Measurements of peroxyacetylnitrate in the marine boundary layer over the Atlantic     

K. P. Müller  J. Rudolph 《Journal of Atmospheric Chemistry》1992,15(3-4):361-367

The atmospheric concentration of peroxyacetylnitrate (PAN) was measured during a cruise of the R.S. Polarstern from Bremerhaven (Germany) to Rio Grande do Sul (Brazil) in September/ October 1988. The measurements were made in-situ by a combination of electron capture gaschromatography with a cryogenic preconcentration step. The theoretical lower limit of detection (3) was 0.4 ppt. The mixing ratios of PAN varied by more than three orders of magnitude from 2000 ppt in the English Channel to less than 0.4 ppt south of the Azores (38° N). South of 35° N, PAN levels were below the detection limit, except at 30–31° S off the eastern coast of South America. Here, PAN mixing ratios of 10 to 100 ppt were detected in continentally influenced air masses. Detectable levels of PAN were mostly observed in air masses of continental or high northern origin. Changes in the wind directions were usually associated with substantial changes in the PAN mixing ratios.  相似文献   

Periodicities in sea-level changes at Stockholm     

R. P. Kane  D. Gobbi 《Climatic change》1992,21(1):77-85

The annual mean sea-level time series for Stockholm (Sweden) for 1825–1984 (160 data points) had a large long-term negative (almost linear, only slightly quadratic) trend. After correcting for the same, the detrended series was subjected to maximum entropy spectral analysis (MESA). Choosing selected periodicities for further multiple regression analysis, series for the first 80 yr (1825–1904) showed periodicities at T = 2.40, 5.0, 6.1, 13.5, 14.8 and 32 yr, significant at a 2 level. The three largest peaks (italicized) had amplitudes of approximately (2.5–3.0) ± 0.8 cm. The latter 80 yr (1905–1984) showed significant periodicities at T= 2.05, 2.7, 3.0, 3.6, 4.4, 5.5, 6.3, 7.7, 9.8, 20.5 and 33 yr. The three largest peaks (italicized) had amplitudes of approximately (2.0–2.5) ± 0.7 cm. The whole period of 160 yr (1825–1984) showed significant periodicities at T = 2.05, 2.9, 3.2, 4.5, 4.9, 5.6, 6.4, 7.8, 11.0, 13.7, 14.8, 29 and 43 yr. The three largest peaks (italicized) had amplitudes of approximately (1.6–1.9) ± 0.6 cm. All these significant peaks explained a variance of only about 30% or less, indicating a large random component of approximately 70%. Peaks at T = 11 yr (sunspot cycle) or T = 18.6 yr (lunar nodal term) were either absent or very weak. Most of the other peaks were transient (present in the first 80 yr or the latter 80 yr) except an uncertain quasibiennial oscillation (QBO) (T = 2–3 yr) and T = 5–6 yr and T 30 yr, which seemed to be persistent throughout the whole period. Some periodicities seem to resemble those seen in the Southern Oscillation (SO) index.  相似文献   

Time resolved simulation of lightning by lip     

Jebens DS  Lakkaraju HS  McKay CP  Borucki WJ 《Geophysical research letters》1992,19(3):273-276

In this letter, we report results of time resolved spectra of lightning simulation in air by laser-induced plasma (LIP). The measured electron temperatures varied from (1.7 +/- 0.1)X10(4) K at 600 ns to (1.2 +/- 0.1)X10(4)K at 4 microseconds after the ignition of the plasma. Electron densities in the plasma varied from (7.0 +/- 1.4)X10(17)/cm3 to (9.0 +/- 1.8)X10(16)/cm3 for the above times. We also present, for the first time, a comparison of state variables for LIP and natural lightning. We find that immediately following the ignition both natural lightning and LIP reach temperatures in excess of 16,000K and relax to ambient pressure with different rates. They are expected to approach 2000 - 4000 K temperature range, which is important to chemical synthesis, in an asymptotically similar fashion.  相似文献   

Periodicities in the time series of annual minimum temperatures for the United States Gulf Coast region     

R. P. Kane  D. Gobbi 《Pure and Applied Geophysics》1992,138(2):323-333

The minimum winter temperature series for the United States Gulf Coast for 1799–1988 (190 values) was subjected to Maximum Entropy Spectral Analysis. Significant periodicities in the QBO region (T-2–3 years) and atT=3.7, 4.5, 5.5, 6.5, 7.5, 12.9, 15.5 and 22 years were detected. Some of these were present in the first half only (1799–1893) while others in the latter half only (1894–1988), indicating a transient nature. Also, more than 50% of the variance was random. Many of the significant periodicities are seen in other geophysical parameters. Some may be harmonics of the 11-year sunspot cycle and the 22-year Hale magnetic sunspot cycle.  相似文献   

Geochemical stratigraphy of the Huronian continental volcanics at Thessalon,Ontario: contributions of two-stage crustal fusion     

Wayne T. Jolly  A. P. Dickin  Tsai-Way Wu 《Contributions to Mineralogy and Petrology》1992,110(4):411-428

The 1500 m thick sequence of Huronian continental volcanics at Thessalon, Ontario is subdivided into 4 volcanic cycles, each of which includes abundant early mafic end-members, central intermediate flows, and late rhyolite units. Major and trace element concentrations are dominated by extensive gabbroic fractionation trends that ultimately produced two types of felsic flows: (1) rhyolites with high light rare earth element (LREE) and relatively low large-ion lithophile element (LILE) concentrations (high-LREE, low-LILE rhyolites), and (2) following late separation of REE-rich accessory phases, rhyolites depleted in LREE (low-LREE, high-LILE rhyolites). Mafic end-members of individual volcanic cycle are progressively less siliceous and less enriched in LILE and LREE with height in the stratigraphic section. Ti/Zr ratios gradually rise from 35 in early mafic flows to stabilize at about 85 in late units, while average SiO₂ contents decrease from 56 to about 50% and Mg# rises from about 48 to 52. -Nd values are consistently negative, indicating variable degrees of pre-fractionation crustal contamination of the end-member magmas during their uprise through the crust. Mixing models are consistent with up to 50% contamination by crustal material of tonalitic hornblende-gneiss composition. A progressive increase in -Nd, from about-5.0 to-0.5 upward in the volcanic succession, reflects a decreasing degree of crustal contamination due to development of insulating layers along margins of the feeder system. Detailed stratigraphic variations suggest that successive magmas batches were intercepted by a progressively fractionating, periodically replenished magma source, giving rise to open-system magmatism. Despite the prevalence of crustal assimilation in the Huronian lavas, (La/Sr)N ratios are too low in least contaminated end-members to be explained by contamination of tholeiitic magmas. The late basalts resemble instead modern island are basalts, and it is suggested that the subcontinental mantle source was enriched by subduction-related processes during crustal formation. Within individual volcanic cycles gabbroic fractionation trends systematically deviate from calculated factors toward compositions characteristic of hornblende-gneiss. Such relations suggest that further crustal contamination of the magmas occurred simultaneous with crystal fractionation. probably within undulating sills at upper crustal levels. Quantitative analysis suggests assimilation/fractional crystallization (A/FC) ratios of about 0.45. As a result of extensive two-stage contamination, rhyolites from the initial volcanic cycle incorporate a total of over 60% of crust.  相似文献   

Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′E to 14°38′E     

Anton P le Roex  Henry J B Dick  Ronald T Watkins 《Contributions to Mineralogy and Petrology》1992,110(2-3):253-268

Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K₂O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)_n ratios are particularly high (3.4–7.8). ⁸⁷Sr/⁸⁶Sr (0.70290–0.70368), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51284) and ²⁰⁶Pb/²⁰⁴Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry.  相似文献   

Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)     

BECCALUVA  L.; BARBIERI  M.; BORN  H.; BROTZU  P.; COLTORTI  M.; CONTE  A.; GARBARINO  C.; G.  C.B. GOMES; M.  ACCIOTTA; MORBIDELLI  L.; RUBERTI  E.; SIENA  F.; TRAVERSA  G. 《Journal of Petrology》1992,33(6):1371-1404

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.  相似文献   

Electron optical and X-ray powder diffraction study of synthetic and natural potassic cordierites     

P. Daniels  W. V. Maresch  W. Schreyer  K. Sahl 《Contributions to Mineralogy and Petrology》1992,111(4):484-492

The microstructural and X-ray diffraction characteristics of natural K-bearing cordierites in buchites (Blaue Kuppe, Germany), and paralavas (Bokaro, India) are compared to those of three suites of synthetic, K-bearing Mg-cordierite, studied after annealing glasses of the requisite compositions for durations between 5 min and 255 days at 1,290° C and 1 bar. In analogy to pure Mg-cordierite, hexagonal high-cordierite initially crystallizes from the glass and subsequently transforms to orthorhombic low-cordierite. After annealing for 30–60 min, the crystals develop tweed-structure. With prolonged annealing, the pattern coarsens and develops into lamellar twinning. Higher K-contents favour earlier development of tweed-contrast. Distortion indices obtained by X-ray powder diffraction show a sharp initial increase of with annealing time, followed by a levelling off after approximately 10 h. Higher K-contents delay this initial increase, and decrease drastically the maximum distortion index that can be attained. The contrasting observations with respect to increasing K-content are due to the different levels of information yielded by TEM and X-ray diffraction. Analyses of electron diffraction patterns indicate that the metric state of individual crystals in any single sample annealed for more than one hour is highly heterogeneous, while no compositional differences could be detected. Hexagonal and variously distored crystals coexist. Thus intermediate structural states of cordierite in the classical sense are shown to exist, although intermediate distortion indices obtained by routine X-ray powder diffraction are largely due to a summation effect over such structurally heterogeneous populations. Although distinct differences in microstructure between the synthetic and the natural Fe²⁺-bearing cordierites exist, the Bokaro samples most closely resemble the early (1–10 h) tweed-structure of the synthetic products, whereas the Blaue Kuppe samples are comparable to a more mature (1–3 days) stage. It is thus concluded that the cordierite-bearing Bokaro paralavas cooled considerably faster than the Blaue Kuppe buchites.  相似文献   

Les gisements d'or des tonalites archéennes (Abitibi,Québec)     

M. Jébrak 《Mineralium Deposita》1992,27(1):1-9

Résumé De nombreux gisements ont été mis en exploitation depuis une dizaine d'années dans des plutons granitiques de la ceinture de roches vertes archéennes de l'Abitibi. La plupart d'entre eux sont encaissés par des faciès sodiques. Dans la zone sud-est de cette ceintúre, il existe deux types de concentrations, des zones filoniennes et des disséminations à caractère porphyrique.Les gisements filoniens sont encaissés dans des sills ou des dykes de tonalite-trondhjemite. Deux associations minéralogiques sont distinguées, l'une avec tourmaline et scheelite, l'autre avec hématite et métaux de base, spécifiques de chacun des blocs lithotectoniques qui composent la ceinture. Les variations paragénétiques peuvent être mise en relation avec la profondeur de mise en place des systèmes hydrothermaux. A l'échelle d'un bloc, on observe des variations de la structure des minéralisations controlées par les variations de la pression de fluide, plus importante au coeur des massifs et conduisant à des structures plus régulières empruntant des zones de faiblesse préexistantes.Les disséminations sont associées à un granite tardif issu de la refusion de tonalites. Dans la région de Launay, près d'Amos, l'or est associé à des zones d'épisyénites avec pyrite et molybdénite, ou avec des zones de cisaillement. Elles pourraient correspondre à des concentrations plus précoces.

---

Several deposits have been developped since 10 years in granitics plutons of the Archean greenstone belt of Abitibi. Most of them are hosted by Na-rich granitoids. In the south-eastern part of Abitibi, two main type of deposit may be distinguished:The lode type is hosted in pre-tectonic dykes or sills of tonalite-trondhjemite. Two mineralogical association are caracterised, one with tourmaline, scheelite, the other with hematite, and seems specific of lithotectonic blocs. Paragenetic variations may be related to vertical variations of deposition. On a bloc scale, high fluid pressure predominate in the center of pluton and may be responsible for more regular structure.The disseminated type is hosted in late granodioritic intrusions associated with tonalite. The only occurrence of that type is the Launay deposit, near Amos. Gold is associated either with abite-rich episyenite, with pyrite and Mo, or with shear-zone cross-cutting the granitic intrusions.

  相似文献   

Seismic hazard monitoring in Kamchatka and its applications to the M = 6.6 earthquake of 6 October 1987     

V. M. Zobin  E. I. Gordeev  V. F. Bakhtiarov  E. I. Ivanova  Yu. M. Khatkevich  V. N. Khodenko  V. E. Levin  V. P. Mityakin 《Natural Hazards》1992,6(1):51-70

The earthquake of 6 October 1987 (M = 6.6), which occurred near the Shipunsky Cape, Kamchatka, was the largest crustal event in the vicinity of the main city of Kamchatka — Petropavlovsk-Kamchatsky — during the last three decades. It was followed by numerous aftershocks. This earthquake allowed us to test the effectiveness of the seismic hazard monitoring in Kamchatka, including the seismological, geodetic and hydrogeochemical surveys. The seismic survey provided the location and source nature of the main shock and aftershocks and the seismic environment of the main shock. The geodetic and hydrogeochemical surveys have yielded data on the response to earthquakes of the Earth's surface deformations, water level, and chemical elements concentration in the underground water. As a result, the following data were obtained:

u

The earthquake of 6 October had a seismic moment 4–10 E18 Nm, thrust type of faulting and the source volume of 20 × 20 × 10 km³. The maximum intensity was VI–VII (MSK-64 scale) and maximum acceleration 88 cm/s².

Before this event, a relative increase in the number of the upper mantle (depth more than 100 km) moderate magnitude earthquakes during 5 years and a one-year period of seismic quiescence for small shallow earthquakes, were recognized. Significant anomalies in HCO₃ and H₃BO₃ concentrations in the underground waters were observed in the wells a week before the main shock.

  相似文献