Annual and spatial variations of chemical and physical properties in the Ross Sea surface waters (Antarctica)     

Serena Massolo  Roberta Messa  Paola Rivaro  Riccardo Leardi 《Continental Shelf Research》2009

Temperature, salinity, meltwater percentage, water column stability, dissolved oxygen and nutrients were measured in seawater samples collected at three fixed depths (0, 20, 100 m) in 104 stations located in three different areas of the Ross Sea (Antarctica), during four Italian Antarctic surveys carried out between 1998 and 2006. Nutrient data were used to quantify the nutrient removal, which appears particularly high in 2006, especially in polynya area. The N:P and Si:N disappearance ratios were studied to estimate the dominant phytoplanktonic community. No significant differences in the nutrient drawdown ratio were observed, in fact the N:P ratio was always below the Redfield standard ratio.  相似文献   

Tracking the lithium isotopic evolution of the mantle using carbonatites     

Ralf Halama  William F. McDonough  Roberta L. Rudnick  Keith Bell 《Earth and Planetary Science Letters》2008,265(3-4):726-742

Carbonatites are mantle-derived, intraplate magmas that provide a means of documenting isotopic variations of the Earth's mantle through time. To investigate the secular Li isotopic evolution of the mantle and to test whether Li isotopes document systematic recycling of material processed at or near the Earth's surface into the mantle, we analyzed the Li isotopic compositions of carbonatites and spatially associated mafic silicate rocks. The Li isotopic compositions of Archean (2.7 Ga) to Recent carbonatites (δ⁷Li = 4.1 ± 1.3 (n = 23, 1σ)) overlap the range typical for modern mantle-derived rocks, and do not change with time, despite ongoing crustal recycling. Thus, the average Li isotopic composition of recycled crustal components has not deviated greatly from the mantle value (~ + 4) and/or Li diffusion is sufficiently fast to attenuate significant heterogeneities over timescales of 10⁸ years. Modeling of Li diffusion at mantle temperatures suggests that limited δ⁷Li variation in the mantle through time reflects the more effective homogenization of Li in the mantle compared to radiogenic isotope systems. The real (but limited) variations in δ⁷Li that exist in modern mantle-derived magmas as well as carbonatites studied here may reflect isotopic fractionation associated with shallow-level processes, such as crustal assimilation and diffusive isotopic fractionation in magmatic systems, with some of the scatter possibly related to low-temperature alteration.  相似文献   

(137)Cs baseline levels in the Mediterranean and Black Sea: a cross-basin survey of the CIESM Mediterranean Mussel Watch programme     

Thébault H  Rodriguez Y Baena AM  Andral B  Barisic D  Albaladejo JB  Bologa AS  Boudjenoun R  Delfanti R  Egorov VN  El Khoukhi T  Florou H  Kniewald G  Noureddine A  Patrascu V  Pham MK  Scarpato A  Stokozov NA  Topcuoglu S  Warnau M 《Marine pollution bulletin》2008,57(6-12):801-806

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify (137)Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured (137)Cs levels were found to be very low (usually < 1 Bq kg(-1) wet wt) (137)Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.  相似文献   

Seismic performance assessment of “hybrid” structures using two-level multy group GIS oriented approach: case studies     

Roberta Apostolska  Golubka Necevska-Cvetanovska  Veronika Shendova  Julijana Bojadjieva 《Bulletin of Earthquake Engineering》2018,16(10):4797-4824

In this paper, a two-level multi-group approach to seismic performance assessment of existing building stock is presented and discussed. The first level of assessment is a simple visual screening based on the principles originally developed in FEMA (Rapid visual screening of buildings for potential seismic hazards: a handbook—FEMA 154 and 155, Applied Technology Council, Redwood City, 2002). The second level of assessment is based on an integrated approach (field survey, geotechnical investigations, experimental testing and analytical investigations) with incorporated procedures of different levels of complexity. The acceptance criteria for assessment are founded on demand versus capacity relationships, defined at element and story level. The developed approach was applied in performance assessment of the existing buildings in Karposh, which is one of the largest and oldest municipalities in Skopje, the capital of the Republic of Macedonia. Rapid visual screening (level_1 activity) was performed for 161 existing buildings. For two selected buildings, level_2 assessment was carried out. The results from the assessment were uploaded into the existing geo-referenced building inventory database on the Karposh municipality that represents a practical tool for the decision makers in enforcing decisions on design and construction of seismically resilient building environment.  相似文献   

Quantitative in situ XRD measurement of shock metamorphism in Martian meteorites using lattice strain and strain‐related mosaicity in olivine     

Laura E. Jenkins  Roberta L. Flemming  Phil J. A. McCausland 《Meteoritics & planetary science》2019,54(4):902-918

All Martian meteorites have experienced shock metamorphism to some degree. We quantitatively determined shock‐related strain in olivine crystals to measure shock level and peak shock pressure experienced by five Martian meteorites. Two independent methods employing nondestructive in situ micro X‐ray diffraction (μXRD) are applied, i.e., (1) the lattice strain method, in which the lattice strain value (ε) for each olivine grain is derived from a Williamson–Hall plot using its diffraction pattern (peak width variation with diffraction angle) with reference to a best fit calibration curve of ε values obtained from experimentally shocked olivine grains; (2) the strain‐related mosaicity method, allowing shock stage to be estimated by measuring the streaking along the Debye rings of olivine grain diffraction spots to define their strain‐related mosaic spread, which can then be compared with olivine mosaicity in ordinary chondrites of known shock stage. In this study, both the calculated peak shock pressures and the estimated shock stages for Dar al Gani 476 (45.6 ± 0.6 GPa), Sayh al Uhaymir 005/8 (46.1 ± 2.2 GPa), and Nakhla (18.0 ± 0.6 GPa) compare well with literature values. Formal shock assessments for North West Africa 1068/1110 (53.9 ± 2.1 GPa) and North West Africa 6234 (44.6 ± 3.1 GPa) have not been reported within the literature; however, their calculated peak shock pressures fall within the range of peak shock pressures defining their estimated shock stages. The availability of nondestructive and quantitative μXRD methods to determine shock stage and peak shock pressure from olivine crystals provides a key tool for shock metamorphism analysis.  相似文献   

Rockfall trajectory modeling combined with heuristic analysis for assessing the rockfall hazard along the Maratea SS18 coastal road (Basilicata,Southern Italy)   总被引：2，自引：1，他引：1  

Roberta Pellicani  Giuseppe Spilotro  Cees J. Van Westen 《Landslides》2016,13(5):985-1003

In this paper, a study aimed to assess the rockfall hazard along a portion of the SS18 coastal road, located in the coastal area of Maratea (Basilicata Region, Southern Italy), is presented. The relevance of this study derives from the location of the study area, because the SS18 is a strategic roads in a touristic area, and, since the hazard assessment was performed in 2004 within a project financed by the Viability Regional Department of Autonomous National Company of Roads (ANAS), from the possibility to validate the results by using real rockfall events occurred after 2004. The procedure for assessing the rockfall hazard was composed of four sequential analyses: (i) geomechanical and kinematic characterization of rock mass, (ii) implementation of Romana’s (1985) Slope Mass Rating (SMR) method for identifying the potential boulder release areas (rockfall initiation areas), (iii) determination of rockfall trajectories by using a 3D numerical model (ROTOMAP), (iv) calculation and mapping of the hazard index by combining three factors, i.e., (a) lithological features of outcropping materials on rock faces, (b) kinematic compatibility defined by simulating the rockfall trajectories, and (c) spatial distribution of occurred rockfall events. Finally, the proposed methodology was validated by combining the distribution of the hazard levels along the road with the location on the SS18 of the rockfall events occurred from 2004 to 2014.  相似文献   

A method to reveal climatic variables triggering slope failures at high elevation     

Roberta Paranunzio  Francesco Laio  Guido Nigrelli  Marta Chiarle 《Natural Hazards》2015,76(2):1039-1061

  相似文献   

Middle to Late Pleistocene palaeoenvironmental evolution of the southeastern Alpine Valeriano Creek succession (northeastern Italy)     

Giovanni Monegato  Sally E. Lowick  Cesare Ravazzi  Roberta Banino  Marta Donegana  Frank Preusser 《第四纪科学杂志》2010,25(5):617-632

The Middle–Late Pleistocene alluvial and lacustrine succession of Valeriano Creek (southeastern Alpine foothills, 190 m a.s.l.) documents the environmental evolution of the piedmont plain before the onset of the Last Glacial Maximum (LGM). The sedimentary record was investigated by multidisciplinary stratigraphical and sedimentological studies coupled with petrographic and palaeobotanical analysis. A chronology has been provided by luminescence, radiocarbon dating and pollen biochronology. The succession developed at the valley mouth of a small catchment and is confined in the piedmont plain by the alluvial fans of major rivers. The oldest deposits were formed during a cold phase during the late Middle Pleistocene. This part of the piedmont plain was generally stable until Termination II, when it was trenched more than 15 m deep by watercourses. The infilling succession of the trench, mostly by low‐energy alluvial sediments interbedded with mire and peat deposits, documents, for the first time on the southern side of the Alps, the relationships between fluvial activity, vegetation and climate change at the foothills piedmont plain during late Marine Isotope Stage (MIS) 5. The stadial–interstadial climate forcing implies a local reorganisation of fluvial dynamics and of forest composition, although substantial plant cover persisted even during cooler stadials. In accordance with coeval alluvial and speleothem records from the northern side of the Alps, this environmental evolution supports a very restricted Alpine glaciation of the main fluvial catchments of the southeastern Alps during MIS 5a–d. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Users’ perception analysis for sustainable beach management in Italy     

Valentina Marin  Francesca Palmisani  Roberta Ivaldi  Rosanna Dursi  Mauro Fabiano 《Ocean & Coastal Management》2009,52(5):268-277

It is generally accepted that end-users’ perception is likely to play a pivotal role for planning and policy consideration. Beach user analysis is thus an important component defining beach management policies. In the framework of a wider project on beaches management, an investigation on residents and tourists was conducted. A survey conducted through questionnaires and interviews was carried out in six coastal municipalities. Results allowed obtaining a clear picture about user profile, perception of the beaches, awareness and attitude about themes related to beach management (i.e. Blue Flag award and beach nourishment practices). Their integration with the “expert knowledge” based analysis allowed to support the definition of beach management interventions.  相似文献   

High-<Emphasis Type="Italic">T</Emphasis> behaviour of gedrite: thermoelasticity,cation ordering and dehydrogenation     

Michele Zema  Mark D. Welch  Roberta Oberti 《Contributions to Mineralogy and Petrology》2012,163(5):923-937

The thermoelastic behaviour of a natural gedrite having the crystal-chemical formula ^ANa_0.47 ^B(Na_0.03 Mg_1.05 Fe_0.86²⁺ Mn_0.02 Ca_0.04) ^C(Mg_3.44 Fe_0.36²⁺ Al_1.15 Ti_0.05⁴⁺) ^T(Si_6.31 Al_1.69)O₂₂ ^W(OH)₂ has been studied by single-crystal X-ray diffraction to 973 K (Stage 1). After data collection at 973 K, the crystal was heated to 1,173 K to induce dehydrogenation, which was registered by significant changes in unit-cell parameters, M1–O3 and M3–O3 bond lengths and refined site-scattering values of M1 and M4 sites. These changes and the crystal-chemical formula calculated from structure refinement show that all Fe²⁺ originally at M4 migrates into the ribbon of octahedrally coordinated sites, where most of it oxidises to Fe³⁺, and there is a corresponding exchange of Mg from the ribbon into M4. The resulting composition is that of an oxo-gedrite with an inferred crystal-chemical formula ^ANa_0.47 ^B(Na_0.03 Mg_1.93 Ca_0.04) ^C(Mg_2.56 Mn_0.02²⁺ Fe_0.10²⁺ Fe_1.22³⁺ Al_1.15 Ti_0.05⁴⁺) ^T(Si_6.31 Al_1.69) O₂₂ ^W[O_1.12²⁻ (OH)_0.88]. This marked redistribution of Mg and Fe is interpreted as being driven by rapid dehydrogenation at the H3A and H3B sites, such that all available Fe in the structure orders at M1 and M3 sites and is oxidised to Fe³⁺. Thermoelastic data are reported for gedrite and oxo-gedrite; the latter was measured during cooling from 1,173 to 298 K (Stage 2) and checked after further heating to 1,273 K (Stage 3). The thermoelastic properties of gedrite and oxo-gedrite are compared with each other and those of anthophyllite.  相似文献