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431.
A sediment succession from Højby Sø, a lake in eastern Denmark, covering the time period 9400–7400 cal yr BP was studied using high-resolution geochemistry, magnetic susceptibility, pollen, macrofossil, diatom, and algal pigment analysis to investigate responses of the terrestrial and aquatic ecosystems to the 8.2 ka cold event. A reduced pollen production by thermophilous deciduous tree taxa in the period c. 8250–8000 cal yr BP reveal that the forest ecosystem was affected by low temperatures during the summer and winter/early-spring seasons. This finding is consistent with the timing of the 8.2 ka cold event as registered in the Greenland ice cores. At Højby Sø, the climate anomaly appears to have started 200–250 yr earlier than the 8.2 ka cold event as the lake proxy data provide strong evidence for a precipitation-induced distinct increase in catchment soil erosion beginning around 8500 cal yr BP. Alteration of the terrestrial environment then resulted in a major aquatic ecosystem change with nutrient enrichment of the lake and enhanced productivity, which lasted until c. 7900 cal yr BP.  相似文献   
432.
Mineral carbonation is one of several alternatives for CO2 sequestration and storage. The reaction rates of appropriate minerals with CO2, for instance olivine and serpentine with vast resources, are relatively slow in a CO2 sequestration context and the rates have to be increased to make mineral carbonation a good storage alternative. Increasing the dissolution rate of olivine has been the focus of this paper. Olivine was milled with very high energy intensity using a laboratory planetary mill to investigate the effect of mechanical activation on the Mg extraction potential of olivine in 0.01 M HCl solution at room temperature and pressure. Approximately 30–40% of each sample was dissolved and water samples were taken at the end of each experiment. The pH change was used to calculate time series of the Mg concentrations, which also were compared to the final Mg concentrations in the water samples. Percentage dissolved and the specific reaction rates were estimated from the Mg concentration time series. The measured particle size distributions could not explain the rate constants found, but the specific surface area gave a good trend versus dissolution for samples milled wet and the samples milled with a small addition of water. The samples milled dry had the lowest measured specific surface areas (<4 m2/g), but had the highest rate constants. The crystallinity calculated from X-ray diffractograms, was the material parameter with the best fit for the observed differences in the rate constants. Geochemical modelling of mechanically activated materials indicated that factors describing the changes in the material properties related to the activation must be included. The mechanically activated samples in general reacted faster than predicted by the theoretical models. Mechanical activation as a pre-treatment method was found to enhance the initial specific reaction rates by approximately three orders of magnitude for a sample milled dry for 60 min in a planetary mono mill compared to an unactivated sample. Wet milling in the planetary mill did not produce samples with the same maximum reaction rate as dry milling, but wet milling in general might be easier to implement into a wet carbonation process. Mechanical activation in a planetary mill is likely to consume too much energy for CO2 sequestration purposes, but the increase in obtained olivine rate constants illustrates a potential for using milling as a pre-treatment method.  相似文献   
433.
The selection criteria for the project of a new radio telescope in Egyptare described. The telescope will have a diameter of 32 m and will belocated in Abu Simbel (Upper Egypt). One major task of the telescope isthe participation in VLBI network operation.  相似文献   
434.
Garnet peridotite xenoliths in the Quaternary Pali-Aike alkali olivine basalts of southernmost South America are samples of the deeper portion of continental lithosphere formed by accretion along the western margin of Gondwanaland during the Phanerozoic. Core compositions of minerals in garnet peridotites indicate temperatures of 970 to 1160°C between 1.9 and 2.4 GPa, constraining a geothermal gradient which suggests a lithospheric thickness of approximately 100 km below this region. Previously, this lithosphere may have been heated and thinned to ≤80 km during the Jurassic break-up of Gondwanaland, when widespread mafic and silicic volcanism occurred in association with extension in southern South America. Subsequent cooling, by up to >175°C, and thickening, by about 20 km, of the lithosphere is reflected in low-temperature (<970°C) spinel peridotites by chemical zonation of pyroxenes involving a rimward decrease in Ca, and in moderate- and high-temperature (>970°C) peridotites by textural evidence for the transformation of spinel to garnet. A recent heating event, which probably occurred in conjunction with modal metasomatism related to the genesis of the Pali-Aike alkali olivine basalts, has again thinned the lithosphere to <100 km. Evidence for this heating is preserved in moderate- and high-temperature (>970°C) peridotites as chemical zonation of pyroxenes involving a rimward increase in Ca, and by kelyphitic rims around garnet. The majority of moderate- and high-temperature (>970°C) xenoliths are petrochemically similar to the asthenospheric source of mid-oceanic ridge basalts: fertile (>20% modal clinopyroxene and garnet), Fe-rich garnet lherzolite with major element composition similar to estimates of primitive mantle, but large-ion-lithophile and light-rare-earth element depletion relative to heavy-rare-earth elements, and with Sr, Nd, Pb, Os, and O isotopic compositions similar to MORB. In contrast, infertile, Mg-rich spinel harzburgite is predominant among low-temperature (<970°C) xenoliths. This implies a significant chemical gradient and increasing density with depth in the mantle section represented by the xenoliths, and the absence of a deep, low density, olivine-rich root below the southernmost South American crust such as has been inferred below Archean cratons. With respect to both temperature/rheology and chemistry/density, the subcontinental mantle lithosphere below southernmost South America is similar to that below oceanic crust. It is interpreted to have formed by tectonic capture, during the Paleozoic, of a segment of what had previously been oceanic lithosphere generated at a late Proterozoic mid-oceanic spreading ridge.  相似文献   
435.
The Anthropocene is proposed as a new interval of geological time in which human influence on Earth and its geological record dominates over natural processes. A major challenge in demarcating the Anthropocene is that the balance between human‐influenced and natural processes varies over spatial and temporal scales owing to the inherent variability of both human activities (as associated with culture and modes of development) and natural drivers (e.g. tectonic activity and sea level variation). Against this backdrop, we consider how geomorphology might contribute towards the Anthropocene debate by focusing on human impact on aeolian, fluvial, cryospheric and coastal process domains, and how evidence of this impact is preserved in landforms and sedimentary records. We also consider the evidence for an explicitly anthropogenic geomorphology that includes artificial slopes and other human‐created landforms. This provides the basis for discussing the theoretical and practical contributions that geomorphology can make to defining an Anthropocene stratigraphy. It is clear that the relevance of the Anthropocene concept varies considerably amongst different branches of geomorphology, depending on the history of human actions in different process domains. For example, evidence of human dominance is more widespread in fluvial and coastal records than in aeolian and cryospheric records, so geomorphologically the Anthropocene would inevitably comprise a highly diachronous lower boundary. Even to identify this lower boundary, research would need to focus on the disambiguation of human effects on geomorphological and sedimentological signatures. This would require robust data, derived from a combination of modelling and new empirical work rather than an arbitrary ‘war of possible boundaries' associated with convenient, but disputed, ‘golden’ spikes. Rather than being drawn into stratigraphical debates, the primary concern of geomorphology should be with the investigation of processes and landform development, so providing the underpinning science for the study of this time of critical geological transition. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
436.
Wildfire denudes vegetation and impacts chemical and physical soil properties, which can alter hillslope erosion rates. Post‐wildfire erosion can also contribute disproportionately to long‐term erosion rates and landscape evolution. Post‐fire hillslope erosion rates remain difficult to predict and document at the hillslope scale. Here we use 210Pbaex (lead‐210 mineral‐adsorbed excess) inventories to describe net sediment erosion on steep, convex hillslopes in three basins (unburned, moderately and severely burned) in mountainous central Idaho. We analyzed nearly 300 soil samples for 210Pbaex content with alpha spectrometry and related net sediment erosion to burn severity, aspect, gradient, curvature and distance from ridgetop. We also tested our data against models for advective, linear and non‐linear diffusive erosion. Statistically lower net soil losses on north‐ versus south‐facing unburned hillslopes suggest that greater vegetative cover and soil cohesion on north‐facing slopes decrease erosion. On burned hillslopes, erosion differences between aspects were less apparent and net erosion was more variable, indicating that vegetation influences erosion magnitude and fire drives erosion variability. We estimated net soil losses throughout the length of unburned hillslopes, including through a footslope transition to concave form. In contrast, on burned hillslopes, the subtle shift from convex to concave form was associated with deposition of a post‐fire erosion pulse. Such overall patterns of erosion and deposition are consistent with predictions from a non‐linear diffusion equation. This finding also suggests that concave sections of overall convex hillslopes affect post‐disturbance soil erosion and deposition. Despite these patterns, no strong relationships were evident between local net soil losses and gradient, curvature, distance from ridgetop, or erosion predicted with advection or diffusion equations. The observed relationship between gradient and erosion is therefore likely more complex or stochastic than often described theoretically, especially over relatively short timescales (60–100 years). Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
437.
Early marine diagenetic dolomite is a rather thermodynamically-stable carbonate phase and has potential to act as an archive of marine porewater properties. However, the variety of early to late diagenetic dolomite phases that can coexist within a single sample can result in extensive complexity. Here, the archive potential of early marine dolomites exposed to extreme post-depositional processes is tested using various types of analyses, including: petrography, fluid inclusion data, stable δ13C and δ18O isotopes, 87Sr/86Sr ratios, and U-Pb age dating of various dolomite phases. In this example, a Triassic carbonate platform was dissected and overprinted (diagenetic temperatures of 50 to 430°C) in a strike-slip zone in Southern Spain. Eight episodes of dolomitization, a dolostone cataclasite and late stage meteoric/vadose cementation were recognized. The following processes were found to be diagenetically relevant: (i) protolith deposition and fabric-preservation, and marine dolomitization of precursor aragonite and calcite during the Middle–Late Triassic; (ii) intermediate burial and formation of zebra saddle dolomite and precipitation of various dolomite cements in a Proto-Atlantic opening stress regime (T ca 250°C) during the Early–Middle Jurassic; (iii) dolomite cement precipitation during early Alpine tectonism, rapid burial to ca 15 km, and high-grade anchizone overprint during Alpine tectonic evolution in the Early Eocene to Early Miocene; (iv) brecciation of dolostones to cataclasite during the onset of the Carboneras Fault Zone activity during the Middle Miocene; and (v) late-stage regression and subsequent meteoric overprint. Data shown here document that, under favourable conditions, early diagenetic marine dolomites and their archive data may resist petrographic and geochemical resetting over time intervals of 108 or more years. Evidence for this preservation includes preserved Late Triassic seawater δ13CDIC values and primary fluid inclusion data. Data also indicate that oversimplified statements based on bulk data from other petrographically-complex dolomite archives must be considered with caution.  相似文献   
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