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Lithium isotopes in island arc geothermal systems: Guadeloupe, Martinique (French West Indies) and experimental approach 总被引：1，自引：0，他引：1
We report lithium (Li) isotopic measurements in seawater-derived waters that were discharged from geothermal wells, thermal springs, and sub-marine springs located in volcanic island arc areas in Guadeloupe (the Bouillante geothermal field) and Martinique (Lamentin plain and the Diamant areas). While Li isotopic signatures of the geothermal fluids collected from deep reservoirs were found to be homogeneous for a given site, the δ7Li signatures for each of these reservoirs were significantly different. The first low temperature (25-250 °C) experiments of Li isotope exchange during seawater/basalt interaction confirmed that Li isotopic exchange is strongly temperature dependent, as previously inferred from natural studies. Li isotopic fractionation ranged from +19.4‰ (Δsolution-solid) at 25 °C to +6.7‰ at 250 °C. These experiments demonstrated the importance of Li isotopic fractionation during the formation of Li-bearing secondary minerals and allowed us to determine the following empirical relationship between isotopic fractionation and temperature: Δsolution-solid = 7847/T − 8.093. Application of experimental results and literature data to the Bouillante area suggested that geothermal water was in equilibrium at 250-260 °C. It likely has a deep and large reservoir located in the upper sheeted dike complex of the oceanic crust, just below the transition zone between andesite volcanic flows and the basaltic dikes. The upper dike section, from which Li is extracted by hydrothermal fluids, was characterized by light Li isotopic values in the rocks, indicating retention of 6Li by the altered rocks. For the Lamentin and Diamant areas, the geothermal fluids appeared to be in equilibrium with reservoir volcano-sedimentary rocks at 90-120 °C and 180 °C, respectively. Further evidence for this argument is provided by the fact that only the Na/Li thermometric relationship determined for sedimentary basins yielded temperature values in agreement with those measured or estimated for the reservoir fluids. This suggests the importance of a sedimentary signature in these reservoir rocks. Altogether, this study highlights that the use of Li isotopic systematics is a powerful tool for characterizing the origin of geothermal waters as well as the nature of their reservoir rocks. 相似文献
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Bernard Sanjuan Romain Millot Chrystel Dezayes Michel Brach 《Comptes Rendus Geoscience》2010,342(7-8):546-559
Three deep wells (5000 m) have been drilled into a fractured granite basement at Soultz-sous-Forêts, within the Tertiary Rhine Graben, in order to develop a heat exchanger and produce electricity after the creation of an EGS reservoir. Very few analyses representative of the deep geothermal fluids are available because of frequent contamination by drilling fluids or injected waters. These indicate similar chemical and isotopic compositions (NaCl fluids) and high salinities (about 100 g/l) suggesting a common sedimentary origin and identical water–rock interaction processes at equilibrium temperatures close to 230 °C in a sedimentary rather than a granite reservoir. The latter would be situated closer to the Graben centre where the Triassic Buntsandstein formation is deepest and hottest. Tracer tests conducted after 2000 show that the deep native geothermal brine is omnipresent in the fluids discharged during the production and circulation tests. Its natural convective flux was estimated at 1–1.2 m3/h. 相似文献
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The hydrothermal system of Saint-Gervais-les-Bains, France is located in a south western low-elevation point of the Aiguilles Rouges crystalline Massif. The crystalline rocks are not directly outcropping in the studied area but certainly exist beyond 300 m depth. Uprising waters are pumped from two different aquifers below the Quaternary deposits of the Bon Nant Valley. In the Lower Trias-Permian aquifer crossed by De Mey boreholes (27–36 °C), the ascending Na-SO4 and high-Cl thermal water from the basement (4.8 g/L) is mostly mixed by a Ca-SO4 and low-Cl cold water circulating in the autochthonous cover of the Aiguilles Rouges Basement. The origin of the saline thermal water probably results from infiltration and circulation in the basement until it reaches deep thrust faults with leaching of residual brines or fluid inclusions at depth (Cl/Br molar ratio lower than 655). The dissolution of Triassic halite (Cl/Br > 1000) is not possible at Saint-Gervais-les-Bains because the Triassic cold waters have a low-Cl concentration (< 20 mg/L). Water–rock interactions occur during the upflow via north–south strike-slip faults in the basement and later on in the autochthonous cover. For the De Mey Est borehole, gypsum dissolution is occurring with cationic exchanges involving Na, as well as low-temperature Mg dissolution from dolomite in the Triassic formations. The aquifer of imbricated structures (Upper-Middle Trias) crossed by the Lépinay well (39 °C) contains thermal waters, which are strongly mixed with a low-Cl water, where gypsum dissolution also occurs. The infiltration area for the thermal end-member is in the range 1700–2100 m, close to the Lavey-les-Bains hydrothermal system corresponding to the Aiguilles Rouges Massif. For the Ca-SO4 and low-Cl end-member, the infiltration area is lower (1100–1300 m) showing circulation from the Mont Joly Massif. The geothermometry method indicates a reservoir temperature of probably up to 65 °C but not exceeding 100 °C. 相似文献
35.
Northern latitude chemical weathering rates: clues from the Mackenzie River Basin, Canada 总被引：9，自引：0，他引：9
The main scope of this study is to investigate parameters controlling chemical weathering rates for a large river system submitted to subarctic climate. More than 110 river water samples from the Mackenzie River system (northern Canada) have been sampled and analyzed for major and trace elements and Sr isotopic ratios in the dissolved phase. The three main morphological units are reflected in water chemistry. Rivers from the Canadian Shield are very dilute, dominated by silicate weathering (Millot et al., 2002), whereas the rivers of the Rocky and Mackenzie Mountains as well as the rivers of the sedimentary Interior Platform are dominated by carbonate weathering and are SO4 rich. Compared to the rivers of the Mackenzie and Rocky Mountains, the rivers of the interior plains are organic, silica, and Na rich and constitute the dominant input term to the Mackenzie River mainstream. Rivers of the Canadian Shield area do not significantly contribute to the Mackenzie River system. Using elemental ratios and Sr isotopic ratios, a mathematical inversion procedure is presented that distinguishes between solutes derived from silicate weathering and solutes derived from carbonate weathering. Carbonate weathering rates are mostly controlled by runoff, which is higher in the mountainous part of the Mackenzie basin. These rates are comparable to the carbonate weathering rates of warmer areas of the world. It is possible that part of the carbonate weathering is controlled by sulfide oxidative weathering, but its extent remains difficult to assess. Conversely to what was stated by Edmond and Huh (1997), overall silicate weathering rates in the Mackenzie basin are low, ranging from 0.13 to 4.3 tons/km2/yr (Na + K + Ca + Mg), and confirm the negative action of temperature on silicate weathering rates for river basins in cold climates. In contrast to what has been observed in other large river systems such as the Amazon and Ganges Rivers, silicate weathering rates appear 3 to 4 times more elevated in the plains than in the mountainous headwaters. This contradicts the “Raymo hypothesis” (Raymo and Ruddiman, 1992). Isotopic characterization of suspended material clearly shows that the higher weathering rates reported for the plains are not due to the weathering of fine sediments produced in the mountains (e.g., by glaciers) and deposited in the plains. Rather, the relatively high chemical denudation rates in the plains are attributed to lithology (uncompacted shales), high mechanical denudation, and the abundance of soil organic matter derived from incomplete degradation and promoting crystal lattice degradation by element complexation. The three- to fourfold factor of chemical weathering enhancement between the plains and mountains is similar to the fourfold factor of enhancement found by Moulton et al. (2000) between unvegetated and vegetated watershed. This study confirms the negative action of temperature on silicate weathering for cold climate but shows that additional factors, such as organic matter, associated with northern watersheds are able to counteract the effect of temperature. This acceleration by a factor of 4 in the plains is equivalent to a 6°C increase in temperature. 相似文献
36.
Guillermo Booth-Rea José Miguel Azañón Vı́ctor Garcı́a-Dueñas Romain Augier Mario Sánchez-Gómez 《Comptes Rendus Geoscience》2003,335(2):265-274
The Santi Petri dome (western Betics, southern Spain) shows a core-complex-like structure, where migmatitic gneisses and schists outcrop below low-grade slates and phyllites, all of which form the basement of the Neogene Málaga basin. The migmatites and schists suffered a coaxial-flattening event during isothermal decompression and were later exhumed by ductile ESE non-coaxial stretching. Further exhumation was achieved by W- to SW-transport brittle low-angle normal faulting. Subsequently these extensional structures were gently folded in the core of a NE/SW-oriented antiform during the Tortonian. Finally the Santi Petri domal geometry was accentuated by the interference of orthogonal high-angle faults with ENE–WSW and NNW–SSE orientation. This core-complex-like structure, formed by superposition of extensional and compressive tectonic events, does not represent a classical, purely extensional core complex, which shows that metamorphic structure and geometry are not decisive criteria to define a core-complex. 相似文献
37.
ABSTRACT Nappe refolding, back-thrusting and normal faulting frequently cause severe late-stage overprinting of the architecture of an orogen. A combined investigation of nappe stack polarity, kinematics of shearing and metamorphic gradients in the Western Alps develops criteria for distinguishing between these three modes of late-stage deformation. This distinction is a prerequisite for any retro-deformation necessary for understanding the main tectonic and metamorphic evolution of collisional orogens. In the case of the Western Alps overprint was by mega-scale nappe refolding in the Oligocene. This implies exhumation of the HP-rocks prior to postnappe folding, i.e. during nappe stacking and by foreland-directed ascent within a subduction channel. 相似文献
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Caritg Séverine Burkhard Martin Ducommun Romain Helg Urs Kopp Lionel Sue Christian 《地学学报》2004,16(1):27-37
We document two phases of folding within the central part of the Late Palaeozoic Anti‐Atlas chain of Morocco. A first generation of SW–NE folds involve a horizontal shortening of 10–20%, accommodated by polyharmonic buckle folding of contrasting wavelengths in Ordovician Jbel Bani quartzites and Devonian Jbel Rich carbonates. A second generation of folds with similar style and wavelengths in an E–W direction lead to complex interference patterns. Dome and basins are developed within the Jbel Rich and within Lower Cambrian dolomites. Both folding phases are related to thick‐skinned uplift of Precambrian basement in a Laramide style. In contrast to the typical Rocky Mountain foreland style, however, cover deformation in the Anti‐Atlas is mostly decoupled from the undying basement along thick incompetent horizons such as the Lower Cambrian Lie‐de‐Vin and Silurian shales. 相似文献
39.
Jean Carignan Nathalie Vigier Romain Millot 《Geostandards and Geoanalytical Research》2007,31(1):7-12
The CRPG (Nancy, France) has prepared secondary reference materials for Li isotope measurements by mixing 7 Li or 6 Li spikes and either L-SVEC or IRMM-016 certified reference materials to produce solutions having a known Li concentration and isotopic composition. The Li7-N and Li6-N solution samples (1.5 mol l−1 HNO3 ) have nominal δ7 Li isotopic compositions of 30.1‰ and -9.7‰ respectively relative to L-SVEC and concentrations of 100 mg l−1 . Repeated measurement of these samples using the QUAD-ICP-MS at the CRPG yielded δ7 Li of 30.4 ± 1.1‰ (n = 13) and -8.9 ± 0.9‰ (n = 9) at the 2s level of confidence. An additional LiCl-N solution was measured and yielded a delta value of 9.5 ± 0.6‰ (n = 3). Identical results were obtained at the BRGM (Orléans, France) from determinations performed with a Neptune MC-ICP-MS (30.2 ± 0.3‰, n = 89 for the Li7-N, -8.0 ± 0.3‰, n = 38 for the Li6-N and 10.1 ± 0.2‰, n = 46 for LiCl-N at the 2s level of confidence). The deviation of measured composition relative to the nominal value for the Li6-N solution might be explained by either contamination during preparation or an error during sample weighing. These secondary reference materials, previously passed through ion exchange resin or directly analysed, may be used for checking the accuracy of Li isotopic measurements over a range of almost 40‰ and will be available to the scientific community upon request to J. Carignan or N. Vigier, CRPG. 相似文献
40.
Michael Abratis Jonas Mädler Siegfried Hautmann Romain Meyer Lothar Viereck-Götte 《Chemie der Erde / Geochemistry》2007,67(2):133-150
New 40Ar/39Ar age data are determined for Cenozoic basaltic rocks from the Thuringian Rhön and Heldburg Gangschar (area also referred to as Grabfeld), integral parts of the Central European Volcanic Province. Applying the incremental heating technique on groundmass and plagioclase separates provided data which considerably specify our knowledge on the eruption ages in these volcanic fields and narrow down the duration of volcanic activity compared to earlier studies. All data but one outlier range between 20 and 14 Ma, being thus similar to those of the neighbouring Vogelsberg volcanic complex. The spectrum of ages is clearly divided into two distinct subsets: the Rhön ages are between 20 and 18 Ma, those of the Heldburg Gangschar are between 16 and 14 Ma. Thus, the present data clearly indicate a striking regional and temporal division of the Thuringian Miocene volcanism. The composition of the volcanic rocks in the two volcanic fields is remarkably diverse, ranging from tholeiitic basalts over alkali basalts and basanites to nephelinites. However, radiometric ages do not correlate with geochemical or petrological characteristics of the volcanics within each volcanic field, indicating that the different magma types erupted broadly contemporaneously.The outlier in age (29 Ma) is from a volcanic dyke of the NE Rhön area close to the NW end of the Thuringian Forest. However, more data are required to approve the significance of this age value, in particular since the rock showed isotopic age disturbance. 相似文献