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51.
52.
Two Mississippi Valley-type (MVT) ore deposits, Kicking Horse and Monarch, have been studied with the aim of comparing the ores at the two localities and to characterize the origin of the mineralizing fluids and the ore formation process(es). Both deposits are hosted by the Middle Cambrian Cathedral Formation carbonate host rocks, Kicking Horse on the north and Monarch on the south flank of the Kicking Horse valley near Field (SE British Columbia). The ore bodies are situated at the transition of (western) basinal to (eastern) shallow-water strata of the paleo-Pacific passive margin succession in the Cordilleran Foreland Province of the Western Canada Sedimentary Basin. Both deposits are related spatially to normal faults. In both localities, the ore minerals are dominated by pyrite, sphalerite, and galena. Dolomite, minor quartz, and calcite are also present in close association with the ores. The salinity (21–30 wt% NaCl eq.) and homogenization temperatures (63–182°C) measured in fluid inclusions in carbonate, quartz, and sphalerite lie within the typical range of MVT fluid conditions. The good stoichiometry (50–53 mol% CaCO3), low δ18O values (−21 to −14‰ Vienna Peedee belemnite) and relatively high homogenization temperatures (>95°C) of the dolomite suggest the dolomites were formed under burial diagenesis. The ore-forming fluids probably interacted with siliciclastic units, based on elevated Li contents and 87Sr/86Sr ratios, which are highest in the dolomite type after the main ore stage. We propose that the ores formed from the mixing of a downward-infiltrating, sulfur-bearing halite-dissolution fluid with an upward-migrating, metal-rich evaporated seawater fluid, which had already undergone minor mixing with a dilute fluid.  相似文献   
53.
Predicting sediment flux from fold and thrust belts   总被引:8,自引:1,他引:8  
The rate of sediment influx to a basin exerts a first-order control on stratal architecture. Despite its importance, however, little is known about how sediment flux varies as a function of morphotectonic processes in the source terrain, such as fold and thrust growth, variations in bedrock lithology, drainage pattern changes and temporary sediment storage in intermontane basins. In this study, these factors are explored with a mathematical model of topographic evolution which couples fluvial erosion with fold and thrust kinematics. The model is calibrated by comparing predicted topographic relief with relief measured from a DEM of the Central Zagros Mountains fold belt. The sediment-flux curve produced by the Zagros fold belt simulation shows a delay between the onset of uplift and the ensuing sediment flux response. This delay is a combination of the natural response time of the geomorphic system and a time lag associated with filling, and then subsequently uplifting and re-eroding, the proximal part of the basin. Because deformation typically propagates toward the foreland, the latter time lag may be common to many ancient foreland basins. Model results further suggest that the response time of the bedrock fluvial system is a function of rock resistance, of the width of the region subject to uplift and erosion, and, assuming a nonlinear dependence of fluvial erosion upon channel gradient, of uplift rate. The geomorphic response time for the calibrated Zagros model is on the order of a few million years, which is commensurate with, or somewhat larger than, typical recurrence intervals for episodes of thrusting. However, model experiments also highlight the potential for significant variations in both geomorphic response time and in sediment flux as a function of varying rock resistance. Given a reasonable erodibility contrast between resistant and erodible lithologies, model sediment flux curves show significant sediment flux variations that are related solely to changes in rock resistance as the outcrop pattern changes. An additional control on sediment flux to a basin is drainage diversion in response to folding or thrusting, which can produce major shifts in the location and magnitude of sediment source points. Finally, these models illustrate the potential for a significant mismatch between tectonic events and sediment influx to a basin in cases where sediment is temporarily ponded in an intermontane basin and later remobilized.  相似文献   
54.
Worldwide alkali olivine basalts (AOB) and their differentiation series have been subdivided into continental, oceanic, or island-arc assemblages according to the inferred crustal environment at their time and place of eruption. No systematic differences have been found in major element composition of the AOB's from these three different environments. As plotted on (Na2O + K2O) vs. SiO2 and AMF diagrams, AOB differentiation trends also show no differences between environments. Thus, AOB appears to be a primary magma generated at sufficient depth in the mantle that its major element content is unaffected by chemical or thermal differences between mantle regions underlying continents, ocean basins, or island arcs. The major element chemistry of AOB is also apparently unaffected by passage through different types of crust.  相似文献   
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56.
In this paper, the diagenesis from either side of a major Cenozoic reverse fault in the Northern Oman Mountains is documented. Detailed petrographical and geochemical analysis of calcite-filled fractures in carbonate strata of Late Triassic and Early Cretaceous age in the hanging wall and footwall in Wadi Ghalilah reflect a different diagenetic history. In both hanging wall and footwall most of the fractures are pre-burial, extensional in origin, formed by a crack-seal mechanism, and the calcite vein infill has a host-rock buffered signature. In the hanging wall, the fluid responsible for calcite precipitation of these extensional fractures was a marine fluid at 60 °C. These veins predate deep burial and contractional tectonic deformation and consequently do not provide any information about syntectonic fluid flow. Neither do the pre-burial extension fractures in the footwall which are also host-rock buffered. The fractures post-dating the tectonic stylolitization in the footwall, by contrast, show evidence of syntectonic migration of saline formation waters at temperatures between 80 and 160 °C during contractional deformation. These fluids probably were sourced from the subsurface via the reverse fault, which acted as a fluid conduit. At the same time, however, this fault functioned as a permeability barrier towards the hanging wall, since no evidence of syntectonic fluid flow is present here. In this way compartmentalization of the hanging wall and footwall block was realized.  相似文献   
57.
Gas hydrates accumulate on the Gulf of Mexico seafloor around hydrocarbon seeps in waters sufficiently deep to provide adequate pressure/temperature combinations. High microbial activities occur around the hydrate accumulations. To understand apparent catalytic effects of bioproducts on hydrate formation, the mechanism of sII hydrate nucleation in unconsolidated porous media was investigated in our laboratory. Because smectite clays interacting with biopolymers had been shown to promote laboratory hydrates by decreasing induction times, increasing formation rates and altering morphology, these materials commonly found in near-surface sediments were selected for study as possible nucleating agents. Dynamic light scattering (DLS) with a helium–neon laser was used to measure particle diameters down to about 2 nm. Scanning electron microscopy (SEM) was utilized to verify particle sizes and to give additional information on biopolymer–clay associations. This paper presents evidence that nanometer-sized particles of mineral–bioproduct associations of about 80 nm–450 nm diameter may act as nucleation sites for hydrate crystal initiations in sediments and then remain dispersed throughout the accumulated hydrate mass. Emulsan biopolymer was shown by SEM to apparently unfold and associate with the smectite (nontronite) in a backbone arrangement and to give multiple hydrate nucleation sites along a linear network. SEM and DLS measurements were in agreement on particle sizes and shapes. X-ray diffraction suggested that biopolymer intercalates the smectite interlayer, probably driven by clay associations with biopolymer hydrophilic groups. It is hypothesized that hydrocarbon gases attach to biopolymer hydrophobic fatty-acid branches protruding from clay interlayers and subsequently facilitate hydrate structure formation by interacting with nearby water associated with the hydrophilic segments of the biopolymer.  相似文献   
58.
This study presents a new approach to geobarometry by combining fluid inclusion and clumped isotope (Δ47) thermometry on carbonate minerals. The offset between homogenisation temperatures of primary fluid inclusions with known composition and Δ47 temperatures of the host mineral allows a direct estimation of the fluid pressure at the time of carbonate crystallisation. This new approach is illustrated via hydrothermal dolomite samples from the Variscan foreland fold‐and‐thrust belt in northern Spain. Clumped isotope analyses yield crystallisation temperatures (107–168°C) which are higher than homogenisation temperatures in corresponding samples (95–145°C). The calculated pressure values suggest that dolomitizing fluids were overpressured during formation of zebra dolomite textures, whereas lower pressures are obtained for dolomite cement from breccia textures. This new approach to geobarometry opens up the possibility of estimating the pressure of carbonate crystallisation and has potential applications in diagenesis, basin analysis, ore geology and tectonics.  相似文献   
59.
Using data obtained with the Rossi X-ray Timing Explorer , we report the detection of a 5-Hz quasi-periodic oscillation (QPO) in the bright low-mass X-ray binary and Z source Cygnus X-2 during high overall intensities (the high-intensity state). This QPO was detected on the so-called normal-branch and can be identified with the normal-branch QPO or NBO. Our detection of the NBO is the first one during times when Cygnus X-2 was in the high-intensity state. The rms amplitude of this QPO decreased from 2.8 per cent between 2 and 3.1 keV to <1.9 per cent between 5.0 and 6.5 keV. Above 6.5 keV, its amplitude rapidly increased to ∼12 per cent rms above 16 keV. The time lags of the QPO were consistent with being zero below 5 keV (compared with the 2–3.1 keV band), but they rapidly increased to ∼70 ms (140°) around 10 keV, above which the time lags remained approximately constant near 70 ms. The photon energy dependences of the rms amplitude and the time lags are very similar to those observed for the NBO with other satellites ( Ginga , EXOSAT ) at different (i.e. lower) intensity states.  相似文献   
60.
Carbonate reservoirs in the Córdoba petroleum system (NE Mexico) passed through a multiphase deformation history complicating the petroleum geology. The area evolved from passive margin and foreland setting to Laramide fold and thrust belt (FTB) that was subsequently buried below the Tertiary-Quaternary Veracruz Basin, which in turn underwent transpressional deformation. Reconstruction of paleo-burial (erosion) and paleo-thermicity through the different zones of the FTB and adjacent foreland is a challenging task since classical calibration tools fail to discriminate between several kinematic and thermal models. In this study results from detailed diagenetic and fluid inclusion (FI) analyses on carbonates from the western part of the Córdoba Platform helped constraining paleo-thermicity. Combined microthermometry, synchrotron FTIR analyses and PVT modeling of cogenetic hydrocarbon-aqueous FI allowed also calculation of absolute pressures. Thermal modeling exercises calibrated with organic maturity parameters, bottom-hole temperatures or temperatures from FI demonstrate that without controlling also paleo-erosion the model results may be misleading.  相似文献   
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