Regional climate modelling in CLARIS-LPB: a concerted approach towards twentyfirst century projections of regional temperature and precipitation over South America     

E. Sánchez  S. Solman  A. R. C. Remedio  H. Berbery  P. Samuelsson  R. P. Da Rocha  C. Mourão  L. Li  J. Marengo  M. de Castro  D. Jacob 《Climate Dynamics》2015,45(7-8):2193-2212

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The scope for generating bio-oils with relatively low oxygen contents via hydropyrolysis   总被引：3，自引：0，他引：3  

J. Dilcio Rocha  Carlos A. Luengo  Colin E. Snape   《Organic Geochemistry》1999,30(12):1599

The primary oils obtained in high yields from fast (fluidised-bed) pyrolysis of biomass generally have high oxygen contents (ca. 40% w/w). The scope for using pyrolysis under hydrogen pressure (hydropyrolysis), to give oils with much lower oxygen contents compared to normal pyrolysis has been investigated. Fixed-bed hydropyrolysis tests have been conducted on cellulose, sugar cane bagasse and eucalyptus wood using hydrogen pressures up to 10 MPa, with heating rates of 5 and 300°C min⁻¹. A colloidal FeS catalyst was used in some tests (Fe loading of 5%, w/w) to increase overall conversions. Further, the attractive option of using a two-stage reactor in which the primary oil vapors are passed though a bed of hydrotreating catalyst is also described. Raising the hydrogen pressure from atmospheric to 10 MPa reduced the oxygen content of the primary oil by over 10% to below 20% w/w. The addition of a dispersed iron sulphide catalyst gave conversions close to 100% for all three biomass samples investigated at 10 MPa under conditions in the fixed-bed reactor where significant diffusional resistances existed and reduced the oxygen content of the bio-oil by a further 10%. Although NMR indicated that the oils became increasingly aromatic as more oxygen was removed, the increase in hydrogen pressure decreased the extent of overall aromatisation that occurs primarily due to the lower char yields obtained. In two-stage tests for cellulose, using a commercial sulphided Ni/Mo γ-Al₂O₃ catalyst at 400°C, increasing the hydrogen pressure from 2.5 to 10 MPa decreased the oxygen content of the oil by over 20% to 10% w/w. The H/C ratios were higher and O/C ratios smaller for the two-stage bio-oils compared to their single stage counterparts. However, the differences in the O/C ratios between the single and two-stage bio-oils increase with pressure.  相似文献   

The Common Fisheries Policy: An enforcement problem     

José-María Da Rocha  Santiago Cerviño  Sebastian Villasante 《Marine Policy》2012

Marine populations in Europe are in decline due to the unsuccessful results of the Common Fisheries Policy. By combining data of scientific recommendations from ICES, TACs approved and reported landings with an age-structured model, the objectives of this paper are to investigate the level of compliance of the TAC regulation, and the level of enforcement and its economic impact on fishery resources. The results presented here suggest that while there does not exist a regular pattern between TAC proposal and TAC approved, there is a clear pattern between TAC approved and reported landings. As a consequence, there is a regular lack of enforcement at national fisheries authority level. The paper also presents results of the recovery plans for the Southern hake and the Atlantic cod fisheries as case studies to illustrate the level of enforcement based on collusion between national fisheries advisers and industry. The results from both cases studies analyzed here indicate that drastic solutions could generate positive results for the recovery of the stocks, but perhaps they are not always the best measure in fisheries management due to the high economic losses for fishermen and social effects on coastal communities in the short and medium term. Finally, this work demonstrates that if the recovery plans had been implemented, the net present profits for both fisheries would have increased over time.  相似文献   

A land-use-based modelling chain to assess the impacts of Natural Water Retention Measures on Europe’s Green Infrastructure     

Sarah Mubareka  Christine Estreguil  Claudia Baranzelli  Carla Rocha Gomes  Carlo Lavalle  Barbara Hofer 《International journal of geographical information science》2013,27(9):1740-1763

This article details the process of integrating models to answer a specific policy-driven question: ‘What could be the impact of proposed Natural Water Retention Measures (NWRMs) on Europe’s Green Infrastructure (GI)?’ It describes the new Land Use Modelling Platform (LUMP), now enabling a high spatial scale (100-m) and large coverage (pan-European), whereby several sector-specific models contribute to assessing the impact of regional-level policy on a given spatial topic of concern. The configuration (land claims and land allocations modules) and calibration (accessibility and biophysical suitability) of the LUMP are explained. Four NWRM scenarios (riparian areas, afforestation, grassland and baseline scenario) are configured to run the simulations. For the reference: year 2006, the spatial representation of GI is based on land-use features of a refined version of the CORINE Land Cover (CLC), and resumed as connected components made of nodes and links.

Mathematical morphological image processing and network graph theory model, available from the free software package GUIDOS (the Joint Research Center of the European Commission), enabled the measurement of the GI connectivity and identified most critical links. Results show that the competition for land claimed by different economic sectors, combined with policy-driven rule-sets for the implementation of different NWRMs, yields very different results for the 2030 land-use projections, and subsequently for the morphology of GI. Three indicators associated with the morphology of GI are computed in order to assess the model outputs for 2030. The indicators are computed to answer the following questions: (1) How is the quantity of GI affected by each of the NWRM, and what proportion of that GI is most valuable? (2) What is the location of the most critical nodes and connectors of GI, and what land-use conversions occur under these? (3) Are the average components getting larger or smaller?

Whereas the grassland measure results in the largest net increase of GI, the afforestation measure results in the overall largest number of hectares of key nodes and links within the network. Land conversions occur under the critical GI nodes and links, with a large increase in agricultural areas, especially for the riparian measure under critical nodes and the grassland measure under critical links. Also predominant is the swapping of land from pasture to forest under critical links with the afforestation measure. The riparian measure most increases the average size of GI components, and all three measures contribute to bridging two large components which were divided in the 2006 land-use map, thus increasing the size of the largest component by more than 50%.  相似文献   

Talc mineralisation associated with soft hematite ore, Gongo Soco deposit, Minas Gerais, Brazil: petrography, mineral chemistry and boron-isotope composition of tourmaline     

Alexandre Raphael Cabral  Michael Wiedenbeck  Francisco Javier Rios  Ant?nio Augusto Seabra Gomes Jr  Orlando Garcia Rocha Filho  Richard David Jones 《Mineralium Deposita》2012,47(4):411-424

Talc mineralisation occurs as hematite–talc schist between soft hematite ore and dolomitic itabirite at Gongo Soco, Quadrilátero Ferrífero of Minas Gerais, Brazil. The hematite–talc schist and soft hematite have a prominent tectonic foliation of tabular hematite. Tabular hematite without preferential orientation is superimposed on the tectonic foliation. The talcose schist is enriched in F and has a constant Fe/S ratio. Electron-microprobe analyses indicate trace amounts of S in different generations of hematite. The whole-rock Fe/S ratio possibly represents sulfate S from hematite-hosted fluid inclusions. Fluid inclusions in foliation-overprinting hematite and chlorite geothermometry from talcose rocks suggest, respectively, temperatures from <200°C to ~300°C. Tourmaline, a rarely observed mineral in the hematite–talc schist, belongs to the alkali group and falls in the dravite compositional field. Boron-isotope determinations of tourmaline crystals, using secondary ion mass spectrometry, vary from −20‰ to −12‰ δ¹¹B. This compositional isotopic range and the tourmaline chemical composition suggest a meta-evaporitic origin. A non-marine evaporitic setting is the most likely source of acidic, highly oxidising fluids, which resulted in the abundant F-bearing talc and the presence of otherwise immobile Ti in hematite. Oxidising brines were channelled along shear zones and converted dolomitic itabirite into the Gongo Soco soft hematite and the talc mineralisation. The latter is envisaged as the hydrothermal wall-rock alteration of dolomitic itabirite, which gave rise to the soft hematite ore.  相似文献   

Moisture transport and intraseasonal variability in the South America monsoon system   总被引：1，自引：0，他引：1  

Leila M. V. Carvalho  Ana E. Silva  Charles Jones  Brant Liebmann  Pedro L. Silva Dias  Humberto R. Rocha 《Climate Dynamics》2011,36(9-10):1865-1880

This paper examines moisture transport on intraseasonal timescales over the continent and over the South Atlantic convergence zone (SACZ) during the South America (SA) summer monsoon. Combined Empirical Orthogonal Function analysis (EOFc) of Global Precipitation Climatology Project pentad precipitation, specific humidity, air temperature, zonal and meridional winds at 850?hPa (NCEP/NCAR reanalysis) are performed to identify the large-scale variability of the South America monsoon system and the SACZ. The first EOFc was used as a large-scale index for the South American monsoon (LISAM), whereas the second EOFc characterized the SACZ. LISAM (SACZ) index showed spectral variance on 30?C90 (15?C20) days and were both band filtered (10?C100?days). Intraseasonal wet anomalies were defined when LISAM and SACZ anomalies were above the 75th percentile of their respective distribution. LISAM and SACZ wet events were examined independently of each other and when they occur simultaneously. LISAM wet events were observed with the amplification of wave activity in the Northern Hemisphere and the enhancement of northwesterly cross-equatorial moisture transport over tropical continental SA. Enhanced SACZ was observed with moisture transport from the extratropics of the Southern Hemisphere. Simultaneous LISAM and SACZ wet events are associated with cross-equatorial moisture transport along with moisture transport from Subtropical Southwestern Atlantic.  相似文献   

Patterns of rare earth and other trace elements in different size fractions of clays of Campanian–Maastrichtian deposits from the Portuguese western margin (Aveiro and Taveiro Formations)     

Rosa Marques  M. Isabel Prudêncio  M. Isabel Dias  Fernando Rocha 《Chemie der Erde / Geochemistry》2011,71(4):337-347

The Upper Cretaceous (Campanian–Maastrichtian) Taveiro and Aveiro Formations belong to the northern sector of the Lusitanian basin (Portuguese western margin). The Taveiro Formation was deposited in alluvial fans, including mud flow beds, lakes and sinuous rivers. The Aveiro Formation was deposited in a flat region with low hydrodynamics channels, with the formation of a barrier island-tidal system. The reconstruction of this sedimentary basin may be difficult due to its complex architecture. This work aims a methodology to be used in the reconstruction of Cretaceous sedimentary environments of the Lusitanian basin, through the establishment of geochemical patterns of different size fractions of those deposits. Chemical analysis was performed by instrumental neutron activation analysis (INAA), and the mineralogical composition obtained by X-ray diffractometry (XRD). The whole rock and different size fractions (? ≥ 125 μm, 63–125 μm, 20–63 μm, 2–20 μm and ? < 2 μm) of selected samples were studied aiming the rare earth elements (REE) and other trace elements distribution and its correlation with the grain size and mineralogy.The results obtained for the studied Cretaceous sediments showed that REE patterns and other trace elements distribution in the different size fractions may be used as a tool to differentiate deposits within and between sedimentary formations. Within the Taveiro Formation, REE are concentrated in the silt fractions (20–63 μm and 2–20 μm) of the Reveles deposit, and in the clay size fraction of S. Pedro deposit, which is richer in kaolinite. The 1st transition elements, particularly Zn, are correlated with the presence of smectite in the clay fraction of Reveles deposit. In the sand and silt size fractions (>2 μm) of samples from Taveiro Formation correlations were found between: Ga and 1st transition elements, and phyllosilicates; Cs and mica; and Rb and Ba, and K–feldspars.The Bustos deposit (Aveiro Formation) samples are very fine-grained and with a high proportion of the fine silt fraction where REE are concentrated, especially the heavy ones. Incorporation of MREE, Co and U in carbonates of the coarser fraction appears to occur. The abundances of the 1st transition elements, Ga and As, are correlated with phyllosilicates.Significant differences were found in the trace elements patterns of the various analysed size fractions of the Lusitanian basin of Cretaceous sediments, between and even within formations, which can be used as a methodological approach for a fine paleogeographic reconstruction.  相似文献   

Interactive effects of environmental variability and human impacts on the long-term dynamics of an Amazonian floodplain lake and a South Atlantic coastal lagoon   总被引：2，自引：1，他引：1  

Reinaldo L. Bozelli  Adriano Caliman  Rafael D. Guariento  Luciana S. Carneiro  Jayme M. Santangelo  Marcos P. Figueiredo-Barros  Joo J.F. Leal  Adriana M. Rocha  Letícia B. Quesado  Paloma M. Lopes  Vinicius F. Farjalla  Claudio C. Marinho  Fabio Roland  Francisco A. Esteves 《Limnologica》2009,39(4):306-313

Human activities are exposing freshwater ecosystems to a wide range of stressors, whose direct and indirect effects can be alleviated or exacerbated through interactive effects with dynamic environmental drivers. This study used long-term data from two Neotropical lacustrine freshwater systems (Batata Lake, an Amazonian floodplain lake and Imboassica lagoon, an Atlantic coastal lagoon) subjected to different kinds of environmental fluctuations (i.e., flood pulse and sandbar opening) and anthropogenic impacts (i.e., siltation and eutrophication). Our objective was to determine whether the effects of human perturbations are contingent on modifications of important biotic and abiotic characteristics through environmental variability. For both ecosystems, environmental variability consistently interacted with anthropogenic perturbations to alter most of the variables analyzed, such as nutrient dynamics, chlorophyll-a concentration, zooplankton and benthic invertebrate species richness, and temporal community stability, which indicates that interactive effects between environmental variability and anthropogenic perturbations may impact a myriad of ecosystem properties. Furthermore, the nature of these interactive effects was highly dependent on the variable considered and on the ecosystem analyzed. For example, at Imboassica lagoon, sandbar openings interacted synergistically with trophic state to increase the phosphorus concentration in the water column. At Batata Lake, flooding generally alleviated the negative effects of siltation on species richness by both diluting inorganic suspended material concentration and by promoting local recruitment from the regional species pool. Such results indicate that our ability to understand and predict the outcome of anthropogenic impacts on inland aquatic systems can be hampered if we consider human stressors as “static” phenomena disconnected from dynamic interactions with major local environmental drivers.  相似文献   

Shear effects on hollow section piers under seismic actions: experimental and numerical analysis   总被引：1，自引：0，他引：1  

Raimundo Delgado  Pedro Delgado  Nelson Vila Pouca  António Arêde  Patrício Rocha  Aníbal Costa 《Bulletin of Earthquake Engineering》2009,7(2):377-389

Shear effects are often a very important issue on the seismic behaviour of piers, particularly for hollow section bridge piers. In fact, for this type of piers the cyclic response is similar to that of a structural wall in which both the transverse reinforcement ratio and the detailing can play an important role on its performance, even likely to be determinant in terms of the failure mechanism. On the other hand, codes and design guidelines are usually very conservative concerning shear capacity in order to avoid any shear failure mechanism likely to trigger well known catastrophic consequences. Therefore, research studies on this topic are still needed for a better understanding of pier cyclic shear response and also for improvement of the performance under seismic actions. Pursuing this general objective, this paper partially reports on an experimental/numerical campaign carried out on 1:4 reduced scale bridge piers in order to highlight and investigate shear-type problems. Within the scope of this paper, two specimens types were selected having equal rectangular hollow section (900 × 450 mm², 75 mm thick) but different transverse reinforcement detailing, namely one with a single stirrup per wall (representative of typical bridge construction without seismic design requirements) and another with multiple stirrups, according to Eurocode 8 provisions. Numerical simulations of the experimental results were also conducted aiming at contributing for complete and consistent interpretations of experimental results. Detailed modelling was performed allowing for realistic simulations of the non linear behaviour, particularly suitable when a significant shear component is involved. Therefore, the numerical strategy was based on a detailed 3D FEM discretization using a two-scalar variable damage model for the concrete constitutive law and a suitable cyclic behaviour law for steel bars represented by truss elements. Results have shown that shear deformation and failure modes are well simulated, while providing detailed insight concerning concrete damage pattern and distribution of yielding on the transverse and longitudinal reinforcement.  相似文献   

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia     

C. Rocha  J. Ibanhez  C. Leote   《Marine Chemistry》2009,115(1-2):43-58

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).  相似文献