Sediment chemical contamination of a shallow water area close to the industrial zone of Porto Marghera (Venice Lagoon, Italy)   总被引：1，自引：0，他引：1  

Zonta R  Botter M  Cassin D  Pini R  Scattolin M  Zaggia L 《Marine pollution bulletin》2007,55(10-12):529-542

The industrial zone of Porto Marghera is one the most important "contaminated sites of national interest" (SIN) in Italy, being identified as an area of high environmental risk. The site includes a wide shallow water area of the Venice Lagoon extending toward the city of Venice, which was investigated in order to acquire information on the pollutant level and distribution. Grain-size, heavy metal, nutrient, and organic micropollutant concentrations were determined in the surface sediment layers (0-5 and 5-10 cm depths) of 51 sites. A generally low contamination was found, except for Hg concentration, which increases the toxicological risk in most of the sites of the area, according to the results of a comparison with Sediment Quality Guidelines. A heavy pollution fingerprint (Cd, Cu, Hg, Pb, and Zn up to 15.2, 257, 11.9, 248, and 3010 mg/kg d.w., respectively) was instead found near the Tresse Island, which is ascribed to the spill of pollutants from the contaminated sediment disposed therein. Grain-size and heavy metal profiles down to a depth of 40 cm in eight selected sites, finally show a probable decrease of the pollution affecting the area in recent years.  相似文献   

Scintillometer Intercomparison Study—Continued   总被引：3，自引：3，他引：0  

J. Kleissl  C. J. Watts  J. C. Rodriguez  S. Naif  E. R. Vivoni 《Boundary-Layer Meteorology》2009,130(3):437-443

An earlier study by one of the authors reported significant differences of up to 21% in linear regression slopes between six Kipp & Zonen large-aperture scintillometers. In this note, the consistency of this increasingly popular instrument for measuring sensible heat fluxes at the km scale was quantified by comparing measurements from four Scintec boundary-layer scintillometers and one large-aperture scintillometer over nearly identical transects. The Kipp & Zonen instrument’s sensible heat fluxes were more than 20% larger than those from the Scintec instruments, while the difference in regression slopes amongst the Scintec instruments was 3% or less.  相似文献   

Response on the Comment on “Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol,and 3-methyl-2-buten-1-ol as a function of temperature” by Rodriguez et al. (J. Atmos. Chem. (2008) 59:187–197)     

Diana Rodriguez  Ana Rodriguez  Amparo Soto  Alfonso Aranda  Yolanda Diaz-de-Mera  Alberto Notario 《Journal of Atmospheric Chemistry》2009,63(1):95-95

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Search for sulfates on the surface of Ceres          下载免费PDF全文

C. Bu  G. Rodriguez Lopez  C. A. Dukes  O. Ruesch  L. A. McFadden  J.‐Y. Li 《Meteoritics & planetary science》2018,53(9):1946-1960

The formation of hydrated salts is an expected consequence of aqueous alteration of Main Belt objects, particularly for large, volatile‐rich protoplanets like Ceres. Sulfates, present on water‐bearing planetary bodies (e.g., Earth, Mars, and carbonaceous chondrite parent bodies) across the inner solar system, may contribute to Ceres’ UV and IR spectral signature along with phyllosilicates and carbonates. We investigate the presence and stability of hydrated sulfates under Ceres’ cryogenic, low‐pressure environment and the consequent spectral effects, using UV–Vis–IR reflectance spectroscopy. H₂O loss begins instantaneously with vacuum exposure, measured by the attenuation of spectral water absorption bands, and a phase transition from crystalline to amorphous is observed for MgSO₄·6H₂O by X‐ray powder diffraction. Long‐term (>40 h), continuous exposure of MgSO₄·nH₂O (n = 0, 6, 7) to low pressure (10^?3–10^?6 Torr) causes material decomposition and strong UV absorption below 0.5 μm. Our measurements suggest that MgSO₄·6H₂O grains (45–83 μm) dehydrate to 2% of the original 1.9 μm water band area over ~0.3 Ma at 200 K on Ceres and after ~42 Ma for 147 K. These rates, inferred from an Avrami dehydration model, preclude MgSO₄·6H₂O as a component of Ceres’ surface, although anhydrous and minimally hydrated sulfates may be present. A comparison between Ceres emissivity spectra and laboratory reflectance measurements over the infrared range (5–17 μm) suggests sulfates cannot be excluded from Ceres’ mineralogy.  相似文献   

Analysis of the regional pattern of sea level change due to ocean dynamics and density change for 1993–2099 in observations and CMIP5 AOGCMs     

Roberto A. F. Bilbao  Jonathan M. Gregory  Nathaelle Bouttes 《Climate Dynamics》2015,45(9-10):2647-2666

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Provenance record of late Maastrichtian–late Palaeocene Andean Mountain building in the Amazonian retroarc foreland basin (Madre de Dios basin,Peru)          下载免费PDF全文

Mélanie Louterbach  Martin Roddaz  Pierre‐Olivier Antoine  Laurent Marivaux  Sylvain Adnet  Julien Bailleul  Elton Dantas  Roberto Ventura Santos  Farid Chemale Jr  Patrice Baby  Caroline Sanchez  Ysabel Calderon 《地学学报》2018,30(1):17-23

Biostratigraphic, sedimentological and provenance analyses suggest that a proto‐Andean Cordillera already existed in southern Peru by late Maastrichtian–late Palaeocene times. A 270‐m‐thick stratigraphic section shows changes in depositional environments from shallow marine (early Maastrichtian) to non‐marine (late Maastrichtian) then back to estuarine (late Palaeocene) conditions. An erosional surface separates lower Maastrichtian from upper Maastrichtian deposits. Above this surface, the late Maastrichtian unit exhibits moderately developed palaeosols and syn‐sedimentary normal faults. The sedimentary evolution is accompanied by a decrease in sedimentation rate and by changes in provenance. Shallow marine lower Maastrichtian deposits have a cratonic provenance as shown by their low εNd(0) values (?15 to ?16) and the presence of Precambrian inherited zircon grains. The upper Maastrichtian deposits have a mixed Andean and cratonic origin with εNd(0) values of ~12.6 and yield the first Cretaceous and Permo‐Triassic zircon grains. Estuarine to shallow marine upper Palaeocene deposits have an Andean dominant source as attested by higher εNd(0) values (?6 to ?10) and by the presence of Palaeozoic and Late Cretaceous zircon grains. The changes in depositional environments and sedimentation rates, as well as the shift in detrital provenance, are consistent with a late Maastrichtian–late Palaeocene period of Andean mountain building. In agreement with recently published studies, our data suggest that an Andean retroarc foreland basin was active by late Maastrichtian–late Palaeocene times.  相似文献   

Effective run‐off flow length over biological soil crusts on silty loam soils in drylands          下载免费PDF全文

Roberto Lázaro  Adolfo Calvo‐Cases  Amparo Lázaro  Isabel Molina 《水文研究》2015,29(11):2534-2544

Surface hydrological behaviour is important in drylands because it affects the distribution of soil moisture and vegetation and the hydrological functioning of slopes and catchments. Microplot scale run‐off can be relatively easily measured, i.e. by rainfall simulations. However, slope or catchment run‐off cannot be deduced from microplots, requiring long‐time monitoring, because run‐off coefficients decrease with increasing drainage area. Therefore, to determine the slope length covered by run‐off (run‐off length) is crucial to connect scales. Biological soil crusts (BSCs) are good model systems, and their hydrology at slope scale is insufficiently known. This study provides run‐off lengths from BSCs, by field factorial experiments using rainfall simulation, including two BSC types, three rain types, three antecedent soil moistures and four plot lengths. Data were analysed by generalized linear modelling, including vascular plant cover as covariates. Results were the following: (i) the real contributing area is almost always much smaller than the topographical contributing area; (ii) the BSC type is key to controlling run‐off; run‐off length reached 3 m on cyanobacterial crust, but hardly over 1 m on lichen crust; this pattern remained through rain type or soil moisture; (iii) run‐off decreased with BSC development because soil sealing disappears; porosity, biomass and roughness increase and some changes occur in the uppermost soil layer; and (iv) run‐off flow increased with both rain type and soil moisture but run‐off coefficient only with soil moisture (as larger rains increased both run‐off and infiltration); vascular plant cover had a slight effect on run‐off because it was low and random. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Seismic microzoning of Arica and Iquique,Chile     

Alix Becerra  Luis Podestá  Roberto Monetta  Esteban Sáez  Felipe Leyton  Gonzalo Yañez 《Natural Hazards》2015,79(1):567-586

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Drivers of change in Brazil’s carbon dioxide emissions     

Manfred Lenzen  Roberto Schaeffer  Jonas Karstensen  Glen P. Peters 《Climatic change》2013,121(4):815-824

Brazil’s economic development has been underpinned by a diverse and – in a global comparison – unusual set of energy carriers, notably hydroelectricity and ethanol from sugar cane. Its energy mix makes Brazil one of the least energy-related carbon-intensive economies worldwide. Given that the country is fast becoming one of the world’s economic powerhouses, decision-makers need to understand the drivers underlying past and current carbon dioxide emissions trends. We therefore investigate a) which key long-term drivers have led to Brazil’s unique emissions profile, and b) the implications of these drivers for Brazil’s national policies. We show that Brazil’s emissions are growing mainly due to increasing individual standards of living, exports and population size, and that this growth is so far unchallenged by technological and structural improvements toward lower emissions intensities and more efficient production structures. As these trends are likely to continue amidst growing international pressure on key economies to reduce their carbon emissions, a decoupling of drivers from emissions is needed to simultaneously meet development and environmental goals.  相似文献   

Experiments using new initial soil moisture conditions and soil map in the Eta model over La Plata Basin     

Moira E. Doyle  Javier Tomasella  Daniel A. Rodriguez  Sin Chan Chou 《Meteorology and Atmospheric Physics》2013,121(3-4):119-136

An effort towards a more accurate representation of soil moisture and its impact on the modeling of weather systems is presented. Sensitivity tests of precipitation to soil type and soil moisture changes are carried out using the atmospheric Eta model for the numerical simulation of the development of a mesoscale convective system over northern Argentina. Modified initial soil moisture conditions were obtained from a hydrological balance model developed and running operationally at INPE. A new soil map was elaborated using the available soil profile information from Brazil, Paraguay, Uruguay, and Argentina and depicts 18 different soil types. Results indicate that more accurate initial soil moisture conditions and incorporating a new soil map with hydraulic parameters, more representative of South American soils, improve daily total precipitation forecasts both in quantitative and spatial representations.  相似文献