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61.
Chemical and isotopic data for 23 geothermal water samples collected in New Zealand within the Taupo Volcanic Zone (TVZ) are reported. Major and trace elements including Li, B and Sr and their isotopic compositions (δ7Li, δ11B, 87Sr/86Sr) were determined in high temperature geothermal waters collected from deep boreholes in different geothermal fields (Ohaaki, Wairakei, Mokai, Kawerau and Rotokawa geothermal systems). Lithium concentrations are high (from 4.5 to 19.9 mg/L) and Li isotopic compositions (δ7Li) are homogeneous, ranging between −0.5‰ and +1.4‰. In particular, it is noteworthy that, except for the samples from the Kawerau geothermal field having slightly higher δ7Li values (+1.4%), the other geothermal waters have a near constant δ7Li signature around a mean value of 0‰ ± 0.6 (2σ, n = 21). Boron concentrations are also high and relatively homogeneous for the geothermal samples, falling between 17.5 and 82.1 mg/L. Boron isotopic compositions (δ11B) are all negative, and display a range between −6.7‰ and −1.9‰. These B isotope compositions are in agreement with those of the Ngawha geothermal field in New Zealand. Lithium and B isotope signatures are in a good agreement with a fluid signature mainly derived from water/rock interaction involving magmatic rocks with no evidence of seawater input. On the other hand, Sr concentrations are lower and more heterogeneous and fall between 2 and 165 μg/L. The 87Sr/86Sr ratios range from 0.70549 to 0.70961. These Sr isotope compositions overlap those of the Rotorua geothermal field in New Zealand, confirming that some geothermal waters (with more radiogenic Sr) have interacted with bedrocks from the metasedimentary basement. Each of these isotope systems on their own reveals important information about particular aspects of either water source or water/rock interaction processes, but, considered together, provide a more integrated understanding of the geothermal systems from the TVZ in New Zealand.  相似文献   
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The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable87 Sr/86 Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.  相似文献   
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Natural and anthropogenic forcing factors and their changes significantly impact water resources in many river basins around the world. Information on such changes can be derived from fine scale in situ and satellite observations, used in combination with hydrological models. The latter need to account for hydrological changes caused by human activities to correctly estimate the actual water resource. In this study, we consider the catchment area of the Garonne river (in France) to investigate the capabilities of space-based observations and up-to-date hydrological modeling in estimating water resources of a river basin modified by human activities and a changing climate. Using the ISBA–MODCOU and SWAT hydrological models, we find that the water resources of the Garonne basin display a negative climate trend since 1960. The snow component of the two models is validated using the moderate-resolution imaging spectroradiometer snow cover extent climatology. Crop sowing dates based on remote sensing studies are also considered in the validation procedure. Use of this dataset improves the simulated evapotranspiration and river discharge amounts when compared to conventional data. Finally, we investigate the benefit of using the MAELIA multi-agent model that accounts for a realistic agricultural and management scenario. Among other results, we find that changes in crop systems have significant impacts on water uptake for agriculture. This work constitutes a basis for the construction of a future modeling framework of the sociological and hydrological system of the Garonne river region.  相似文献   
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Hybrid depositional systems are created by the interaction of two or more hydrodynamic processes that control facies distribution and their characteristics in terms of sedimentary structures and depositional geometry. The interaction of wave and tide both in the geological sedimentary record and modern environments has been rarely described in the literature. Mixed coastal environments are identified by the evidence of wave and tidal structures and are well identified in nearshore environments, while their recognition in lower shoreface–offshore environments lacks direct information from modern settings. Detailed field analyses of 10 stratigraphic sections of the Lower Ordovician succession (Fezouata and Zini formations; Anti‐Atlas, Morocco) have allowed the definition of 14 facies, all grouped in four facies zones belonging to a storm‐dominated, wave‐dominated sedimentary siliciclastic system characterized by symmetrical ripples of various scales. Peculiar sedimentary organization and sedimentary structures are observed: (i) cyclical changes in size of sedimentary structures under fair‐weather or storm‐weather conditions; (ii) decimetre‐deep erosional surfaces in swaley cross‐stratifications; (iii) deep internal erosion within storm deposits; (iv) discontinuous sandstone layers in most depositional environments, and common deposition of sandstones with a limited lateral extension, interpreted to indicate that deposition at all scales (metric to kilometric) is discontinuous; (v) combined flow–oscillation ripples showing aggrading–prograding internal structures alternating with purely aggrading wave ripples; and (vi) foreshore environments characterized by alternating phases of deposition of parallel stratifications, small‐scale and large‐scale ripples and tens of metres‐wide reactivation surfaces. These characteristics of deposition suggest that wave intensity during storm‐weather or fair‐weather conditions was continuously modulated by another controlling factor of the sedimentation: the tide. However, tidal structures are not recognized, because they were probably not preserved due to dominant action of storms and waves. A model of deposition is provided for this wave‐dominated, tide‐modulated sedimentary system recording proximal offshore to intertidal–foreshore environments, but lacking diagnostic tidal structures.  相似文献   
66.
We examined the spatial dynamic of artisanal fishing fleets around five European marine protected areas (MPAs) to derive general implications for the evaluation of MPAs as fisheries management tools. The coastal MPAs studied were located off France, Malta and Spain and presented a variety of spatial designs and processes of establishment. We developed a standardized methodology to define factors influencing effort allocation and to produce fishing effort maps by merging GIS with geostatistical modelling techniques. Results revealed that in most cases the factors “distance to the no-take”, “water depth”, and “distance to the port” had a significant influence on effort allocation by the fishing fleets. Overall, we found local concentration of fishing effort around the MPA borders. Thus, neglecting the pattern of fishing effort distribution in evaluating MPA benefits, such as spillover of biomass, could hamper sound interpretation of MPAs as fisheries management tools.  相似文献   
67.
The Eocene–Oligocene transition (EOT, ~34 Ma) is the largest global cooling of the Cenozoic Era and led the Earth's climatic system to change from a greenhouse to an icehouse mode. Although it is well documented in marine settings, the few studies focusing on continental environments have demonstrated regional heterogeneities. The study core CDB1, located in the Rennes Basin (Western France), is a unique terrestrial (lacustrine–palustrine) record comprising well‐preserved and terrestrial‐derived organic‐rich sediments encompassing the EOT. Clay minerals and the first organic nitrogen isotope record (δ15Norg) of terrestrial origin for this period are used to reconstruct palaeoclimate changes across this key interval. As suggested in worldwide marine and a few continental records, a stepwise transition from warm/humid conditions in the Late Eocene to cooler/drier conditions in the Early Oligocene is confirmed in the area. In addition, an episode of drier conditions in the Late Eocene and humid/dry cycles in the Early Oligocene are suggested.  相似文献   
68.
The Cenozoic-age metamorphic structure of the Alps consists of a throughgoing pressure-dominated belt (blueschists and eclogites) that strikes parallel to the orogen and was later truncated by two thermal domes characterised by Barrow-type metamorphism (Lepontine dome and Tauern window). This study documents for the first time that relics of Fe-Mg carpholite occur also within meta-sedimentary units that are part of the north-eastern Lepontine structural and metamorphic dome, where so far exclusively Barrovian assemblages were found. They occur in meta-sediments of both Valais Oceanderived Lower Penninic Bündnerschiefer and structurally lower Europe-derived Sub-Penninic cover nappes and slices. These high-pressure units were subsequently overprinted by a thermal event, as is documented by the growth of new minerals typical for Barrovian metamorphism.We present evidence for a two-stage metamorphic evolution in the northern part of the Lepontine dome: (1) Early subduction-related syn-D1 (Safien phase) HP/LT metamorphism under blueschist facies conditions (350–400 °C and 1.2–1.4 GPa) was immediately followed by “cold” isothermal (or cooling) decompression during D2 nappe-stacking (Ferrera phase). (2) Collisionrelated Barrovian overprint (500–570 °C and 0.5–0.8 GPa) postdates the D3 nappe-refolding event (Domleschg phase) and represents a late heating pulse, separated by D2 and D3 from the D1 high-pressure event. It occurred before and/or during the initial stages of D4 (Chiéra phase) representing a second nappe-refolding event.In discussing possible heat sources for the late Barrow-type heating pulse it is argued that heat release from radioactive decay of accreted material may play an important role in contributing much to heat production. Based on the field evidence, we conclude that heat transfer was essentially conductive during these latest stages of the thermal evolution.  相似文献   
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