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31.
Oxygen, magnesium, and silicon isotopic abundances in Vigarano 1623-5 were studied using secondary ion mass spectrometry to investigate correlations between isotopic and petrologic properties of this unique forsterite-bearing FUN inclusion. Vigarano 1623-5 displays large, correlated mass-dependent fractionation effects, tightly linked to mineralogy within distinct petrologic units of the inclusion. The pyroxene-rich and melilite-rich interior parts of the inclusion display highly mass-fractionated isotopic compositions of oxygen, magnesium, and silicon, consistent with Rayleigh distillation during evaporation of a melt with initial oxygen composition close to a solar composition. However, the chemical composition, enriched in magnesium and silicon, suggests a precursor already fractionated by prior melt evaporation. A discontinuous igneous rim was produced by a flash-melting event followed by isotopic exchange in the rim melilite with planetary-like oxygen, mechanical fragmentation, and reassembly with an accretionary rim of heterogeneous materials. Al-rich minerals in 1623-5 show evidence for having crystallized with live 26Al but at less than the “canonical” level of most CV calcium-aluminum-rich inclusions. However, well-defined 26Al-26Mg isochrons are not found and temporal implications are ambiguous.  相似文献   
32.
Abstract– Evaporation rates of K2O, Na2O, and FeO from chondrule‐like liquids and the associated potassium isotopic fractionation of the evaporation residues were measured to help understand the processes and conditions that affected the chemical and isotopic compositions of olivine‐rich type IA and type IIA chondrules from Semarkona. Both types of chondrules show evidence of having been significantly or totally molten. However, these chondrules do not have large or systematic potassium isotopic fractionation of the sort found in the laboratory evaporation experiments. The experimental results reported here provide new data regarding the evaporation kinetics of sodium and potassium from a chondrule‐like melt and the potassium isotopic fractionation of evaporation residues run under various conditions ranging from high vacuum to pressures of one bar of H2+CO2, or H2, or helium. The lack of systematic isotopic fractionation of potassium in the type IIA and type IA chondrules compared with what is found in the vacuum and one‐bar evaporation residues is interpreted as indicating that they evolved in a partially closed system where the residence time of the surrounding gas was sufficiently long for it to have become saturated in the evaporating species and for isotopic equilibration between the gas and the melt. A diffusion couple experiment juxtaposing chondrule‐like melts with different potassium concentrations showed that the diffusivity of potassium is sufficiently fast at liquidus temperatures (DK > 2 × 10?4cm2 s?1 at 1650 °C) that diffusion‐limited evaporation cannot explain why, despite their having been molten, the type IIA and type IA chondrules show no systematic potassium isotopic fractionation.  相似文献   
33.
This paper describes the economic and technological benefits of installing continuous welded rail(CWR) track on sharp(radius ≤ 300 m) railway curves. A new form of prestressed concrete sleepers developed by the V. Lazaryan Dnipropetrovsk National University of Railway Transport is shown to improve the lateral shift resistance of CWR track in sharp curves and the use of anchor sleepers on tangents is shown to make it possible to lower the fastening temperature of the CWR track in order to increase the rail lifespan.  相似文献   
34.
Echo sounders served to locate a large number of shallow- and deepwater gas seeps at the bottom of all three basins of Lake Baikal during the years 2005 to 2008. A substantial proportion of the shallow gas seeps was located near the delta of the Selenga River, and at the Posolskii uplift. Deepwater gas seeps were recorded at the lake bed both inside and outside of areas where a bottom-simulating reflector was identified in seismic profiles. By monitoring the activity of gas emissions at the gas seeps, times of episodic gas ebullition could be distinguished from times of persistent gas bubble streams. A maximum gas flare height of more than 950 m above the bottom was recorded at the St. Petersburg mud volcano located in the central basin of Lake Baikal. Based on calculations from echo sounder data, the ascent velocity of gas bubbles reached 40 cm/s. In the area of gas seepage, there was a thick near-bottom layer, in which the gradient of water temperature was equal to the adiabatic gradient. This implies complete mixing of the water close to the lake bed, resulting from ascending gas bubbles released at seep sites. Analyses of vertical temperature profiles indicate possibly localized upwelling up to the lake surface when gas emissions are intensive.  相似文献   
35.
Micro-computed tomography (μCT) is a fast and powerful technology for studying textural, physical, and chemical properties of solid objects in three dimensions. While regularly used for sample documentation and curation, it is often assumed that μCT techniques are essentially nondestructive or at least very little destructive. However, there are very few studies proving or rejecting the assumption of nondestructiveness. Here we study whether X-ray tomographic imaging affects the noble gas budget of matrix samples from the CV3 carbonaceous chondrite Allende. We irradiated powdered and homogenized matrix samples in the Bruker SkyScan 1272 μCT instrument at three different X-ray tube acceleration voltages of 30, 70, and 100 keV. By comparing the noble gas concentrations and especially the elemental and isotopic ratios of the irradiated samples with data for two non-irradiated aliquots, we found no significant differences. Our study therefore demonstrates that X-ray tomographic imaging has no measurable effect on the noble gas budget and can therefore safely be used for sample characterization prior to noble gas studies.  相似文献   
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