Solubility of Fe-ettringite (Ca₆[Fe(OH)₆]₂(SO₄)₃ · 26H₂O)     

Göril Möschner  Barbara Lothenbach  Andrea Ulrich  Ruben Kretzschmar 《Geochimica et cosmochimica acta》2008,72(1):1-18

The solubility of Fe-ettringite (Ca₆[Fe(OH)₆]₂(SO₄)₃ · 26H₂O) was measured in a series of precipitation and dissolution experiments at 20 °C and at pH-values between 11.0 and 14.0 using synthesised material. A time-series study showed that equilibrium was reached within 180 days of ageing. After equilibrating, the solid phases were analysed by XRD and TGA while the aqueous solutions were analysed by ICP-OES (calcium, sulphur) and ICP-MS (iron). Fe-ettringite was found to be stable up to pH 13.0. At higher pH-values Fe-monosulphate (Ca₄[Fe(OH)₆]₂(SO₄) · 6H₂O) and Fe-monocarbonate (Ca₄[Fe(OH)₆]₂(CO₃) · 6H₂O) are formed. The solubilities of these hydrates at 25 °C are:   相似文献   

Comparison Between Radar and Automatic Weather Station Refractivity Variability     

Ruben Hallali  Francis Dalaudier  Jacques Parent du Chatelet 《Boundary-Layer Meteorology》2016,160(2):299-317

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Primary production, plant and detrital biomass, and particle transport in the Columbia River Estuary     

Lawrence F. Small  C.David McIntire  Keith B. MacDonald  J.Ruben Lara-Lara  Bruce E. Frey  Michael C. Amspoker  Ted Winfield 《Progress in Oceanography》1990,25(1-4)

The dynamics of primary production and particulate detritus cycling in the Columbia River Estuary are described, with particular reference to mechanisms that account for patterns within the water column, on the tidal flats, and in the adjacent wetlands. Analysis of patterns in phytoplankton flora and biomass and in distribution of detrital particulate organic matter (DPOC) in the water column indicated that salinities of 1–5 delineated an essentially freshwater flora from a marine or euryhaline flora, and that living phytoplankton was converted to DPOC at the freshwater-brackishwater interface. Similarly, the benthic diatom assemblages on tidal flats reflected either the fresh or the brackish nature of the water inundating the flats. Emergent vascular plants were grouped into six associations by cluster analysis, the associations being separated mainly on the bases of different relative abundances of freshwater, euryhaline or brackishwater species, and on whether samples occurred in high or low marsh areas.Annual rates of net areal 24-hr production averaged 55, 16, and 403gC m⁻²y⁻¹ for phytoplankton, benthic algae, and emergent vascular vegetation, respectively. Total production over the whole estuary was 17,667 metric tons C y⁻¹ for phytoplankton, 1,545mt C y⁻¹ for benthic algae, and 11,325mt C y⁻¹ for emergent vascular plants, for a grand total to 30,537mt C y⁻¹. Phytoplankton biomass turned over approximately 39 times per year on average, while benthic algae turned over about twice and emergent plants once per year.Budgets for phytoplankton carbon (PPOC) and DPOC were developed based on PPOC and DPOC import and export, grazing loss, and in situ production and conversion of PPOC to DPOC. It is suggested that 36,205mt y⁻¹ of PPOC is converted to DPOC in the estuary, principally at the freshwater-brackishwater interface. About 40,560mt y⁻¹ of PPOC is exported to the ocean, and 159,185mt y⁻¹ of DPOC is transported into the marine zone of the estuary (no data are available on DPOC export to the ocean). Thus, the estuary acts principally as a conduit for the transport of particles to the sea, and only secondarily as a converter of viable phytoplankton cells to detrital carbon and as a trap for DPOC.  相似文献   

Palaeomagnetic and rock-magnetic study of a Pliocene volcanic section in southern Georgia (Caucasus)     

Goguitchaichvili  A.T.  Sologachvili  D.Z.  Prévot  M.  Calvo  M.  Pavlenichvili  E. Sh.  Maissuradze  G.M.  Schnepp  E. 《Geologie en Mijnbouw》1997,76(1-2):135-143

Twenty-six basaltic flows were sampled for a paleomagnetic and rock-magnetic study of the Tchuntchka section in the Akhalkalaki volcanic region in southern Georgia (Caucasus). Three to five samples from each flow were subjected to thermal or alternating-field demagnetization. The upper part of the section yields normal (D = 355.5°, I = 54.2°, N = 17, ₉₅ = 2.5°, k = 226), and the lower part reversed polarity directions (D = 180.3°, I = – 59.4,° N = 8, ₉₅ = 4.8°, k = 135). An anomalous direction was found in one flow in the upper part (D = 118.5°, I = – 77.3°). Rock-magnetic experiments show that the remanence is carried in most cases by magnetite or low-Ti titanomagnetite. The fraction of grains with a multidomain magnetic structure does not seem to be important. The remanence carried by such grains is removed only partly by low-temperature demagnetization. A tentative magnetostratigraphic correlation between the 3.8-Ma-old Thoki and Tchuntchka sites is proposed.  相似文献   

Provenance of siliciclastic and hybrid turbiditic arenites of the Eocene Hecho Group,Spanish Pyrenees: implications for the tectonic evolution of a foreland basin     

M. A. Caja  R. Marfil  D. Garcia  E. Remacha  S. Morad  H. Mansurbeg  A. Amorosi  C. Martínez‐Calvo  R. Lahoz‐Beltrá 《Basin Research》2010,22(2):157-180

The Eocene Hecho Group turbidite system of the Aínsa‐Jaca foreland Basin (southcentral Pyrenees) provides an excellent opportunity to constrain compositional variations within the context of spatial and temporal distribution of source rocks during tectonostratigraphic evolution of foreland basins. The complex tectonic setting necessitated the use of petrographic, geochemical and multivariate statistical techniques to achieve this goal. The turbidite deposits comprise four unconformity‐bounded tectonostratigraphic units (TSU), consisting of quartz‐rich and feldspar‐poor sandstones, calclithites rich in extrabasinal carbonates and hybrid arenites dominated by intrabasinal carbonates. The sandstones occur exclusively in TSU‐2, whereas calclithites and hybrid arenites occur in the overlying TSU‐3, TSU‐4 and TSU‐5. The calclithites were deposited at the base of each TSU and hybrid arenites in the uppermost parts. Extrabasinal carbonate sources were derived from the fold‐and‐thrust belt (mainly Cretaceous and Palaeocene limestones). Conversely, intrabasinal carbonate grains were sourced from foramol shelf carbonate factories. This compositional trend is attributed to alternating episodes of uplift and thrust propagation (siliciclastic and extrabasinal carbonates supplies) and subsequent episodes of development of carbonate platforms supplying intrabasinal detrital grains. The quartz‐rich and feldspar‐poor composition of the sandstones suggests derivation from intensely weathered cratonic basement rocks during the initial fill of the foreland basin. Successive sediments (calclithites and hybrid arenites) were derived from older uplifted basement rocks (feldspar‐rich and, to some extent, rock fragments‐rich sandstones), thrust‐and‐fold belt deposits and from coeval carbonate platforms developed at the basin margins. This study demonstrates that the integration of tectono‐stratigraphy, petrology and geochemistry of arenites provides a powerful tool to constrain the spatial and temporal variation in provenance during the tectonic evolution of foreland basins.  相似文献   

Rock-magnetic and paleomagnetic survey on dated lava flows erupted during the Bruhnes and Matuyama chrons: the Mascota Volcanic Field revisited (Western Mexico)     

Rafael García-Ruiz  Avto Goguitchaichvili  Miguel Cervantes-Solano  Juan Morales  Rafael Maciel-Peña  José Rosas-Elguera  Ruben Cejudo-Ruiz  Jaime Urrutia-Fucugauchi 《Studia Geophysica et Geodaetica》2017,61(2):249-263

A rock magnetic and paleomagnetic investigation was performed on some selected, radiometrically dated lava flows from the Mascota Volcanic Field (MVF), western Trans- Mexican Volcanic Belt. A set of rock-magnetic experiments and standard paleomagnetic analysis were carried out on 19 sites spanning the time interval from 2268 to 72 kyr. The paleomagnetic directions are anchored to absolute radiometric ages while no such information was available in previous studies. This makes possible to correctly evaluate the fluctuation of Earth’s magnetic field from Pliocene to Pleistocene and reveal the firm evidence of possible Levantine excursion. Both Ti-poor and Ti-rich titanomagnetites seem to carry the remanent magnetization with Curie temperatures ranging from 350°C to 537°C. Thirteen flows correspond to the Brunhes chron, one of them exhibits transitional directions, while the remaining six sites belong to the Matuyama chron. New and existing dataset for MVF were used to estimate the paleosecular variation parameters. The selected data include 35 Plio-Quaternary lava flows. After excluding the poor quality data, as well as the transitional directions, the mean paleodeclination is 356.1° and oaleoinclination 39.9°, which agree well with the geocentric axial dipole (GAD) and the expected paleodirections for the Plio-Pleistocene, as derived from the reference poles for the stable North America. The corresponding mean paleomagnetic poles are paleolongitude 226.7° and paleolatitude 86.0°. The virtual geomagnetic pole scatter for the MVF is 15.2°, which is consistent with the value expected from model G at latitude of 20° (this model provides an interpretation of the paleosecular variation at different latitudes for the time of interest). The combined paleomagnetic data, supported by positive reversal test, indicate no paleomagnetically detectable vertical-axis rotations in the study area. The evidence of one transitional directions was detected, which may correspond to the Levantine excursion (360-370 kyr) or unnamed event between 400-420 kyr.  相似文献   

An analysis of the convergence of Newton iterations for solving elliptic Kepler’s equation     

A. Elipe  J. I. Montijano  L. Rández  M. Calvo 《Celestial Mechanics and Dynamical Astronomy》2017,129(4):415-432

In this note a study of the convergence properties of some starters \( E_0 = E_0(e,M)\) in the eccentricity–mean anomaly variables for solving the elliptic Kepler’s equation (KE) by Newton’s method is presented. By using a Wang Xinghua’s theorem (Xinghua in Math Comput 68(225):169–186, 1999) on best possible error bounds in the solution of nonlinear equations by Newton’s method, we obtain for each starter \( E_0(e,M)\) a set of values \( (e,M) \in [0, 1) \times [0, \pi ]\) that lead to the q-convergence in the sense that Newton’s sequence \( (E_n)_{n \ge 0}\) generated from \( E_0 = E_0(e,M)\) is well defined, converges to the exact solution \(E^* = E^*(e,M)\) of KE and further \( \vert E_n - E^* \vert \le q^{2^n -1}\; \vert E_0 - E^* \vert \) holds for all \( n \ge 0\). This study completes in some sense the results derived by Avendaño et al. (Celest Mech Dyn Astron 119:27–44, 2014) by using Smale’s \(\alpha \)-test with \(q=1/2\). Also since in KE the convergence rate of Newton’s method tends to zero as \( e \rightarrow 0\), we show that the error estimates given in the Wang Xinghua’s theorem for KE can also be used to determine sets of q-convergence with \( q = e^k \; \widetilde{q} \) for all \( e \in [0,1)\) and a fixed \( \widetilde{q} \le 1\). Some remarks on the use of this theorem to derive a priori estimates of the error \( \vert E_n - E^* \vert \) after n Kepler’s iterations are given. Finally, a posteriori bounds of this error that can be used to a dynamical estimation of the error are also obtained.  相似文献   

Two simple image slicers for high resolution spectroscopy     

M. Tala  L. Vanzi  G. Avila  C. Guirao  E. Pecchioli  A. Zapata  F. Pieralli 《Experimental Astronomy》2017,43(2):167-176

We present the design, manufacturing, test and performance of two image slicers for high resolution spectroscopy. Based on the classical Bowen-Walraven concept, our slicers allow to make two slices of the image of the input fibre. We introduce the idea of a second fibre that can be cropped in half to reach the same width of the science target fibre and that can be used for simultaneous wavelength reference. The slicers presented are mirror and prism based, respectively. Both devices work within expectation, showing differences mainly in their efficiency. The prism based slicer is the solution that was adopted for the FIDEOS spectrograph, an instrument built by the AIUC for the ESO 1m telescope of La Silla. Test spectra obtained with this instrument are included as examples of a real application of the device.  相似文献   

Dynamics of diffuse carbon dioxide emissions from Cumbre Vieja volcano,La Palma,Canary Islands     

Eleazar Padrón  Nemesio M. Pérez  Fátima Rodríguez  Gladys Melián  Pedro A. Hernández  Hirochika Sumino  Germán Padilla  José Barrancos  Samara Dionis  Kenji Notsu  David Calvo 《Bulletin of Volcanology》2015,77(4):1-15

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Collapse and explosion in a rotating star     

G. Ruben  I. Tuominen 《Astronomische Nachrichten》1988,309(2):103-120

The collapse, bounce, shock wave and expansion of the envelope of a rotating star have been analysed in the adiabatic approximation using the particle-in-cell method. The bounce takes place first in the equatorial plane and a shock wave arises there which shortly afterwards crosses the surface of the star. In the envelope, and to a less extent in the remainder of the star, there is a fast and lasting meridional motion the direction of which changes. As a consequence of the fast meridional motion in the envelope, mass and angular momentum are transported towards the axis of rotation. If the initial star rotates fast enough this will cause a secondary radial expansion in the polar region and a mass ejection. These motions reduce the strong anisotropy caused originally by the equatorial expansion. Strong whirls may arise along the axis of rotation. In the remainder of the star the meridional motion becomes supersonic. The temperature in the envelope depends to a high degree on the choice of the equation of state. Massloss is proportional to the energy initially added. The final loss of angular momentum and of energy is quite large, both losses being about 25%.  相似文献