readily achieved if melts from different parts of the melting column escape without thorough homogenization. An AFC model which incorporates variability in parental magma composition is then able to simulate the range of compositions observed at Hold with Hope. This carries the implication that the variations observed are more readily attributed to changes in uncontaminated parental magma than to variations in the composition or amount of contaminant. Received: 5 March 1998 / Accepted: 16 June 1998  相似文献   
39.
Melanoidins, acidic polymeric products of amino acid/sugar condensation reactions, are shown to be capable of reacting with and binding functionalized lipid molecules. Pyrolysis gas chromatography is used to monitor the inclusion of lipids (alcohols and acids) into, and to monitor the changes in composition caused by artificial diagenesis of, the melanoidins. Artificial diagenesis of the lipidcontaining melanoidins produces a material resembling kerogen. The possible role of melanoidins in the formation of kerogens is discussed as are internal transformations within kerogens during diagenesis.  相似文献   
40.
Pleistocene sediments and soils exposed at Stebbing in central Essex, England are described, analysed and interpreted. The sand and gravel units above Eocene London Clay and Upper Pliocene Red Crag are shown to be a high level member of the Kesgrave Formation, with a surface immediately beneath that of the Westland Green Gravels, which are tentatively assigned to the Pre-Pastonian ‘a’ Stage of the British Quaternary succession. The rubified, argillic soil developed in the surface of these fluvial deposits is a composite of the Valley Farm and Barham Soils and displays micromorphological evidence of several phases of clay illuviation, gleying and clay coating disruption. Originally truncated and buried beneath Anglian gelifluction deposits, cover sand and till, the soil has been exhumed in most places by subsequent erosion. The full succession, however, is preserved within large gulls that formed by periglacial cambering prior to this erosion. More recent loess incorporation and pedogenesis have modified the exhumed soil and the materials within the gulls.  相似文献   
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